公开(公告)号：US11077423B2

公开(公告)日：2021-08-03

申请号：US16943998

申请日：2020-07-30

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC分类号： B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  C07D241/10 ,  C07F19/00 ,  B01D53/02

摘要： Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10913718B2

公开(公告)日：2021-02-09

申请号：US16396905

申请日：2019-04-29

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

IPC分类号： C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

摘要： A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

公开(公告)号：US10858374B2

公开(公告)日：2020-12-08

申请号：US16522162

申请日：2019-07-25

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Rasha Abdulhalim ,  Youssef Belmabkhout

IPC分类号： C07F5/00 ,  B01D53/02 ,  B01D53/14 ,  B01D53/26 ,  B01D53/28 ,  B01J20/22 ,  C02F1/28 ,  F25B17/08 ,  C02F103/08

摘要： A method for preparing a metal-organic framework (MOF) comprising contacting one or more of a rare earth metal ion component with one or more of a tetratopic ligand component, sufficient to form a rare earth-based MOF for controlling moisture in an environment. A method of moisture control in an environment comprising adsorbing and/or desorbing water vapor in an environment using a MOF, the MOF including one or more of a rare earth metal ion component and one or more of a tetratopic ligand component. A method of controlling moisture in an environment comprising sensing the relative humidity in the environment comprising a MOF; and adsorbing water vapor on the MOF if the relative humidity is above a first level, sufficient to control moisture in an environment.

公开(公告)号：US10563554B2

公开(公告)日：2020-02-18

申请号：US16507730

申请日：2019-07-10

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Osama Shekhah

IPC分类号： B01D53/02 ,  F01N3/08 ,  B01J20/22 ,  F01N3/022

摘要： In general, this disclosure describes method of capturing and storing CO2 on a vehicle. The method includes contacting an vehicle exhaust gas with one or more of a first metal organic framework (MOF) composition sufficient to separate CO2 from the exhaust gas, contacting the separated CO2 with one or more of a second MOF composition sufficient to store the CO2 and wherein the one or more first MOF composition comprises one or more SIFSIX-n-M MOF and wherein M is a metal and n is 2 or 3. Embodiments also describe an apparatus or system for capturing and storing CO2 onboard a vehicle.

公开(公告)号：US10335779B2

公开(公告)日：2019-07-02

申请号：US15564920

申请日：2016-04-07

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC分类号： B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22

摘要： Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US10328414B2

公开(公告)日：2019-06-25

申请号：US15564909

申请日：2016-04-07

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC分类号： B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

摘要： Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US10130908B2

公开(公告)日：2018-11-20

申请号：US15100513

申请日：2014-11-26

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Bassem A. Almaythalony ,  Osama Shekhah ,  Youssef Belmabkhout

IPC分类号： B01D53/22 ,  B01D71/02 ,  B01D67/00 ,  B01D69/02 ,  B01D69/10 ,  B01D53/28

摘要： Metal organic framework membranes can be used in gas separation applications.

公开(公告)号：US11952391B2

公开(公告)日：2024-04-09

申请号：US17251387

申请日：2019-06-11

申请人： King Abdullah University of Science and Technology

发明人： Hao Jiang ,  Mohamed Eddaoudi

IPC分类号： G16C20/10 ,  C07F5/00 ,  G16C20/50 ,  B01J20/22

CPC分类号： C07F5/003 ,  B01D2253/204 ,  B01D2253/302 ,  B01J20/226

摘要： Embodiments of the present disclosure describe materials comprising a metal component, a first polytopic ligand, and a second polytopic ligand that associate to form an intricate mixed-linker structure with a merged-net. Embodiments of the present disclosure further describe methods of synthesizing intricate mixed-linker structure comprising: contacting a metal precursor, first ligand precursor, and second ligand precursor under reaction conditions sufficient to form an intricate mixed-linker structure with a merged net.

公开(公告)号：US11701637B2

公开(公告)日：2023-07-18

申请号：US16642525

申请日：2018-09-19

申请人： King Abdullah University of Science and Technology

发明人： Sk Md Towsif Abtab ,  Youssef Belmabkhout ,  Prashant Bhatt ,  Mohamed Eddaoudi

IPC分类号： B01D53/04 ,  B01J20/22 ,  B01D53/02 ,  B01D53/26 ,  B01D53/28 ,  B01J20/30 ,  B01J20/34 ,  C07C63/331 ,  C07F11/00 ,  C07F15/02

CPC分类号： B01J20/226 ,  B01D53/02 ,  B01D53/261 ,  B01D53/28 ,  B01J20/3085 ,  B01J20/3458 ,  C07C63/331 ,  C07F11/005 ,  C07F15/025 ,  B01D2253/204 ,  B01D2257/80

摘要： Embodiments of the present disclosure describe a metal-organic framework (MOF) composition comprising a plurality of metal clusters, wherein the metal is chromium; and one or more tetratopic ligands; wherein the metal clusters and ligands associate to form a MOF with soc topology. A method of making a MOF comprising contacting a template MOF of formula Fe-soc-MOF and a reactant including chromium in a presence of dimethylformamide sufficient to replace Fe with Cr and form an exchanged MOF of formula Cr-soc-MOF. A method of sorbing water vapor comprising exposing a Cr-soc-MOF to an environment; and sorbing water vapor using the Cr-soc-MOF.

公开(公告)号：US11566198B2

公开(公告)日：2023-01-31

申请号：US17022201

申请日：2020-09-16

申请人： King Abdullah University of Science and Technology ,  Saudi Arabian Oil Company

发明人： Mohamed Eddaoudi ,  Youssef Belmabkhout

IPC分类号： B01J20/22 ,  B01J20/28 ,  B01J31/16 ,  C10L3/06 ,  C10L3/10 ,  B01D53/02 ,  B01D53/04

摘要： Embodiments provide a method of compound removal from a fluid. The method includes contacting one or more metal organic framework (MOF) compositions with a fluid and sorbing one or more compounds, such as CO2, H2S and condensable hydrocarbons. One or more of CO2, H2S and condensable hydrocarbons can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF.