公开(公告)号：US4975301A

公开(公告)日：1990-12-04

申请号：US288852

申请日：1988-12-23

申请人： Ray Andrews ,  James W. Kridler

发明人： Ray Andrews ,  James W. Kridler

IPC分类号： C03C8/18 ,  C03C17/34

CPC分类号： C03C8/18 ,  C03C17/007 ,  C03C17/3411 ,  C03C17/3642 ,  C03C17/3673 ,  C03C8/12 ,  C03C8/14 ,  C03C8/16 ,  C03C8/22 ,  C03C2217/452 ,  C03C2217/479 ,  C03C2217/485

摘要： A method of decorating a glass substrate that has conductive coating applied thereto as electrically resistive heating elements comprises applying to said glass substrate a glass enamel composition comprising 5 to 25 percent by weight glass coloring agents, 1 to 25 percent by weight of a metal that will be resistant to rapid oxidation under the conditions in which the glass enamel is fired, and the remainder a soda free flux glass. The conductive coating composition is next applied and comprises finely divided conductive noble metals including silver, and a glass binder. The glass enamel composition and the conductive coating composition are fired onto the substrate. The glass enamel and conductive coating do not visibly react and the conductive coating cannot be seen through the glass enamel.

摘要翻译： 将作为电阻加热元件涂覆有导电涂层的玻璃基板的装饰方法包括向所述玻璃基板施加包含5至25重量％的玻璃着色剂，1至25重量％的金属的玻璃搪瓷组合物， 在玻璃搪瓷烧成的条件下耐快速氧化，其余为无苏打的助熔玻璃。 接着涂覆导电涂料组合物，并且包括细分的包含银的导电贵金属和玻璃粘合剂。 将玻璃搪瓷组合物和导电涂料组合物烧制到基材上。 玻璃搪瓷和导电涂层不会明显反应，导电涂层不能通过玻璃搪瓷看到。

公开(公告)号：US4837383A

公开(公告)日：1989-06-06

申请号：US255383

申请日：1988-10-11

申请人： Ray Andrews

发明人： Ray Andrews

IPC分类号： C03C17/34

CPC分类号： C03C17/34 ,  C03C2217/452 ,  C03C2217/479

摘要： A glass enamel composition that may be fired upon a glass substrate to paint an opaques ceramic color. The glass enamel composition is of special utility in the formation of back windows of automobiles in which an electrically conductive heating grid is also to be formed. The glass enamel composition is comprised of lead or lead-free glass flux material, pigment, a printing vehicle, and a aluminum and/or lithium oxide. The aluminum and/or lithium oxide prevents sliding of the ceramic color to fibrous mold surfaces during hot forming the glass substrate. The aluminum and/or lithium oxide functions a migration preventor to prevent the migration of ions of the electrically conductive material to the glass which would, in the absence of the migration preventor, stain the glass.

摘要翻译： 可以在玻璃基材上烧制以制造不透明陶瓷颜色的玻璃搪瓷组合物。 玻璃搪瓷组合物在形成还要形成导电加热网格的汽车后窗中是特别有用的。 玻璃搪瓷组合物由铅或无铅玻璃助熔剂材料，颜料，印刷载体和铝和/或氧化锂组成。 在热成型玻璃基板期间，铝和/或氧化锂防止陶瓷颜色滑动到纤维模具表面。 铝和/或氧化锂起到迁移防止剂的作用，以防止导电材料的离子迁移到玻璃上，在不存在迁移防护剂的情况下，玻璃会污染玻璃。

公开(公告)号：US4117182A

公开(公告)日：1978-09-26

申请号：US753926

申请日：1976-12-23

申请人： Ray Andrews

发明人： Ray Andrews

IPC分类号： B44C1/16 ,  B41M3/12 ,  B44C1/165 ,  B44C1/17 ,  C03C17/32 ,  C04B41/86 ,  B32B3/00

CPC分类号： B41M3/12 ,  B44C1/172 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24843 ,  Y10T428/24851 ,  Y10T428/2826 ,  Y10T428/2878 ,  Y10T428/2891 ,  Y10T428/31855

摘要： A novel heat release layer for use in connection with decalcomanias which include a vitreous design layer surrounded by a heat release layer and a heat activatable adhesive layer is disclosed. In particular, the novel heat release layer disclosed comprises a normally solid straight chain, primary aliphatic oxyalkylated alcohol which preferably has a molecular weight above about 1350.In addition, methods of preparing such heat release decalcomanias are also disclosed, including applying a heat release layer to a backing sheet, applying a design layer to the heat release layer, and applying a heat activatable adhesive layer to the design layer, again wherein the heat release layer is as described above.A novel combination of heat release layers and heat activatable adhesive layers is also disclosed, including the heat release layer described above in combination with a heat activatable adhesive layer including an acrylic resin and a tackifier for the acrylic resin including a polyethylene glycol and/or a solid polyoxyalkylene derivative of propylene glycol or ethylene diamine, and including an organic solvent therein, as well as the combination of the heat release layer with a heat activatable adhesive layer including a straight chain, primary aliphatic oxyalkylated alcohol, a cellulosic derivative, a plasticizer and an organic solvent.

公开(公告)号：US4303717A

公开(公告)日：1981-12-01

申请号：US68925

申请日：1979-08-23

申请人： Ray Andrews

发明人： Ray Andrews

IPC分类号： B44C1/17 ,  B32B3/00

CPC分类号： B44C1/172 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24843 ,  Y10T428/2817 ,  Y10T428/2822 ,  Y10T428/2826 ,  Y10T428/2839

摘要： A novel heat release layer for use in connection with decalcomania paper and in decalcomanias which include a vitreous design layer surrounded by a heat release layer and a heat activatable adhesive layer is disclosed. In particular, the novel heat release layer disclosed comprises a combination of a normally solid straight chain, primary aliphatic oxyalkylated alcohol with either/or (1) a normally solid polyethylene glycol having an average molecular weight of greater than about 1,000, and (2) an amide of a fatty acid. Preferably, the oxyalkylated alcohol has a molecular weight above about 1350, the polyethylene glycol is present in the heat release layer in an amount of from about 1 to 50 weight percent thereof, and/or the amide of a fatty acid is present in the heat realease layer in an amount of from about 1 to 25 weight percent thereof. In addition, methods of preparing such heat release decalcomanias are also disclosed, including applying a heat release layer to a backing sheet, applying a design layer to the heat release layer, and applying a heat activatable adhesive layer to the design layer, again wherein the heat release layer is as described above. A novel combination of heat release layers and heat activatable adhesive layers is also disclosed, including the heat release layer described above in combination with a heat activatable adhesive layer including an acrylic resin and a tackifier for the acrylic resin, and including an organic solvent therein.

摘要翻译： 公开了一种与脱墨纸和包装玻璃体设计层相连的脱墨纸和热可活化粘合剂层的新型隔热层。 特别地，所公开的新型放热层包括通常为固体的直链，伯脂肪族烷氧基化醇与（1）平均分子量大于约1,000的通常为固体的聚乙二醇的组合，和（2） 脂肪酸的酰胺。 优选地，烷氧基化醇的分子量高于约1350，聚乙二醇以约1-50重量％的量存在于放热层中，和/或在热量中存在脂肪酸的酰胺 其量为约1至25重量％。 此外，还公开了制备这种放热脱脂剂的方法，包括将热释放层施加到背衬片上，将设计层施加到散热层，以及将热可活化粘合剂层施加到设计层，其中， 散热层如上所述。 还公开了热释放层和可热活化的粘合剂层的新颖组合，包括上述散热层与包含丙烯酸树脂和丙烯酸树脂增粘剂的可热活化粘合剂层组合，并且其中包含有机溶剂。