公开(公告)号：US4420415A

公开(公告)日：1983-12-13

申请号：US294930

申请日：1981-08-21

申请人： Nakaji Yuki ,  Hiroshi Kitagawa

发明人： Nakaji Yuki ,  Hiroshi Kitagawa

IPC分类号： C01B32/384 ,  B01J20/20 ,  C01B13/02 ,  C01B21/04 ,  C01B37/00 ,  C01B31/08 ,  B01D53/02

CPC分类号： B01J20/20

摘要： Carbon molecular sieves having excellent oxygen adsorption properties may be obtained from a vinylidene chloride copolymer. The copolymer is carbonized for the removal of its chlorine components and the resulting char is pulverized. Specific amounts of a carbonaceous sintering agent such as coal tar pitch and an organic binder such as microcrystalline cellulose are then added to the pulverized product and the mixture is shaped into pellets. By thermally treating the pellets under specific conditions in a specific manner, carbon molecular sieves having pore diameters suitable for the adsorption of oxygen may be obtained. The molecular sieves are suitable for concentrating nitrogen in air.

摘要翻译： 可以从偏二氯乙烯共聚物获得具有优异氧吸附性能的碳分子筛。 将共聚物碳化以除去其氯组分，并将所得炭粉碎。 然后将特定量的碳焦烧结剂如煤焦油沥青和有机粘合剂如微晶纤维素加入到粉碎产物中，并将混合物成型为颗粒。 通过以特定方式在特定条件下热处理颗粒，可以获得具有适于吸附氧气的孔径的碳分子筛。 分子筛适用于将氮气浓缩在空气中。

公开(公告)号：US4046709A

公开(公告)日：1977-09-06

申请号：US561164

申请日：1975-03-24

申请人： Nakaji Yuki

发明人： Nakaji Yuki

IPC分类号： C01B31/14 ,  B01J20/20 ,  B01J29/03 ,  C01B31/08 ,  C01B37/00 ,  B01J37/00 ,  B01J21/18 ,  C01B31/00

CPC分类号： C01B31/085

摘要： Granular molecular sieve may be obtained, without necessitating any activng treatment, by subjecting a vinylidene chloride copolymer to a thermal carbonization treatment for removal of hydrochloric acid, pulverizing the resultant product to a grain size smaller than 100 mesh size, adding 15 to 35 parts by weight of a carbonaceous sintering agent and 8 to 15 parts by weight of an organic pelletizer capable of gas generation by heating to 100 parts by weight of the pulverized product, pelletizing the resultant mixture and carbonizing the resultant pellets at a temperature of 400 to 900.degree. C for a period of 2 to 6 hours. The pore diameter of this molecular sieve can be suitably controlled within a range of from 5 to 10 A by appropriately selecting the sintering agent and pelletizer employed and the conditions of the thermal treatment.

摘要翻译： 可以通过使偏二氯乙烯共聚物进行热碳化处理除去盐酸，将所得产物粉碎成小于100目尺寸的粒度，加入15〜35份的方法，得到粒状分子筛，而不需要任何活化处理 碳质烧结剂的重量和8〜15重量份能够通过加热至100重量份粉碎产物而产生气体的有机造粒机，造粒所得混合物并在400-900℃的温度下碳化所得颗粒。 C 2至6小时。 通过适当选择所使用的烧结剂和造粒机以及热处理条件，可以将该分子筛的孔径适当地控制在5〜10A的范围内。

公开(公告)号：US4490160A

公开(公告)日：1984-12-25

申请号：US529740

申请日：1983-09-06

申请人： Nakaji Yuki ,  Hiroshi Kitagawa

发明人： Nakaji Yuki ,  Hiroshi Kitagawa

IPC分类号： C01B31/02 ,  B01D53/02 ,  B01J20/20 ,  C01B13/02 ,  C01B21/04 ,  C01B31/08 ,  C01B31/14 ,  B01D53/04

CPC分类号： B01J20/20 ,  B01D53/02 ,  Y10S95/90

摘要： The invention provides an improvement in the method for the enrichment of nitrogen in air by the method of selective adsorption of oxygen in air on a carbonaceous adsorbent material. The improvement comprises the use of an adsorbent material prepared in a specific manner in which a pulverized coal char is blended with a limited amount of a sulfite pulp waste liquor and the blend is shaped into granules or pellets followed by carbonization at 300.degree. to 450.degree. C. for 1 to 2 hours. An enriched nitrogen gas containing 1% by volume or less of oxygen can readily be obtained by passing air through a column filled with the adsorbent material.

摘要翻译： 本发明通过在碳质吸附剂材料上选择性吸附空气中的氧气的方法提供了在空气中富集氮气的方法的改进。 该改进包括使用以特定方式制备的吸附剂材料，其中将粉煤炭与有限量的亚硫酸盐纸浆废液混合，并将共混物成型为颗粒或颗粒，然后在300-450℃碳化 C. 1至2小时。 通过使空气通过填充有吸附材料的柱，可以容易地获得含有1体积％以下的氧的富氮气。

公开(公告)号：US4067894A

公开(公告)日：1978-01-10

申请号：US666054

申请日：1976-03-11

申请人： Nakaji Yuki ,  Akio Yauchi

发明人： Nakaji Yuki ,  Akio Yauchi

IPC分类号： B01D53/02 ,  B01J20/12 ,  B01J20/20 ,  C02F1/28 ,  B01J21/16

CPC分类号： B01J20/20 ,  B01D53/02 ,  C02F1/283

摘要： Granular metal-capturing agents suitable for treating waste effluents conning heavy metals are obtained by mixing 100 parts by weight of waste clay which has been subjected to a preliminary dry distillation treatment with 25-40 parts by weight of an organic carbonaceous binder agent such as coking coal, granulating 100 parts by weight of this mixture together with 8-15 parts by weight of an organic pelletizing agent such as sulfite pulp waste liquor, and thereafter subjecting the resulting granules to a dry distillation treatment conducted at 450.degree.-900.degree. C.

摘要翻译： 适用于处理含有重金属的废水的颗粒状金属捕获剂通过将100重量份已经进行预干燥处理的废土与25-40重量份的有机碳质粘合剂如焦化混合而获得 煤，将该混合物100重量份与8-15重量份的有机造粒剂如亚硫酸盐纸浆废液一起制粒，然后在450-900℃下进行干燥处理。