公开(公告)号：US08029929B2

公开(公告)日：2011-10-04

申请号：US11630259

申请日：2005-06-20

申请人： Munetoshi Yamaguchi ,  Shinya Kagei ,  Yoshimi Hata

发明人： Munetoshi Yamaguchi ,  Shinya Kagei ,  Yoshimi Hata

IPC分类号： H01M4/50

CPC分类号： H01M4/131 ,  H01M4/502 ,  H01M2004/028

摘要： A positive electrode active material for a lithium battery is provided which offers high-temperature storage property and battery properties and comprises manganese dioxide having a crystal structure that exhibits an X-ray diffraction pattern in which peaks having a peak intensity ratio of not less than 0.05 with respect to the peak at 2θ=37.3°±0.5° are present at positions of 2θ=18.2°±0.5°, 19.5°±0.5°, 28.6°±0.5°, 56.6°±0.5°, 59.1°±0.5°, and 65.1°±0.5°, or further at 2θ=22.0°±1.0°, the X-ray diffraction pattern being obtained using a powder X-ray diffraction device (XRD) that uses CuKα1 rays.

摘要翻译： 提供了一种锂电池用正极活性物质，其具有高温保存性和电池性，并且具有具有X射线衍射图案的晶体结构的二氧化锰，其峰强度比不小于0.05 相对于2θ处的峰值; = 37.3°±0.5°存在于2°的位置; = 18.2°±0.5°，19.5°±0.5°，28.6°±0.5°，56.6°±0.5°，59.1°±0.5° °和65.1°±0.5°，或进一步在2θ= 22.0°±1.0°，使用CuKα1射线的粉末X射线衍射装置（XRD）获得X射线衍射图。

公开(公告)号：US20080032198A1

公开(公告)日：2008-02-07

申请号：US11630259

申请日：2005-06-20

申请人： Munetoshi Yamaguchi ,  Shinya Kagei ,  Yoshimi Hata

发明人： Munetoshi Yamaguchi ,  Shinya Kagei ,  Yoshimi Hata

IPC分类号： H01M4/50

CPC分类号： H01M4/131 ,  H01M4/502 ,  H01M2004/028

摘要： A positive electrode active material for a lithium battery is provided which offers high-temperature storage property and battery properties and comprises manganese dioxide having a crystal structure that exhibits an X-ray diffraction pattern in which peaks having a peak intensity ratio of not less than 0.05 with respect to the peak at 2θ=37.3°±0.5° are present at positions of 2θ=18.2°±0.5°, 19.5°±0.5°, 28.6°±0.5°, 56.6°±0.5°, 59.1°±0.5°, and 65.1°±0.5°, or further at 2θ=22.0°±1.0°, the X-ray diffraction pattern being obtained using a powder X-ray diffraction device (XRD) that uses CuKα1 rays.

摘要翻译： 提供了一种锂电池用正极活性物质，其具有高温保存性和电池性，并且具有具有X射线衍射图案的晶体结构的二氧化锰，其峰强度比不小于0.05的峰 在2θ= 18.2°±0.5°，19.5°±0.5°，28.6°±0.5°，56.6°±0.5°，59.1°±0.5°的位置存在相对于2θ= 37.3°±0.5°处的峰值。 和65.1°±0.5°，或进一步在2θ= 22.0°±1.0°，使用CuKalpha1射线的粉末X射线衍射装置（XRD）获得X射线衍射图。

公开(公告)号：US20050233215A1

公开(公告)日：2005-10-20

申请号：US10530889

申请日：2003-03-06

申请人： Munetoshi Yamaguchi ,  Yasuhiro Ochi ,  Oichi Numata ,  Shigeo Hirayama

发明人： Munetoshi Yamaguchi ,  Yasuhiro Ochi ,  Oichi Numata ,  Shigeo Hirayama

IPC分类号： C25B1/21 ,  H01M4/02 ,  H01M4/04 ,  H01M4/50 ,  H01M10/24 ,  C01G45/02

CPC分类号： H01M4/0452 ,  C25B1/21 ,  H01M4/02 ,  H01M4/0438 ,  H01M4/50 ,  H01M10/24 ,  H01M2004/021

摘要： A positive electrode active material for battery consisting of electrolytic manganese dioxide and a battery wherein this positive electrode active material is used, this electrolytic manganese dioxide being such that, when it is heated and the weight loss thereof is measured, the weight loss at 200° C. to 400° C. is not less than 2.7 wt %. The amount of weight lost in this temperature range is proportional to the quantity of bound waters inside the electrolytic manganese dioxide.

摘要翻译： 一种由电解二氧化锰组成的电池用正极活性物质和使用该正极活性物质的电池，该电解二氧化锰在被加热并测定其重量损失时为200度时的重量损失 至400℃不小于2.7重量％。 在该温度范围内损失的重量与电解二氧化锰内的结合水量成比例。

公开(公告)号：US6123911A

公开(公告)日：2000-09-26

申请号：US150188

申请日：1998-09-10

申请人： Munetoshi Yamaguchi ,  Koichi Numata

发明人： Munetoshi Yamaguchi ,  Koichi Numata

IPC分类号： C01G45/00 ,  C01G45/02 ,  C01G45/12 ,  H01M4/505 ,  H01M4/50

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1242 ,  C01P2006/11 ,  C01P2006/40 ,  H01M10/0525 ,  Y02P70/54

摘要： A process for producing a lithium manganate for lithium secondary batteries comprising mixing a manganese compound and a lithium compound, firing the mixture at 1000 to 1500.degree. C., mixing the resulting complex oxide with a lithium compound, and firing the mixture at 600 to 800.degree. C.

摘要翻译： 一种锂二次电池用锰酸锂的制造方法，其特征在于，将锰化合物和锂化合物混合，将该混合物在1000〜1500℃下烧结，将所得的复合氧化物与锂化合物混合，在600〜800℃下烧成该混合物 DEG C.

公开(公告)号：US5156933A

公开(公告)日：1992-10-20

申请号：US684169

申请日：1991-04-11

申请人： Munetoshi Yamaguchi ,  Yoshinobu Nakamura ,  Hirohisa Senzaki

发明人： Munetoshi Yamaguchi ,  Yoshinobu Nakamura ,  Hirohisa Senzaki

IPC分类号： C25B1/21 ,  H01M4/02 ,  H01M4/06 ,  H01M4/08 ,  H01M4/50

CPC分类号： H01M4/131 ,  C25B1/21 ,  H01M4/485 ,  H01M4/505

摘要： A method of manufacturing manganese dioxide containing 0.05 to 2.0 parts by weight of phosphorus which consists of introducing a manganese sulfate solution and sulfuric acid as an electrolyte into an electrolytic cell, adding to said electrolyte at least one member selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid and compounds thereof and carrying out the electrolysis at a bath temperature of 92.degree. to 100.degree. C. whereby manganese dioxide containing phosphorus is electrodeposited on the cathode.

公开(公告)号：US20060019165A1

公开(公告)日：2006-01-26

申请号：US10496768

申请日：2003-05-22

申请人： Munetoshi Yamaguchi ,  Naoki Kumada ,  Tsuyoshi Nagaishi ,  Yasuhiro Ochi ,  Takeshi Asanuma ,  Koichi Numata ,  Shigeo Hirayama

发明人： Munetoshi Yamaguchi ,  Naoki Kumada ,  Tsuyoshi Nagaishi ,  Yasuhiro Ochi ,  Takeshi Asanuma ,  Koichi Numata ,  Shigeo Hirayama

IPC分类号： H01M4/50 ,  C25B1/21

CPC分类号： H01M4/364 ,  C25D9/06 ,  H01M4/06 ,  H01M4/50 ,  H01M6/04 ,  H01M6/16 ,  H01M2004/028

摘要： A positive electrode active material for a battery, consisting essentially of manganese dioxide, contains 5 to 400 ppm of magnesium or 0.001 to 3.0% by weight of titanium, thereby achieving even higher performance of a battery, such as enhanced pulse characteristics.

摘要翻译： 用于电池的正极活性物质基本上由二氧化锰组成，含有5〜400ppm的镁或0.001〜3.0重量％的钛，从而实现更高的电池性能，例如增强的脉冲特性。