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公开(公告)号：US5620824A
公开(公告)日：1997-04-15
申请号：US272507
申请日：1994-07-07
CPC分类号： G03G9/08 , G03G9/0819 , G03G9/0823 , G03G9/097
摘要： A toner for developing an electrostatic image has colored resin particles-(A) containing a coloring agent or a magnetic powder, and a powdery additive. The powdery additive has organic resin particles-(B) having peaks respectively in a region of particles diameters of 20 m.mu. to 200 m.mu. and a region of particle diameters of 300 m.mu. to 800 m.mu. in their particle size distribution, and the larger-diameters particles included in the region of particle diameters of 300 m.mu. to 800 m.mu. being contained in an amount of from 2% by weight to 20% by weight.
摘要翻译： 用于显影静电图像的调色剂具有含有着色剂或磁性粉末的着色树脂颗粒 - （A）和粉末状添加剂。 粉末状添加剂具有分别在粒径20μm〜200μm的范围内具有峰值的有机树脂粒子，粒径分布为300μm〜800μm的粒子的区域， 包含在粒径为300μm至800μm的区域中的大直径粒子的含量为2重量％至20重量％。
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2.发明授权Carrier for electrophotography, two-component type developer, and image forming method 失效电子照相用载体，双组分型显影剂和成像方法
公开(公告)号：US5670288A
公开(公告)日：1997-09-23
申请号：US599845
申请日：1996-02-12
申请人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Yasuhiro Ichikawa , Wakashi Iida
发明人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Yasuhiro Ichikawa , Wakashi Iida
CPC分类号： G03G9/10 , G03G9/0918 , G03G9/09708 , G03G9/09716 , G03G9/107
摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression: S.sub.2 =(6/.rho..multidot.D.sub.50).times.10.sup.4 wherein .rho. is a specific gravity of carrier; satisfying the following condition: 1.2 .ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.
摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho×D50）×104其中rho是载体的比重; 满足以下条件：1.2
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3.发明授权Carrier for electrophotography, two-component type developer, and image forming method 失效电子照相用载体，双组分型显影剂和成像方法
公开(公告)号：US5512402A
公开(公告)日：1996-04-30
申请号：US246146
申请日：1994-05-19
申请人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Yasuhiro Ichikawa , Wakashi Iida
发明人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Yasuhiro Ichikawa , Wakashi Iida
CPC分类号： G03G9/10 , G03G9/0918 , G03G9/09708 , G03G9/09716 , G03G9/107
摘要： A carrier for electrophotography has carrier particles. The carrier has a 50% average particle diameter (D.sub.50) of from 15 .mu.m to 45 .mu.m and contains from 1% to 20% of carrier particles with a size smaller than 22 .mu.m, not more than 3% of carrier particles with a size smaller than 16 .mu.m, from 2% to 15% of carrier particles with a size of 62 .mu.m or larger, and not more than 2% of carrier particles with a size of 88 .mu.m or larger. The carrier has a specific surface area S.sub.1 as measured by an air-permeability method and a specific surface area S.sub.2 as calculated by the following expression:S.sub.2 =(6/.rho..D.sub.50).times.10.sup.4wherein .rho. is a specific gravity of carrier; satisfying the following condition:1.2.ltoreq.S.sub.1 /S.sub.2 .ltoreq.2.0.
摘要翻译： 电子照相用载体具有载体颗粒。 载体具有15μm至45μm的50％平均粒径（D50），并且含有1％至20％的尺寸小于22μm的载体颗粒，不超过载体颗粒的3％ 尺寸小于16μm，尺寸为62μm或更大的载体颗粒的2％至15％，以及不大于2％的尺寸为88μm或更大的载体颗粒。 载体具有通过透气度法测定的比表面积S1和通过下式计算的比表面积S2：S2 =（6 / rho.D50）×104其中rho是载体的比重; 满足以下条件：1.2
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4.发明授权
公开(公告)号：US5700617A
公开(公告)日：1997-12-23
申请号：US727219
申请日：1996-10-08
申请人： Tsuyoshi Takiguchi , Kenji Okado , Masaaki Taya , Ryoichi Fujita , Makoto Kanbayashi , Wakashi Iida , Tetsuya Ida
发明人： Tsuyoshi Takiguchi , Kenji Okado , Masaaki Taya , Ryoichi Fujita , Makoto Kanbayashi , Wakashi Iida , Tetsuya Ida
CPC分类号： G03G9/09733 , G03G9/09708 , G03G9/09783
摘要： A toner for developing an electrostatic image is formed from toner particles containing a binder resin, a colorant, and a charge-controlling agent. The charge-controlling agent comprises an aromatic oxycarboxylic acid, a metal compound of the aromatic oxycarboxylic acid, and an inorganic compound formed from an inorganic anion and an inorganic cation. The aromatic oxycarboxylic acid, the metal compound of the aromatic carboxylic acid and the inorganic anion are contained in proportions of A (wt. %), B (wt. %) and C (ppm), respectively, satisfying the following conditions: 1/99.ltoreq.A/B.ltoreq.20/80, and 10.sup.2 .ltoreq.C. Because of the inclusion of an inorganic compound providing a sufficient amount of inorganic anion, the charge-controlling agent shows a stable charge-controlling characteristic, and the resultant toner exhibits a stable developing performance and transferability in continuous image formation in various environmental conditions.
摘要翻译： 用于显影静电图像的调色剂由含有粘合剂树脂，着色剂和电荷控制剂的调色剂颗粒形成。 电荷控制剂包括芳族羟基羧酸，芳族羟基羧酸的金属化合物和由无机阴离子和无机阳离子形成的无机化合物。 芳族羟基羧酸，芳族羧酸的金属化合物和无机阴离子分别以A（重量％），B（重量％）和C（ppm）的比例包含，满足以下条件：1 / 99 。 由于含有提供足够量的无机阴离子的无机化合物，电荷控制剂显示出稳定的电荷控制特性，并且所得调色剂在各种环境条件下表现出稳定的连续成像的显影性能和转印性。
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公开(公告)号：US5851714A
公开(公告)日：1998-12-22
申请号：US825395
申请日：1997-03-28
申请人： Masaaki Taya , Kenji Okado , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Wakashi Iida , Tetsuya Ida
发明人： Masaaki Taya , Kenji Okado , Ryoichi Fujita , Makoto Kanbayashi , Tsuyoshi Takiguchi , Wakashi Iida , Tetsuya Ida
CPC分类号： G03G9/08797 , G03G9/081 , G03G9/08755 , G03G9/08793 , G03G9/08795
摘要： A toner for developing an electrostatic image is formed from toner particles containing at least a binder resin, a colorant and an organometallic compound. The binder resin in the toner particles has a tetrahydrofuran-insoluble (THF-insoluble) content of at most 5.0 wt.% based on the binder resin. The toner has a glass transition temperature of 50.degree.-80.degree. C. The toner further has storage modulus characteristics including a storage modulus at 80.degree. C. (G'.sub.80) of 1.times.10.sup.4 -5.times.10.sup.6 �dyn/cm.sup.2 !, a storage modulus at 130.degree. C. (G'.sub.130) providing a ratio G'.sub.80 /G'.sub.130 of 10-5.times.10.sup.3, and a storage modulus curve showing a minimum (G'min) in a temperature region of 110.degree.-190.degree. C. The toner especially exhibits excellent low-temperature fixability, anti-high temperature offset characteristic, storage stability and color-miscibility.
摘要翻译： 用于显影静电图像的调色剂由至少含有粘合剂树脂，着色剂和有机金属化合物的调色剂颗粒形成。 调色剂颗粒中的粘合剂树脂相对于粘合剂树脂具有至多5.0重量％的四氢呋喃不溶（THF不溶性）含量。 调色剂的玻璃化转变温度为50-80℃。该调色剂还具有储能模量特性，包括80℃下的储能模量（G'80）为1×104-5×106 [dyn / cm2]，储能模量 130℃（G'130），比率G'80 / G'130为10-5×103，储能模量曲线在110〜190℃的温度区域为最小值（G'min）。 调色剂特别表现出优异的低温定影性，抗高温偏移特性，储存稳定性和颜色混溶性。
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6.发明授权Toner for developing electrostatic images containing aromatic hydroxycarboxylic acid and metal compound of the aromatic hydroxycarboxylic acid 失效用于显影含有芳族羟基羧酸的静电图像和芳族羟基羧酸的金属化合物的调色剂
公开(公告)号：US5747209A
公开(公告)日：1998-05-05
申请号：US640077
申请日：1996-04-30
申请人： Tsuyoshi Takiguchi , Kenji Okado , Masaaki Taya , Ryoichi Fujita , Makoto Kanbayashi , Kohji Inaba , Wakashi Iida , Kazunori Kato , Tetsuya Ida , Shinya Yachi
发明人： Tsuyoshi Takiguchi , Kenji Okado , Masaaki Taya , Ryoichi Fujita , Makoto Kanbayashi , Kohji Inaba , Wakashi Iida , Kazunori Kato , Tetsuya Ida , Shinya Yachi
CPC分类号： G03G9/09783 , G03G9/09733
摘要： A toner for developing electrostatic images is formed of toner particles comprising (a) a binder resin, (b) a colorant or magnetic material, (c) an aromatic hydroxycarboxylic acid (A), and (d) a metal compound of the aromatic hydroxycarboxylic acid (A). The aromatic hydroxycarboxylic acid (A) and the metal compound of the aromatic hydroxycarboxylic acid (A) are contained in a weight ratio of 1:99 to 10:90. As a result of co-inclusion of a small amount of the aromatic hydroxycarboxylic acid (A) in addition to the metal compound thereof, the resultant toner is provided with a quick chargeability in a low humidity environment and an improved level of triboelectric charge in a high humidity environment, presumably because of the stabilization effect of the small amount of the aromatic hydroxycarboxylic acid (A) on the metal compound thereof.
摘要翻译： 用于显影静电图像的调色剂由调色剂颗粒形成，包括（a）粘合剂树脂，（b）着色剂或磁性材料，（c）芳族羟基羧酸（A），和（d）芳族羟基羧酸的金属化合物 酸（A）。 芳香族羟基羧酸（A）和芳香族羟基羧酸（A）的金属化合物的重量比为1:99〜10:90。 作为除了其金属化合物之外少量芳族羟基羧酸（A）共混物的结果，所得到的调色剂在低湿度环境中具有快速带电性，并且提供了一种改善的摩擦带电量 高湿度环境，大概是因为少量芳族羟基羧酸（A）对其金属化合物的稳定作用。
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7.发明授权Electrophotographic apparatus, image forming method, and process cartridge for developing an image with toner containing an external additive 失效电子照相设备，图像形成方法和用于利用含有外部添加剂的调色剂显影图像的处理盒公开(公告)号：US06285848B1
公开(公告)日：2001-09-04
申请号：US09092935
申请日：1998-06-08
申请人： Shuichi Aita , Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Fumihiro Arahira , Kiyoshi Mizoe , Yoshifumi Hano
发明人： Shuichi Aita , Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Fumihiro Arahira , Kiyoshi Mizoe , Yoshifumi Hano
IPC分类号： G03G1502
CPC分类号： G03G15/0241 , G03G21/0064 , G03G2215/022
摘要： An electrophotographic apparatus includes an electrophotographic photosensitive member, and (i) a charger, (ii) an imagewise exposure device, (iii) a developing device and (iv) a transfer device, disposed in this order opposite to the photosensitive member. The charger includes a charging member including magnetic particles disposed in contact with the photosensitive member so as to charge the photosensitive member based on a voltage received thereby. The magnetic particles are surface-coated with a coupling agent having a linear alkyl group having a least 6 carbon atoms. The developing device also functions to recover residual toner remaining on the photosensitive member processing by the transfer device and the charger. Because of the coating with such a specific coupling agent, the charging magnetic particles can exhibit good triboelectric changeability for the transfer residual toner for a long period.
摘要翻译： 电子照相设备包括电子照相感光构件，以及（i）充电器，（ii）成像曝光装置，（iii）以与感光构件相对的顺序设置的显影装置和（iv）转印装置。 充电器包括充电构件，其包括与感光构件接触设置的磁性颗粒，以便基于由此接收的电压对感光构件充电。 磁性颗粒用具有至少6个碳原子的直链烷基的偶联剂进行表面涂覆。 显影装置还用于恢复由转印装置和充电器处理的感光构件上残留的残留调色剂。 由于用这种特殊的偶联剂进行涂布，所以带电磁性颗粒可以长时间显示转印残留调色剂的良好的摩擦带电性。
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公开(公告)号：US5994019A
公开(公告)日：1999-11-30
申请号：US979960
申请日：1997-11-26
申请人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Kazumi Yoshizaki
发明人： Kenji Okado , Toshiyuki Ugai , Ryoichi Fujita , Kazumi Yoshizaki
CPC分类号： G03G13/025 , G03G15/0241 , G03G2215/022
摘要： An image forming method is disclosed in which a contact charging means is brought into contact with a latent image bearing member to electrostatically charge the latent image bearing member on which electrostatic latent images are formed and developed with a one component type or two component type developer to form toner images, using a developing assembly provided with a developing container and a developer carrying member. The one component developer is comprised of toner particles. The two component type developer is comprised of toner particles and a magnetic carrier. The toner particles of the one component type and two component type developers contains fine particles as an external additive.The latent image bearing member has a surface layer having a volume resistivity A of from 10.sup.8 to 10.sup.15 .OMEGA..multidot.cm; the contact charging means comprises an assembly for electrostatically charging the latent image bearing member by applying a voltage to a charging member having a volume resistivity B of from 10.sup.4 to 10.sup.9 .OMEGA..multidot.cm; the toner has, as an external additive, fine particles having a volume resistivity C of from 10.sup.7 to 10.sup.11 .OMEGA..multidot.cm; the magnetic carrier has a volume resistivity D1 of from 10.sup.9 to 10.sup.15 .OMEGA..multidot.cm; and the developer carrying member has a surface layer having a volume resistivity D2 of from 10.sup.9 to 10.sup.15 .OMEGA..multidot.cm. The resistivities A, B, C, D1 and D2 stasisfy the following conditions: B
摘要翻译： 公开了一种图像形成方法，其中接触充电装置与潜像承载部件接触，以静电潜像形成和显影的潜像承载部件用单组分型或双组分型显影剂静电充电 使用具有显影容器和显影剂承载构件的显影组件形成调色剂图像。 单组分显影剂由调色剂颗粒组成。 双组分型显影剂由调色剂颗粒和磁性载体构成。 单组分型和二组分型显影剂的调色剂颗粒含有作为外部添加剂的细颗粒。 潜像承载部件具有体积电阻率A为108至1015欧米伽×厘米的表面层; 接触充电装置包括用于通过向体积电阻率B为104至109欧姆×xcm的充电部件施加电压来静电充电潜像承载部件的组件; 作为外部添加剂，调色剂具有体积电阻率C为107至1011欧米伽×厘米的细小颗粒; 磁性载体的体积电阻率D1为109〜1015ΩEGEG×cm; 并且显影剂承载构件具有体积电阻率D2为109至1015欧姆×xcm的表面层。 电阻率A，B，C，D1和D2停留在以下条件下：B
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9.发明授权Developer for developing electrostatic image, image forming method, toner imager fixing method and image forming apparatus 失效用于显影静电图像，图像形成方法，调色剂成像器固定方法和图像形成装置的显影剂
公开(公告)号：US5418102A
公开(公告)日：1995-05-23
申请号：US799193
申请日：1991-11-27
CPC分类号： G03G13/08 , G03G15/2057 , G03G9/08788 , G03G9/09758
摘要： A developer for developing an electrostatic image has a toner containing a binder resin and a colorant. The binder resin is comprised of an AB-type block copolymer having segment-A and segment-B.The segment-A has a copolymer structure comprised of a styrene monomer and at least one monomer selected from the group consisting of an acrylic monomer, a methacrylic monomer and a diene monomer, and the segment-B has a copolymer structure comprised of a styrene monomer and at least one monomer selected from the group consisting of an acrylic monomer, a methacrylic monomer and a diene monomer, provided that the segment-A and segment-B have copolymer structures different from each other.
摘要翻译： 用于显影静电图像的显影剂具有含有粘合剂树脂和着色剂的调色剂。 粘合剂树脂由具有段-A和段B的AB型嵌段共聚物组成。 段A具有由苯乙烯单体和至少一种选自丙烯酸单体，甲基丙烯酸单体和二烯单体的单体组成的共聚物结构，段B具有由苯乙烯单体组成的共聚物结构 和至少一种选自丙烯酸单体，甲基丙烯酸单体和二烯单体的单体，条件是段-A和段-B具有彼此不同的共聚物结构。
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10.发明授权Magenta toner, process for producing same and color image forming method using same 失效洋红色调色剂，其制造方法和使用其的彩色图像形成方法
公开(公告)号：US5912099A
公开(公告)日：1999-06-15
申请号：US904476
申请日：1997-08-04
申请人： Makoto Kanbayashi , Masaaki Taya , Ryoichi Fujita , Wakashi Iida , Tetsuya Ida
发明人： Makoto Kanbayashi , Masaaki Taya , Ryoichi Fujita , Wakashi Iida , Tetsuya Ida
摘要： A magenta toner for developing electrostatic images is formed of a binder resin, and a quinacridone pigment providing an X-ray diffraction spectrum showing two peaks in a Bragg angle (2.theta.) region of 5-10 deg. The magenta toner has an improved light fastness, may have a desired hue comparable to a printing process ink and is suitably used for electrophotographic full-color image formation. The magenta toner may preferably be formed through a process including a first kneading step starting from wet blending of a binder resin and two paste pigments including quinacridone and 2,9-dimethylquinacridone, respectively, under mild conditions not causing crystal transformation to form a master batch and a second kneading step of diluting the master batch together with other additive.
摘要翻译： 用于静电图像显影的品红色调色剂由粘合剂树脂形成，并且提供在5-10度的布拉格角（2θ）区域中显示两个峰的X射线衍射光谱的喹吖啶酮颜料。 洋红色调色剂具有改善的耐光性，可以具有与印刷工艺油墨相当的期望色调，并且适用于电子照相全色图像形成。 品红色调色剂可以优选通过包括第一捏合步骤的方法形成，所述方法包括在不引起晶体转变以形成母料的温和条件下分别湿粘合粘合剂树脂和包括喹吖啶酮和2,9-二甲基喹吖啶酮的两种糊状颜料 以及将母料与其他添加剂一起稀释的第二捏合步骤。
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