Abstract:
A polymeric compound having a backbone structure including an addition product of a (meth)acrylate compound and a nucleophile of a cobalt porphyrin complex including a tetraphenylporphyrin derivative represented by Formula 1 coordinated to a cobalt metal, wherein substituents R1 to R4 are as described in the specification, an oxygen permeable membrane including the polymeric compound, and an electrochemical device including the oxygen permeable membrane.
Abstract:
A cathode for use in an electrochemical device, the cathode including a polymer including a backbone, including a polyalkyleneimine-cobalt complex (PEI-Co complex), wherein polyalkyleneimine is coordinated to cobalt; and an electrode material effective for an oxidation-reduction reaction of oxygen, wherein oxygen is a cathode active material.
Abstract:
A polymeric compound including a cross-linked backbone which is a product of a reaction between a multifunctional acrylate compound and a metal porphyrin derivative, wherein the metal porphyrin derivative has a first axial position and a second axial position, and further includes a basic coordination ligand coordinated at the first axial position of the metal porphyrin derivative.
Abstract:
An electrochemical device including: a positive electrode including oxygen as a positive active material; a negative electrode including a lithium ion-intercalatable/deintercalatable material as a negative active material; and an electrolytic solution in fluid communication with the positive electrode and the negative electrode and including a solvent and an oxygen absorbing/desorbing material with an oxygen binding rate of about 60 to about 95% in a pure oxygen atmosphere.