公开(公告)号：US20210171463A1

公开(公告)日：2021-06-10

申请号：US17171127

申请日：2021-02-09

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Dongxu XUE ,  Ryan LUEBKE ,  Vincent GUILLERM ,  Abdul Malik Puthan PEEDIKAKKAL ,  Karim ADIL ,  Lukasz WESELINSKI

IPC: C07D209/88 ,  B01J20/22 ,  B01J31/16 ,  C07C63/66 ,  C07C65/05 ,  C07C65/11 ,  B01J37/04 ,  B01J37/06 ,  C07D317/36

Abstract: A molecular building block composition can include a metal ion component; and a ligand component including a core including at least one functional group associated with the metal ion component and the core.

公开(公告)号：US20180304246A1

公开(公告)日：2018-10-25

申请号：US15564920

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Amandine CADIAU

IPC: B01J31/16 ,  B01J20/22 ,  B01D53/02

CPC classification number: B01J31/1691 ,  B01D53/02 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/708 ,  B01D2257/80 ,  B01J20/226 ,  B01J2540/40 ,  Y02C10/08 ,  Y02E50/346

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US20190282949A1

公开(公告)日：2019-09-19

申请号：US16431860

申请日：2019-06-05

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed EDDAOUDI ,  Amandine CADIAU ,  Prashant M. BHATT ,  Karim ADIL ,  Youssef BELMABKHOUT

IPC: B01D53/02 ,  B01J20/28 ,  C07F15/04 ,  C07F15/02 ,  C07F9/00 ,  B01J20/34 ,  B01J20/22 ,  C07F5/06

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20190270078A1

公开(公告)日：2019-09-05

申请号：US16412512

申请日：2019-05-15

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Amandine CADIAU

IPC: B01J31/16 ,  B01D53/02 ,  B01J20/22

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.

公开(公告)号：US20180093218A1

公开(公告)日：2018-04-05

申请号：US15564935

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed EDDAOUDI ,  Amandine CADIAU ,  Prashant M. BHATT ,  Karim ADIL ,  Youssef BELMABKHOUT

IPC: B01D53/02 ,  B01J20/22 ,  B01J20/34 ,  C07F9/00 ,  C07F5/06 ,  C07F15/02 ,  C07F15/04

CPC classification number: B01D53/02 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/80 ,  B01D2259/40007 ,  B01J20/226 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/3425 ,  B01J20/3483 ,  B01J20/3491 ,  C07F5/066 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04 ,  Y02C10/08

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20210252448A1

公开(公告)日：2021-08-19

申请号：US17251471

申请日：2019-06-11

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Rachid TCHALALA ,  Karumbaiah NANAIAH ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Khaled N. SALAMA

IPC: B01D53/04 ,  B01J20/22 ,  G01N29/036 ,  G01N29/02 ,  G01N27/22

Abstract: Metal-organic frameworks for capturing one or more of SO2, CO2, and H2O are disclosed herein. Non-limiting examples of metal-organic frameworks include NbOFFIVE-1-Ni and AlFFIVE-1-Ni, among others. The metal-organic frameworks can be used in applications for removing and/or sensing one or more of SO2, CO2, and H2O from a fluid composition or an environment, either of which can proceed under dry or humid conditions and/or at room temperature.

公开(公告)号：US20210086128A1

公开(公告)日：2021-03-25

申请号：US17109844

申请日：2020-12-02

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed EDDAOUDI ,  Amandine CADIAU ,  Prashant M. BHATT ,  Karim ADIL ,  Youssef BELMABKHOUT

IPC: B01D53/02 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  C07F5/06 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US20180264394A1

公开(公告)日：2018-09-20

申请号：US15770808

申请日：2016-10-26

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja MOHIDEEN ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Prashant M. BHATT

IPC: B01D53/047 ,  B01J20/22 ,  B01J20/28

CPC classification number: B01D53/047 ,  B01D53/02 ,  B01D53/0462 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/504 ,  B01J20/226 ,  B01J20/2808 ,  B01J20/3085 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/847 ,  C07C45/78 ,  Y02C10/08 ,  Y02E50/346

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

公开(公告)号：US20180093250A1

公开(公告)日：2018-04-05

申请号：US15564909

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed EDDAOUDI ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Osama SHEKHAH ,  Prashant M. BHATT ,  Amandine CADIAU

IPC: B01J20/22 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01D2253/204 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2258/05 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/2808 ,  B01J20/3078 ,  B01J20/3085 ,  C07D241/10 ,  C07F19/005 ,  Y02C10/08 ,  Y02P20/152

Abstract: Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US20200306685A1

公开(公告)日：2020-10-01

申请号：US16903820

申请日：2020-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja MOHIDEEN ,  Karim ADIL ,  Youssef BELMABKHOUT ,  Mohamed EDDAOUDI ,  Prashant M. BHATT

IPC: B01D53/047 ,  B01J20/28 ,  B01J20/22 ,  B01J20/30 ,  C07C45/78 ,  B01D53/02

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.