公开(公告)号：US20210039078A1

公开(公告)日：2021-02-11

申请号：US17078618

申请日：2020-10-23

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC分类号： B01J31/16 ,  B01J20/22 ,  B01D53/02

摘要： Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US11905246B2

公开(公告)日：2024-02-20

申请号：US17171127

申请日：2021-02-09

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

IPC分类号： C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

CPC分类号： C07D209/88 ,  B01J20/226 ,  B01J31/1691 ,  B01J37/04 ,  B01J37/06 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  C07D317/36 ,  B01J2231/34 ,  B01J2531/0211 ,  B01J2531/36 ,  B01J2531/38 ,  B01J2531/845 ,  Y02C20/40

摘要： A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

公开(公告)号：US11344870B2

公开(公告)日：2022-05-31

申请号：US17078618

申请日：2020-10-23

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC分类号： B01J31/16 ,  B01J20/22 ,  B01D53/02

摘要： Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US10744482B2

公开(公告)日：2020-08-18

申请号：US16434472

申请日：2019-06-07

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC分类号： B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

摘要： Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US11077423B2

公开(公告)日：2021-08-03

申请号：US16943998

申请日：2020-07-30

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC分类号： B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  C07D241/10 ,  C07F19/00 ,  B01D53/02

摘要： Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10913718B2

公开(公告)日：2021-02-09

申请号：US16396905

申请日：2019-04-29

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Dongxu Xue ,  Ryan Luebke ,  Vincent Guillerm ,  Abdul Malik Puthan Peedikakkal ,  Karim Adil ,  Lukasz Weselinski

IPC分类号： C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

摘要： A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

公开(公告)号：US10335779B2

公开(公告)日：2019-07-02

申请号：US15564920

申请日：2016-04-07

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Amandine Cadiau

IPC分类号： B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22

摘要： Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US10328414B2

公开(公告)日：2019-06-25

申请号：US15564909

申请日：2016-04-07

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC分类号： B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

摘要： Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US11857910B2

公开(公告)日：2024-01-02

申请号：US17251471

申请日：2019-06-11

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Rachid Tchalala ,  Karumbaiah Nanaiah ,  Karim Adil ,  Youssef Belmabkhout ,  Mohamed Eddaoudi ,  Khaled N. Salama

IPC分类号： B01D53/04 ,  B01J20/22 ,  G01N27/22 ,  G01N29/02 ,  G01N29/036

CPC分类号： B01D53/04 ,  B01J20/226 ,  G01N27/226 ,  G01N29/022 ,  G01N29/036 ,  B01D2253/204 ,  B01D2257/302 ,  B01D2257/504 ,  B01D2257/80 ,  G01N2027/222 ,  G01N2291/0256 ,  G01N2291/0426

摘要： Metal-organic frameworks for capturing one or more of SO2, CO2, and H2O are disclosed herein. Non-limiting examples of metal-organic frameworks include NbOFFIVE-1-Ni and AIFFIVE-1-Ni, among others. The metal-organic frameworks can be used in applications for removing and/or sensing one or more of SO2, CO2, and H2O from a fluid composition or an environment, either of which can proceed under dry or humid conditions and/or at room temperature.

公开(公告)号：US11229872B2

公开(公告)日：2022-01-25

申请号：US16903820

申请日：2020-06-17

申请人： King Abdullah University of Science and Technology

发明人： Mohamed Infas Haja Mohideen ,  Karim Adil ,  Youssef Belmabkhout ,  Mohamed Eddaoudi ,  Prashant M. Bhatt

IPC分类号： B01D53/04 ,  B01D53/047 ,  B01J20/28 ,  B01J20/22 ,  B01J20/30 ,  C07C45/78 ,  B01D53/02

摘要： Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.