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公开(公告)号：US5250396A
公开(公告)日：1993-10-05
申请号：US954411
申请日：1992-09-30
CPC分类号： G03C7/44
摘要： A method of continuously processing an imagewise exposed silver halide photographic material using an automatic processor which has a color development bath, comprising the steps of a) developing with a color developer containing an organic preservative, and b) adding to the color developer during the continuous processing (i) a replenisher for the color developer containing a development agent and other components for the development in an amount of from 20 ml to 600 ml per m.sup.2 of the photographic material processed, and (ii) a water solution in an amount of from 0.1 to 1.2 times the amount of the developer which has evaporated from the bath at a frequency of about once per week or more often.
摘要翻译： 使用具有显色浴的自动处理器连续处理成像曝光的卤化银照相材料的方法，包括以下步骤：a）用含有机防腐剂的彩色显影剂显影，和b）在连续的期间向彩色显影剂添加 处理（i）含有显影剂的显影剂和其它用于显影的成分的补充剂，其量为每毫升加工的照相材料为20ml至600ml，和（ii）水溶液的量为 以每周约一次或更频繁地从浴中蒸发的显影剂的量的0.1至1.2倍。
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公开(公告)号：US4956267A
公开(公告)日：1990-09-11
申请号：US200268
申请日：1988-05-31
申请人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
发明人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
CPC分类号： G03C7/413 , G03C1/48538
摘要： A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.
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公开(公告)号：US5071734A
公开(公告)日：1991-12-10
申请号：US413652
申请日：1989-09-28
CPC分类号： G03C7/407 , Y10S430/164
摘要： A method for continuously processing silver halide color photographic materials using a roller conveyor type of an automatic developing apparatus, comprising:cleaning the entire surface of a roller located over solution surface of at least one of processing baths in the automatic developing apparatus in which at least one of said processing baths comprises the color developing bath by a rinsing water replenisher or a stabilizing replenisher as a substitute for the rinsing water replenisher, andintroducing the cleaning solution into the color developing bath containing at least one organic preservative selected from the group consisting of compounds represented by formulae (I), (II), (III) and (IV) and monosaccharides; ##STR1## wherein R.sup.11 and R.sup.12 each represents hydrogen atoms, unsubstituted or substituted alkyl groups, unsubstituted or substituted alkenyl groups, unsubstituted or substituted aryl groups or hetero aromatic groups, provided that both of R.sup.11 and R.sup.12 are not hydrogen atoms together; ##STR2## wherein R.sup.21, R.sup.22 and R.sup.23 each represents independently a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sup.24 represents a hydrogen atom, a hydroxyl group, a hydrazino group, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, a carbamoyl group or an amino group; X.sup.21 represents a divalent group and n represents 0 or 1; with the proviso that when n is 0, R.sup.24 represents an alkyl group, an aryl group or a heterocyclic group; ##STR3## wherein R.sup.31, R.sup.32 and R.sup.33 each represents hydrogen atoms, alkyl groups, alkenyl groups, aryl groups, aralkyl groups or heterocyclic groups; ##STR4## wherein X.sup.41 represents a trivalent atomic group needed to complete a condensed ring and R.sup.41 and R.sup.42 each represents alkylene groups, arylene groups, alkenylene groups or aralkylene groups.
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公开(公告)号：US5221597A
公开(公告)日：1993-06-22
申请号：US807612
申请日：1991-12-13
IPC分类号： G03C7/42
CPC分类号： G03C7/42
摘要： Disclosed is a method of processing a silver halide color photographic material where an imagewise exposed silver halide color photographic material is, after color-developed, processed with a bleaching solution contains (1,3-diamino-propanetetraacetato)iron (III) complex and that, when the material is processed with the said processing solution having a fixing ability, a jet stream of the said processing solution is run against the emulsion surface of the said photographic material. By the method, rapid desilvering is possible, and the material processed is not stained.
摘要翻译： 公开了一种处理卤化银彩色照相材料的方法，其中成像曝光的卤化银彩色照相材料在显色后用含有（1,3-二氨基 - 丙四乙酸）铁（III）络合物的漂白溶液处理，并且 当用所述处理溶液处理材料具有定影能力时，所述处理溶液的喷射流抵靠所述照相材料的乳液表面流动。 通过该方法，可以快速脱银，并且处理的材料不被染色。
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公开(公告)号：US4966834A
公开(公告)日：1990-10-30
申请号：US239579
申请日：1988-09-01
申请人： Takatoshi Ishikawa , Shinji Ueda
发明人： Takatoshi Ishikawa , Shinji Ueda
IPC分类号： G03C7/42
CPC分类号： G03C7/42
摘要： A method of processing a silver halide color photographic material by the steps of (a) developing an imagewise exposed silver halide color photographic material with a color developing solution substantially free from sulfite ions; and (b) immediately contacting the developed silver halide color photographic material with a bleach-fixing solution containing at least one of (i) from 1.times.10.sup.-2 mol to 2 mol of bromide ions and (ii) from 5.times.10.sup.-4 mol to 5.times.10.sup.-2 mol of iodide ions per liter.In accordance with the method of the invention, silver removal is fully accomplished and the formation of leuco dye is prevented even in rapid processing. Further, the formation of color stain is also prevented.
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6.发明授权
公开(公告)号：US5194368A
公开(公告)日：1993-03-16
申请号：US427831
申请日：1989-09-06
申请人： Shinji Ueda , Tetsuro Kojima , Tohru Kitahara , Tomokazu Yasuda , Yoshihiro Fujita , Takatoshi Ishikawa
发明人： Shinji Ueda , Tetsuro Kojima , Tohru Kitahara , Tomokazu Yasuda , Yoshihiro Fujita , Takatoshi Ishikawa
CPC分类号： G03C5/3956 , G03C7/42
摘要： The present invention relates to a method for processing a silver halide photographic light-sensitive material having at least one silver halide emulsion layer containing silver iodide with a processing solution having fixing ability after developing the light-sensitive material. The object of the present invention is to speed up the fixing process in the foregoing method and to reduce the amount of waste liquor from the fixing process. The present invention is characterized in that the processing with the processing solution having fixing ability is performed while the processing solution is brought into contact with an anion-exchange resin and that 20 to 2,000 l of the processing solution per liter of the anion-exchange resin is brought into contact with the resin.
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公开(公告)号：US5139929A
公开(公告)日：1992-08-18
申请号：US555016
申请日：1990-07-20
申请人： Takatoshi Ishikawa , Shinji Ueda
发明人： Takatoshi Ishikawa , Shinji Ueda
CPC分类号： G03C7/44
摘要： A method for processing an exposed silver halide color photographic material comprising the steps of:(a) color developing an exposed silver halide color photographic material;(b) bleach-fixing said developed material;(c) at least one of washing said bleach-fixed material with water and stabilizing said bleach-fixed material;(d) regenerating a portion of a solution from said step (b) for bleach-fixing to form a replenisher solution comprising at least a carbonyl bisulfite adduct; and(e) replenishing at least one solution in said bleach-fixing step (b) with said replenisher solution from step (d).
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8.发明授权Method for processing silver halide color photographic light-sensitive materials 失效用于处理银色彩色摄影感光材料的方法
公开(公告)号：US5059514A
公开(公告)日：1991-10-22
申请号：US415266
申请日：1989-08-23
申请人： Shinji Ueda , Tetsuro Kojima , Tohru Kitahara , Tomokazu Yasuda , Yoshihiro Fujita , Takatoshi Ishikawa
发明人： Shinji Ueda , Tetsuro Kojima , Tohru Kitahara , Tomokazu Yasuda , Yoshihiro Fujita , Takatoshi Ishikawa
CPC分类号： G03C7/44 , G03C5/3956 , G03C7/42 , Y10S430/164
摘要： The present invention relates to a method for bleaching a silver halide photographic light-sensitive material having at least one silver halide emulsion layer containing silver iodobromide after color-developing it. The object of the present invention is to speed up the bleaching treatment in the aforesaid method and to reduce the amount of waste liquor from the bleaching treatment. The present invention is characterized in that the bleaching is performed in the presence of a bleaching accelerator and that it is carried out while a bleaching solution is brought into contact with an anion-exchange resin.
摘要翻译： PCT No.PCT / JP88 / 01328 Sec。 371日期1989年8月23日 102（e）日期1989年8月23日PCT提交1988年12月24日PCT公布。 公开号WO89 / 06380 日本1987年7月13日。本发明涉及一种漂白卤化银照相感光材料的方法，该方法在显色后含有至少一种含有碘溴化银的卤化银乳剂层。 本发明的目的是加速上述方法的漂白处理，并减少漂白处理废液的量。 本发明的特征在于漂白在漂白促进剂的存在下进行，并且在漂白溶液与阴离子交换树脂接触的同时进行。
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公开(公告)号：US5534394A
公开(公告)日：1996-07-09
申请号：US331876
申请日：1994-11-01
IPC分类号： G03C7/42
CPC分类号： G03C7/421
摘要： A method for processing a silver halide color photographic material with which edge staining and the occurrence of staining on aging after processing can be prevented, and with which the stability of the bleach-fixer can be improved, comprising color developing and bleach-fixing the photographic material, wherein the bleach-fixer contains (1) thiosulfate, (2) at least one type of compound selected from among the group of compounds represented by formulae (I) and (II): ##STR1## wherein Ra, Rb, R.sup.1 through R.sup.4, X.sup.1 and n are as defined in the specification, and (3) an adduct of bisulfite with at least one type of compound selected from among the group of compounds represented by formulae (A), (B), (C) and (D): ##STR2## wherein R.sub.1 through R.sub.11, X, Y, Z, m and n are as defined in the specification.
摘要翻译： 一种用于处理卤化银彩色照相材料的方法，可以防止边缘染色和加工后的老化现象的发生，并且可以改善漂白定影剂的稳定性，包括彩色显影和漂白固定摄影 材料，其中漂白剂定影剂含有（1）硫代硫酸盐，（2）选自由式（I）和（II）表示的化合物组中的至少一种类型的化合物：（I）＆lt; IMAGE＆gt; II）其中Ra，Rb，R1至R4，X1和n如说明书中所定义，和（3）亚硫酸氢盐与至少一种选自式（A）， （B），（C）和（D）：其中R1至R11，X，Y，Z，m和n如说明书中所定义。
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公开(公告)号：US4963474A
公开(公告)日：1990-10-16
申请号：US309588
申请日：1989-02-13
申请人： Yoshihiro Fujita , Shinji Ueda , Takatoshi Ishikawa , Akira Abe
发明人： Yoshihiro Fujita , Shinji Ueda , Takatoshi Ishikawa , Akira Abe
IPC分类号： G03C7/42
CPC分类号： G03C7/42
摘要： A method of processing a silver halide color photographic material in which the material is, after color-developed, processed in a bath having bleaching ability and then in a bath having fixing ability, wherein a bleaching agent in the bath having bleaching ability is at least one iron(III) complex of an aminopolycarboxylic acid of the following formula (I) and the bath having fixing ability contains at least one organic phosphonic acid: ##STR1## wherein n represents 3, 4 or 5, and is preferable 3. Especially, the bleaching agent in the bath having bleaching ability comprises at least one iron(III) complex of a compound selected from the following group (A) and a (1,3-diaminopropanetetraacetato)iron(III) complex in a molar proportion of the former to the latter of being 3 or less, and ammonium ion accounts for 90 mol % or more of the sum of the alkali metal ions and ammonium ion in the bath having fixing ability; Group (A): A-1: Ethylenediaminetetraacetic Acid A-2: Diethylenetriaminepentaacetic Acid A-3: 1,2-Cyclohexanediaminetetraacetic Acid A-4: 1,2-Propylenediaminetetraacetic Acid. According to the method, rapid desilvering is effected, the stability of the fixing agent is improved, bleaching fog is inhibited, the fixing speed is elevated, and the storage stability of the images formed in the material processed is improved.
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