公开(公告)号：US20190169376A1

公开(公告)日：2019-06-06

申请号：US16313389

申请日：2017-06-27

Applicant: SABIC Global Technologies B.V.

Inventor： Christopher Luke Hein ,  Franklin Ehrensbeck ,  Brett D. Ermi ,  Bing Zhou ,  Guangxin Lin ,  Roger W. Hurst

IPC: C08J3/22 ,  C08L69/00 ,  C08L27/18 ,  B29C48/27

Abstract: The disclosure concerns compositions and methods to improve remote phosphor optical properties in polycarbonate. One method includes combining a phosphor component and a polycarbonate component to form a phosphor-polycarbonate composition; and at a fixed phosphor concentration, combining the phosphor-polycarbonate composition with a diffusing agent comprising polytetrafluoroethylene (PTFE), wherein the diffusing agent diffuses light, and wherein the phosphor-polycarbonate composition exhibits an increase in chromaticity coordinate (CIEx) as determined by CIE 1931 or increase in CIE 1976 (u′,v′) of at least about 5% relative to a substantially similar reference composition in the absence of PTFE. Also described are methods to increase yield and reduce product accumulation of an extruded thermoplastic polycarbonate composition through the mixing of PTFE with a phosphor-polycarbonate (PCP) to form a PCP-PTFE component as well as a method forming a phosphor-polycarbonate master batch (PPCMB) composition, and during extrusion, adding PTFE to the PPCMB composition to form a PPCMB-PTFE composition.

公开(公告)号：US11001709B2

公开(公告)日：2021-05-11

申请号：US16479787

申请日：2017-05-05

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke Hein ,  Rahul Patil ,  Bing Zhou ,  Guangxin Lin ,  Chelsea Schmidt ,  David Zoller ,  Shuailei Ma ,  Chester Hassman

IPC: C08L69/00 ,  C08G63/64 ,  C08G77/448 ,  C08K5/053 ,  C08K5/08 ,  C08K5/09 ,  C08K5/13 ,  C08L83/10

Abstract: A polycarbonate copolymer contains aromatic carbonate units; optionally siloxane units; and resorcinol arylate ester units. The resorcinol arylate ester units of the polycarbonate copolymer are derived from a resorcinol composition having a hydroquinone content of 50 to 1200 parts per million, a catechol content of 5 to 29 parts per million, and a phenol content of 0 to 2400, each as determined by high performance liquid chromatography, and further comprising an acid stabilizer.

公开(公告)号：US10899875B2

公开(公告)日：2021-01-26

申请号：US16298235

申请日：2019-03-11

Applicant: SABIC Global Technologies B.V.

Inventor： Husnu Alp Alidedeoglu ,  Prashant Kumar ,  Brian Bougher ,  Cornelis Adrianus Maria van Gool ,  Sasi Sethumadhavan Kannamkumarath ,  Bing Zhou

IPC: C08G63/183 ,  C08G63/78

Abstract: A device for making polybutylene terephthalate includes (1) a slurry paste vessel; (2) a tower reactor to which a mixture of 1,4-butane diol and terephthalic acid from vessel (1) is supplied, the tower reactor having a plurality of reactor zones wherein the lower third of the tower reactor is in the form of a hydrocyclone with attached heat exchanger, and the hydrocyclone has a supply line from vessel (1), the hydrocyclone being connected to the top side of the tower reactor; (3) a first continuously stirred tank reactor to which the product from tower reactor (2) is supplied; (4) an optional second continuously stirred tank reactor to which the product from (3) is supplied; (5) a dual shaft ring reactor to which the product from stirred tank reactor (3) or (4), is supplied; and (6) a pelletizer where the product from dual shaft ring reactor (5) is continuously fed and pelletized.

公开(公告)号：US20190263963A1

公开(公告)日：2019-08-29

申请号：US16298235

申请日：2019-03-11

Applicant: SABIC Global Technologies B.V.

Inventor： Husnu Alp Alidedeoglu ,  Prashant Kumar ,  Brian Bougher ,  Cornelis Adrianus Maria van Gool ,  Sasi Sethumadhavan Kannamkumarath ,  Bing Zhou

IPC: C08G63/183 ,  C08G63/78

Abstract: Disclosed is a continuous process and device for making polybutylene terephthalate (PBT) resin, particularly high molecular weight PBT resin. Also disclosed are a device for conducting the process, and a monitoring process for determining the carboxylic acid end group concentration of the resulting PBT.

公开(公告)号：US20170369638A1

公开(公告)日：2017-12-28

申请号：US15542677

申请日：2016-01-29

Applicant: SABIC Global Technologies B.V.

Inventor： Husnu Alp Alidedeoglu ,  Prashant Kumar ,  Brian Bougher ,  Cornelis Adrianus Maria van Gool ,  Sasi Sethumadhavan Kannamkumarath ,  Bing Zhou

IPC: C08G63/183 ,  C08G63/78

CPC classification number: C08G63/183 ,  B01J2219/00006 ,  C08G63/785

Abstract: Disclosed is a continuous process and device for making polybutylene terephthalate (PBT) resin, particularly high molecular weight PBT resin. Also disclosed are a device for conducting the process, and a monitoring process for determining the carboxylic acid end group concentration of the resulting PBT.

公开(公告)号：US20200308414A1

公开(公告)日：2020-10-01

申请号：US16651589

申请日：2018-12-21

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke Hein ,  Bing Zhou ,  Robert Russell Gallucci

IPC: C09C3/12 ,  C08K9/08 ,  C08K3/22 ,  C08K3/105 ,  C09C1/00

Abstract: A thermoplastic composition comprising: a polymer material; and a passivated inorganic chromophore comprising an inorganic chromophore and a passivation layer, wherein the inorganic chromophore has the formula: AM1-xM?xM?yO3+y, wherein A, M, M?, M?, x, and y are as provided herein, and wherein the passivation layer is derived from a passivation material comprising a polysiloxane having at least one functional group that is hydride, hydroxy, alkoxy, aryloxy, epoxy, carboxy, amino, or a combination thereof.

公开(公告)号：US10655001B2

公开(公告)日：2020-05-19

申请号：US16659692

申请日：2019-10-22

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Christopher Luke Hein ,  Hao Zhou ,  Bing Zhou ,  Manojkumar Chellamuthu ,  Peter Vollenberg

IPC: C08L33/12 ,  C08L69/00 ,  C08L83/10

Abstract: A thermoplastic composition includes: from about 5 wt % to about 70 wt % poly(methyl methacrylate) (PMMA); from about 15 wt % to about 50 wt % of a first poly(carbonate-siloxane) copolymer having a siloxane content of from about 35 wt % to about 45 wt %; and from about 10 wt % to about 45 wt % of a second poly(carbonate-siloxane) copolymer. The second poly(carbonate-siloxane) copolymer has a siloxane content of from about 15 wt % to about 25 wt % or from about 4 wt % to about 8 wt %.

公开(公告)号：US10344119B2

公开(公告)日：2019-07-09

申请号：US15542677

申请日：2016-01-29

Applicant: SABIC Global Technologies B.V.

Inventor： Husnu Alp Alidedeoglu ,  Prashant Kumar ,  Brian Bougher ,  Cornelis Adrianus Maria van Gool ,  Sasi Sethumadhavan Kannamkumarath ,  Bing Zhou

IPC: C08G63/183 ,  C08G63/78 ,  B01J19/00

Abstract: Disclosed is a continuous process and device for making polybutylene terephthalate (PBT) resin, particularly high molecular weight PBT resin. The process includes combining 1,4-butane diol and purified terephthalic acid to form a mixture and continuously supplying the mixture to a tower reactor having a plurality of reactor zones for esterification and/or transesterification. The product is continuously supplied to a first continuously stirred tank reactor, and further to a continuous polycondensation reactor. Particular conditions for each step of the process are further described herein. Also disclosed are a device for conducting the process, and a monitoring process for determining the carboxylic acid end group concentration of the resulting PBT.