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1.发明申请公开(公告)号：US20100280295A1
公开(公告)日：2010-11-04
申请号：US12678774
申请日：2008-09-18
申请人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
发明人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
IPC分类号： C07C5/03
摘要： The present invention relates to a process for the hydrogenation, in particular selective hydrogenation of at least one unsaturated hydrocarbon compound comprising reacting the at least one unsaturated hydrocarbon compound with hydrogen in the presence of a hydrogenation catalyst, wherein the hydrogenation catalyst comprises a mixture of an ordered intermetallic compound and an inert material. According to another aspect, the present invention is concerned with the use of a mixture of at least one ordered intermetallic compound and at least one inert material, as a catalyst. The mixtures for use as a catalyst in the present invention can be prepared easily and achieve a superior activity in relation to the prior art, while preserving the high selectivity to the target compounds, e.g. in the selective hydrogenation of acetylene to ethylene.
摘要翻译： 本发明涉及一种用于氢化，特别是至少一种不饱和烃化合物的选择性氢化的方法，包括在氢化催化剂存在下使至少一种不饱和烃化合物与氢反应，其中氢化催化剂包括 有序金属间化合物和惰性材料。 根据另一方面，本发明涉及使用至少一种有序金属间化合物和至少一种惰性材料的混合物作为催化剂。 在本发明中用作催化剂的混合物可以容易地制备并且相对于现有技术获得优异的活性，同时保持对目标化合物的高选择性。 在乙炔选择性氢化成乙烯。
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2.发明申请Methods of Preparing, Optionally Supported, Ordered Intermetallic Palladium Gallium Compounds, the Compounds, as such, and Their Use in Catalysis 审中-公开制备任选支持的有序金属间化合物钯化合物的方法，化合物，以及它们在催化中的应用公开(公告)号：US20100261939A1
公开(公告)日：2010-10-14
申请号：US12742488
申请日：2008-10-29
申请人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
发明人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
CPC分类号： B01J23/62 , B01J21/04 , B01J21/08 , B01J35/0013 , B01J37/0201 , B01J37/16 , C07C5/09 , C07C7/167 , C07C2521/18 , C07C2523/08 , C07C2523/44 , C22C1/00 , Y02P20/52 , C07C11/04
摘要： The present invention pertains to methods of preparing optionally supported, ordered intermetallic palladium gallium compounds, and the corresponding, optionally supported, intermetallic palladium gallium compounds obtainable by these methods. The present invention also pertains to the use of the optionally supported ordered intermetallic palladium gallium compounds as catalysts, such as in selective hydrogenations of alkynes, in particular ethyne, to give the corresponding alkenes. The optionally supported, ordered intermetallic palladium gallium compounds were found to be highly active and selective catalysts in the above hydrogenation reactions.
摘要翻译： 本发明涉及制备任选负载的有序金属间钯镓化合物的方法，以及通过这些方法获得的相应的任选负载的金属间钯钯化合物的方法。 本发明还涉及使用任选支持的有序金属间钯镓化合物作为催化剂，例如在炔的选择性氢化，特别是乙炔中，得到相应的烯烃。 在上述氢化反应中，发现任选负载的有序金属间钯镓化合物是高活性和选择性的催化剂。
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3.发明授权Use of a mixture of an ordered intermetallic compound and an inert material as a catalyst and corresponding hydrogenation processes 有权使用有序金属间化合物和惰性材料的混合物作为催化剂和相应的氢化方法公开(公告)号：US08519207B2
公开(公告)日：2013-08-27
申请号：US12678774
申请日：2008-09-18
申请人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
发明人： Marc Armbruester , Marcus Schmidt , Kirill Kovnir , Matthias Friedrich , Karina Weinhold , Juri Grin , Robert Schloegl
摘要： The present invention relates to a process for the hydrogenation, in particular selective hydrogenation of at least one unsaturated hydrocarbon compound comprising reacting the at least one unsaturated hydrocarbon compound with hydrogen in the presence of a hydrogenation catalyst, wherein the hydrogenation catalyst comprises a mixture of an ordered intermetallic compound and an inert material. According to another aspect, the present invention is concerned with the use of a mixture of at least one ordered intermetallic compound and at least one inert material, as a catalyst. The mixtures for use as a catalyst in the present invention can be prepared easily and achieve a superior activity in relation to the prior art, while preserving the high selectivity to the target compounds, e.g. in the selective hydrogenation of acetylene to ethylene.
摘要翻译： 本发明涉及一种用于氢化，特别是至少一种不饱和烃化合物的选择性氢化的方法，包括在氢化催化剂存在下使至少一种不饱和烃化合物与氢反应，其中氢化催化剂包括 有序金属间化合物和惰性材料。 根据另一方面，本发明涉及使用至少一种有序金属间化合物和至少一种惰性材料的混合物作为催化剂。 在本发明中用作催化剂的混合物可以容易地制备并且相对于现有技术获得优异的活性，同时保持对目标化合物的高选择性。 在乙炔选择性氢化成乙烯。
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