公开(公告)号：US20180355220A1

公开(公告)日：2018-12-13

申请号：US15757826

申请日：2016-08-16

Applicant: TESA SE

Inventor： Jennifer BESCHMANN ,  Alexander PRENZEL

IPC: C09J7/38 ,  C09J133/08 ,  C09J133/10 ,  C08F220/18 ,  C08F2/48

Abstract: The invention relates to a UV-cross-linked, polyacrylate-based adhesive mass that has high adhesive force and high cohesion and that can be produced by means of a hot-melt process with subsequent cross-linking. This is achieved by providing an adhesive mass that can be obtained by cross-linking a composition, which comprises at least one poly(meth)acrylate having a weight-average molar mass Mw of at least 100,000 g/mol and at least one polyfunctional α-cleaver and is characterized in that the composition contains at least one adhesive-force-increasing resin having a weight average molar mass Mw of at most 30,000 g/mol, which resin can be obtained by polymerizing a monomer composition M1, comprising at least one compound according to formula (I) H2C═C(R1)(COOR2), wherein R1 represents a hydrogen atom or a methyl group and R2 represents a hydrogen atom or a functionalized or non-functionalized C1-C20 alkyl group.

公开(公告)号：US20150299530A1

公开(公告)日：2015-10-22

申请号：US14683376

申请日：2015-04-10

Applicant: TESA SE

Inventor： Michael SIEBERT ,  Alexander PRENZEL ,  Inga AUKTUN ,  Jennifer BESCHMANN

IPC: C09J133/08 ,  D06M17/04 ,  D21H19/00 ,  C09J7/04

CPC classification number: C09J133/08 ,  C08F220/06 ,  C08F2220/1808 ,  C08L2312/06 ,  C09J7/21 ,  C09J7/38 ,  C09J133/02 ,  C09J2203/302 ,  C09J2400/263 ,  C09J2433/00 ,  D06M17/04 ,  D21H19/00

Abstract: Adhesives and pressure-sensitive adhesives comprising polymerization products of acrylates, the adhesives being meltable and comprising polymerization products of esters of (meth)acrylic acid and (meth)acrylic acid, the polymerization product having a molecular weight Mn of greater than 50 000 g/mol and Mw of greater than 500 000 g/mol.

Abstract translation: 粘合剂和压敏粘合剂包括丙烯酸酯的聚合产物，该粘合剂是可熔融的并且包含（甲基）丙烯酸和（甲基）丙烯酸的酯的聚合产物，聚合产物的分子量Mn大于50 000g / mol和Mw大于500000g / mol。

公开(公告)号：US20130190459A1

公开(公告)日：2013-07-25

申请号：US13736476

申请日：2013-01-08

Applicant: tesa SE

Inventor： Alexander PRENZEL ,  Sarah BAMBERG ,  Jennifer BESCHMANN ,  Marten PAPENBROOCK

IPC: C08F20/10

CPC classification number: C08F20/10 ,  C08K5/1515 ,  C08K5/17 ,  C09J133/00

Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at least one substance having at least one epoxide group as crosslinker and at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n is an integer from 0 to 4; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

Abstract translation: 用于具有能够与环氧基团进行交联反应的官能团的聚丙烯酸酯的热交联的交联剂 - 加速剂体系，包括至少一种具有至少一个环氧基团的物质作为交联剂和至少一种式R12N-CR2R3-CR4R5- （CR 6 R 7）n X，其中R 1独立地表示氢，取代或未取代的烷基或环烷基或与氮原子一起形成5-7元环; R2，R3，R4，R5，R6和R7独立地表示氢或具有1至8个碳原子的烷基或形成5-7元环亚烷基; n为0〜4的整数; X代表-OH，-OR，-SH，-SR和-PR2，其中R独立地表示C1-C18烷基，C2-C18烯基或C2-C18炔基，芳基或脂族或芳族杂环 ，作为加速器。

公开(公告)号：US20130123405A1

公开(公告)日：2013-05-16

申请号：US13717939

申请日：2012-12-18

Applicant: Tesa SE

Inventor： Alexander PRENZEL ,  Jennifer BESCHMANN

IPC: C08K5/36

CPC classification number: C08K5/36 ,  C08F2/38 ,  C08F20/18

Abstract: Process for preparing polyacrylates, by the free-radical polymerization of monomer mixtures comprising at least 70% by weight of at least one acrylic and/or methacrylic ester in the presence of amino acids as regulator substances, and reaction solution comprising one or more solvents and one or more monomers, at least 50% by weight of the solvents being organic solvents, and at least 70% by weight of the monomers being acrylic and/or methacrylic esters, with at least one amino acid being present.

Abstract translation: 在作为调节剂物质的氨基酸存在下，通过包含至少70重量％的至少一种丙烯酸和/或甲基丙烯酸酯的单体混合物的自由基聚合以及包含一种或多种溶剂的反应溶液和 一种或多种单体，至少50重量％的溶剂是有机溶剂，并且至少70重量％的单体是丙烯酸和/或甲基丙烯酸酯，其中存在至少一个氨基酸。

公开(公告)号：US20180155468A1

公开(公告)日：2018-06-07

申请号：US15834634

申请日：2017-12-07

Applicant: TESA SE

Inventor： Alexander PRENZEL ,  Sarah BAMBERG ,  Jennifer BESCHMANN ,  Marten PAPENBROOCK

IPC: C08F20/10 ,  C09J133/00 ,  C08K5/1515 ,  C08K5/17

CPC classification number: C08F20/10 ,  C08K5/1515 ,  C08K5/17 ,  C09J133/00

Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at leastone substance having at least one epoxide group as crosslinker and at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n=0; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

公开(公告)号：US20150148444A1

公开(公告)日：2015-05-28

申请号：US14611461

申请日：2015-02-02

Applicant: tesa SE

Inventor： Alexander PRENZEL ,  Jennifer BESCHMANN

IPC: C09J133/08

CPC classification number: C09J133/08

Abstract: The invention relates to a process for preparing a dispersion-based or hotmelt pressure-sensitive adhesive based on at least one polymer, which involves crosslinking the at least one polymer, the polymer having functional groups Y, the polymer additionally being admixed with at least one kind of functionalized particles which have at least one polymeric base unit, characterized in that the particles have a monomer as base unit, the monomer having at least one kind of functional groups Z which are not able to enter into any reaction with the functional group Y and which, by thermal energy, electromagnetic radiation, particulate radiation and/or sound energy, are converted into the group X, the crosslinking of the polymer being brought about at least in part by a reaction of the functional groups X of the particles and of the functional groups Y of the polymer, and additionally to pressure-sensitive adhesives based on at least one crosslinked polymer component, wherein the crosslinking of the polymer component is brought about at least partly through incorporation of functionalized particles, the particles having at least one polymeric base unit and also a monomer with one kind of functional groups Z, these groups Z, following conversion into the groups X by means of thermal energy, electromagnetic radiation, particulate radiation and/or sound energy, being capable of reacting with functional groups Y that are present in the polymer component, and also to the use of surface-modified functionalized particles having a polymeric base unit as crosslinking reagents for the crosslinking of polymers for preparing pressure-sensitive adhesives.

Abstract translation: 本发明涉及一种制备基于至少一种聚合物的基于分散体或热熔粘合剂的方法，所述聚合物包括交联至少一种聚合物，具有官能团Y的聚合物，该聚合物另外与至少一种聚合物混合 具有至少一个聚合碱基单元的官能化颗粒的种类，其特征在于，所述颗粒具有作为基单元的单体，所述单体具有至少一种不能与官能团Y进行任何反应的官能团Z 并且通过热能，电磁辐射，颗粒辐射和/或声能转换成组X，聚合物的交联至少部分地通过颗粒的官能团X和 聚合物的官能团Y，以及基于至少一种交联聚合物组分的压敏粘合剂，其中交联 聚合物组分至少部分地通过引入官能化颗粒而产生，所述颗粒具有至少一个聚合物基体单元，并且还具有一种官能团Z（这些基团Z）的单体，在通过 热能，电磁辐射，颗粒辐射和/或声能，能够与存在于聚合物组分中的官能团Y反应，以及使用具有聚合物基团单元的表面改性官能化颗粒作为交联剂， 用于制备压敏粘合剂的聚合物的交联。