公开(公告)号：US20210040021A1

公开(公告)日：2021-02-11

申请号：US17046037

申请日：2019-06-03

Applicant: SHOWA DENKO K.K.

Inventor： Yohsuke FUKUCHI ,  Shinya OGURO ,  Nozomi INOUE

IPC: C07C17/23

Abstract: Provided is a method for producing hexafluoro-1,3-butadiene, and the method can produce hexafluoro-1,3-butadiene at an industrially sufficient level of yield. In a reaction liquid containing a halogenated butane represented by chemical formula, CF2X1—CFX2—CFX3—CF2X4 (X1, X2, X3, and X4 are each independently a halogen atom other than a fluorine atom), zinc, and an organic solvent, a reaction is conducted to eliminate the halogen atoms other than a fluorine atom, X1, X2, X3, and X4, from the halogenated butane, yielding hexafluoro-1,3-butadiene. During the reaction, the concentration of a zinc halide generated by the reaction, in the reaction liquid is not more than the solubility of the zinc halide in the organic solvent.

公开(公告)号：US20200095132A1

公开(公告)日：2020-03-26

申请号：US16612480

申请日：2018-04-25

Applicant: SHOWA DENKO K.K.

Inventor： Yohsuke FUKUCHI ,  Atsushi NAKAMURA ,  Nozomi INOUE ,  Mitsuhiro HINO ,  Tomoki SEKIGUCHI

IPC: C01G9/04

Abstract: Provided is a method for producing a highly pure aqueous solution of zinc halide from a mixture containing a zinc halide. The method for producing an aqueous solution of zinc halide includes an addition step of adding water and a hydrogen halide to a mixture containing an alcohol having a carbon number of 3 or less, a zinc halide, and zinc to give a liquid mixture, and a distillation step of distilling the liquid mixture to remove the alcohol having a carbon number of 3 or less from the liquid mixture, giving an aqueous solution of zinc halide.

公开(公告)号：US20210332487A1

公开(公告)日：2021-10-28

申请号：US16624938

申请日：2018-06-26

Applicant: SHOWA DENKO K.K.

Inventor： Yohsuke FUKUCHI ,  Nozomi INOUE ,  Hiroshi KOBAYASHI

IPC: C25B9/63 ,  C25B1/245 ,  C25B15/08 ,  C25B9/17 ,  C25B1/02

Abstract: An anode mounting member (16) of a fluorine electrolytic cell including: a plurality of stacked annular packings surrounding a sidewall of a cylindrical anode packing gland (14); a cylindrical exterior member (23) surrounding an outer periphery of the packings; and an annular fastening member (24) that fastens the plurality of packings and the exterior member (23) to the anode packing gland (14), wherein among the packings a first ceramic packing (17) is located at an end of the longitudinal direction on an electrolyte tank side, and a second resin packing (18) is adjacent to the first packing (17), central axes of the anode packing gland (14) and the exterior member (23) coincide, an inner diameter (17r) is 0.2 mm to 1.0 mm larger than an outer diameter (14R), and an outer diameter (17R) is 0.2 mm to 1.0 mm smaller than an inner diameter (23r).

公开(公告)号：US20210163382A1

公开(公告)日：2021-06-03

申请号：US16611879

申请日：2018-04-25

Applicant: SHOWA DENKO K.K.

Inventor： Yohsuke FUKUCHI ,  Atsushi NAKAMURA ,  Nozomi INOUE ,  Mitsuhiro HINO ,  Tomoki SEKIGUCHI

IPC: C07C17/23 ,  C07C17/383

Abstract: Provided is a method that is for producing hexafluoro-1,3-butadiene, discharges small amounts of industrial wastes, and is industrially applicable. The method for producing hexafluoro-1,3-butadiene includes a reaction step of reacting a halogenated butane represented by chemical formula, CF2X1-CFX2-CFX3-CF2X4 (X1, X2, X3, and X4 are each independently a halogen atom other than a fluorine atom) in an organic solvent in the presence of zinc to eliminate the halogen atoms, X1, X2, X3, and X4, other than the fluorine atoms to generate hexafluoro-1,3-butadiene, giving a reaction product containing the hexafluoro-1,3-butadiene, and an aftertreatment step of separating the hexafluoro-1,3-butadiene from the reaction product produced in the reaction step, then adding water to a reaction product residue after the separating, and removing the organic solvent, giving an aqueous solution of zinc halide.