公开(公告)号：US10328380B2

公开(公告)日：2019-06-25

申请号：US15564935

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  C07F5/06 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20210039078A1

公开(公告)日：2021-02-11

申请号：US17078618

申请日：2020-10-23

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC: B01J31/16 ,  B01J20/22 ,  B01D53/02

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US11344870B2

公开(公告)日：2022-05-31

申请号：US17078618

申请日：2020-10-23

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC: B01J31/16 ,  B01J20/22 ,  B01D53/02

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US10744482B2

公开(公告)日：2020-08-18

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US11077423B2

公开(公告)日：2021-08-03

申请号：US16943998

申请日：2020-07-30

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  C07D241/10 ,  C07F19/00 ,  B01D53/02

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10335779B2

公开(公告)日：2019-07-02

申请号：US15564920

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC: B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US10328414B2

公开(公告)日：2019-06-25

申请号：US15564909

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US11534712B2

公开(公告)日：2022-12-27

申请号：US17109844

申请日：2020-12-02

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/02 ,  B01D53/04 ,  B01D53/52 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J20/02 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  B01J31/16 ,  C07F15/02 ,  C07F15/04 ,  C07F5/06 ,  C07F9/00

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US11285426B2

公开(公告)日：2022-03-29

申请号：US16500548

申请日：2018-04-05

Applicant: King Abdullah University of Science and Technology

Inventor： Amandine Cadiau ,  Karim Adil ,  Youssef Belmabkhout ,  Prashant M. Bhatt ,  Mohamed Eddaoudi

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/22 ,  B01J20/34

Abstract: Embodiments of the present disclosure describe a method of capturing chemical species from a fluid composition comprising providing a metal-organic framework characterized by the formula MaMbF5(O/H2O)(pyrazine)2.x(solv), wherein Ma is Ni2+; Mb is Nb5+, Al3+, or Fe3+; x is from 0 to 10 and solv is one or more of H2O, CO2, DMF, EtOH, NMP, MeOH; contacting the metal-organic framework with a fluid composition including H2O, CO2, and one or more other chemical species; and capturing H2O and CO2 simultaneously from the fluid composition.

公开(公告)号：US10857500B2

公开(公告)日：2020-12-08

申请号：US16431860

申请日：2019-06-05

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/52 ,  B01D53/02 ,  B01D53/04 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J20/02 ,  B01J20/22 ,  B01J20/34 ,  B01J31/16 ,  C07F15/02 ,  C07F15/04 ,  C07F5/06 ,  C07F9/00 ,  B01J20/28

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.