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    PROCESS FOR PRODUCING SHORT-CHAIN MACROMOLECULES BASED ON ACRYLATE MONOMERS
    2.
    发明申请
    PROCESS FOR PRODUCING SHORT-CHAIN MACROMOLECULES BASED ON ACRYLATE MONOMERS 审中-公开
    基于丙烯酸酯单体生产短链大分子的方法

    公开(公告)号：US20160311955A1

    公开(公告)日：2016-10-27

    申请号：US15104308

    申请日：2014-11-19

    Applicant: TESA SE

    Inventor： Bernd LÜHMANN ,  Alexander PRENZEL ,  Benjamin PÜTZ ,  Helmut RITTER ,  Stephan ZÖLLNER

    IPC: C08F220/18

    CPC classification number: C08F220/18 ,  C08F2/38 ,  C08F220/14 ,  C08F290/046 ,  C08G18/6245 ,  C08G18/8116 ,  C08F212/08 ,  C08F2220/1825 ,  C08F2220/1858

    Abstract: Acrylate-based oligomers having double-bond end-group-functionalization are produced by means of free-radical polymerization where, in a first step, a monomer mixture of an acrylate component and an aromatic component is reacted with use of a difunctional regulator, the molar quantity of monomer mixture to that of regulator being from 100:20 to 100:0.5 and the polymerization is continued until monomer conversion reaches at least 96%. In a second step, the resultant macromolecules are reacted, in the reactor in which the polymerization was conducted, with at least one compound Z which has a functional group and has an ethylenic doule bond, and at least that portion of the compound Z that contains the ethylenic double bond becomes linked to the macromolecules via reaction of one of the functional groups of the difunctional regulator with the functional group of the compound Z.

    Abstract translation: 具有双键端基官能化的丙烯酸酯类低聚物是通过自由基聚合制备的，其中在第一步中，使用双官能调节剂使丙烯酸酯组分和芳族组分的单体混合物反应， 单体混合物与调节剂的摩尔量为100:20至100:0.5，并继续聚合，直到单体转化率达到至少96％。 在第二步中，使所得的大分子在其中进行聚合的反应器中与至少一种具有官能团并具有烯键式双键的化合物Z反应，并且至少包含含有 乙烯双键通过双官能调节剂的官能团之一与化合物Z的官能团反应而与大分子连接。

    CROSSLINKER-ACCELERATOR SYSTEM FOR POLYACRYLATES
    4.
    发明申请
    CROSSLINKER-ACCELERATOR SYSTEM FOR POLYACRYLATES 有权
    用于聚丙烯酸酯的交联剂加速器系统

    公开(公告)号：US20130190459A1

    公开(公告)日：2013-07-25

    申请号：US13736476

    申请日：2013-01-08

    Applicant: tesa SE

    Inventor： Alexander PRENZEL ,  Sarah BAMBERG ,  Jennifer BESCHMANN ,  Marten PAPENBROOCK

    IPC: C08F20/10

    CPC classification number: C08F20/10 ,  C08K5/1515 ,  C08K5/17 ,  C09J133/00

    Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at least one substance having at least one epoxide group as crosslinker and at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n is an integer from 0 to 4; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

    Abstract translation: 用于具有能够与环氧基团进行交联反应的官能团的聚丙烯酸酯的热交联的交联剂 - 加速剂体系，包括至少一种具有至少一个环氧基团的物质作为交联剂和至少一种式R12N-CR2R3-CR4R5- （CR 6 R 7）n X，其中R 1独立地表示氢，取代或未取代的烷基或环烷基或与氮原子一起形成5-7元环; R2，R3，R4，R5，R6和R7独立地表示氢或具有1至8个碳原子的烷基或形成5-7元环亚烷基; n为0〜4的整数; X代表-OH，-OR，-SH，-SR和-PR2，其中R独立地表示C1-C18烷基，C2-C18烯基或C2-C18炔基，芳基或脂族或芳族杂环 ，作为加速器。

    PROCESS FOR PREPARING POLYACRYLATES
    5.
    发明申请
    PROCESS FOR PREPARING POLYACRYLATES 有权
    制备聚丙烯酸酯的方法

    公开(公告)号：US20130123405A1

    公开(公告)日：2013-05-16

    申请号：US13717939

    申请日：2012-12-18

    Applicant: Tesa SE

    Inventor： Alexander PRENZEL ,  Jennifer BESCHMANN

    IPC: C08K5/36

    CPC classification number: C08K5/36 ,  C08F2/38 ,  C08F20/18

    Abstract: Process for preparing polyacrylates, by the free-radical polymerization of monomer mixtures comprising at least 70% by weight of at least one acrylic and/or methacrylic ester in the presence of amino acids as regulator substances, and reaction solution comprising one or more solvents and one or more monomers, at least 50% by weight of the solvents being organic solvents, and at least 70% by weight of the monomers being acrylic and/or methacrylic esters, with at least one amino acid being present.

    Abstract translation: 在作为调节剂物质的氨基酸存在下，通过包含至少70重量％的至少一种丙烯酸和/或甲基丙烯酸酯的单体混合物的自由基聚合以及包含一种或多种溶剂的反应溶液和 一种或多种单体，至少50重量％的溶剂是有机溶剂，并且至少70重量％的单体是丙烯酸和/或甲基丙烯酸酯，其中存在至少一个氨基酸。

    ADHESIVE SYSTEM MADE OF A MULTIPLICITY OF PRESSURE-SENSITVE ADHESIVE LAYERS
    6.
    发明申请
    ADHESIVE SYSTEM MADE OF A MULTIPLICITY OF PRESSURE-SENSITVE ADHESIVE LAYERS 审中-公开

    公开(公告)号：US20190284446A1

    公开(公告)日：2019-09-19

    申请号：US16347361

    申请日：2017-10-05

    Applicant: TESA SE

    Inventor： Alexander PRENZEL ,  Julia BEFUSS

    IPC: C09J7/38

    Abstract: The intention is to provide an adhesive system which is stable in storage and which when used permits precise positioning of the adhesive, and which can be crosslinked without exceeding moderate temperatures. The said system is moreover intended to provide strong adhesive bonds that attain high performance levels. This is achieved via a kit containing at least two pressure-sensitive adhesive layers A and B, where the two pressure-sensitive adhesive layers A and B mutually independently respectively comprise at least one polymer containing a multiplicity of carboxy groups; in the pressure-sensitive adhesive layer A a portion of the carboxy groups of the polymer containing these has been activated by reaction with an activator AA; and—the pressure-sensitive adhesive layer A—at least one crosslinking agent VA which can enter into a crosslinking reaction with the carboxy groups of the polymer containing these of the pressure-sensitive adhesive layers A and B, but which in the pressure-sensitive adhesive layer A is not significantly reactive; —the pressure-sensitive adhesive layer B—at least one crosslinking agent VB which can accelerate the crosslinking reaction of the carboxy groups of the polymer containing these of the pressure-sensitive adhesive layer B with the crosslinking agent VA and which can permit and accelerate the crosslinking reaction of the carboxy groups of the polymer containing these of the pressure-sensitive adhesive layer A with the crosslinking agent VA and can enter into a crosslinking reaction with the activated carboxy groups of the polymer containing these of the pressure-sensitive adhesive layer A. The invention moreover also relates to an adhesive tape which is obtainable via contact between the pressure-sensitive adhesive layers of the kit, and to a process for producing said adhesive tape.

    CROSSLINKER-ACCELERATOR SYSTEM FOR POLYACRYLATES
    7.
    发明申请
    CROSSLINKER-ACCELERATOR SYSTEM FOR POLYACRYLATES 审中-公开

    公开(公告)号：US20180155468A1

    公开(公告)日：2018-06-07

    申请号：US15834634

    申请日：2017-12-07

    Applicant: TESA SE

    Inventor： Alexander PRENZEL ,  Sarah BAMBERG ,  Jennifer BESCHMANN ,  Marten PAPENBROOCK

    IPC: C08F20/10 ,  C09J133/00 ,  C08K5/1515 ,  C08K5/17

    CPC classification number: C08F20/10 ,  C08K5/1515 ,  C08K5/17 ,  C09J133/00

    Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups capable of entering into linking reactions with epoxide groups, comprising at leastone substance having at least one epoxide group as crosslinker and at least one substance of the formula R12N—CR2R3—CR4R5—(CR6R7)n—X in which the R1 independently represent hydrogen, a substituted or unsubstituted alkyl or cycloalkyl radical or together with the nitrogen atom form a 5-7-membered ring; R2, R3, R4, R5, R6 and R7 independently represent hydrogen or an alkyl radical having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; n=0; and X represents —OH, —OR, —SH, —SR and —PR2, in which R independently represents C1-C18 alkyl radical, C2-C18 alkenyl radical or C2-C18 alkynyl radical, an aryl group or an aliphatic or aromatic heterocycle, as accelerator.

    PRESSURE-SENSITIVE ADHESIVES AND PROCESS FOR PREPARING THEM
    9.
    发明申请
    PRESSURE-SENSITIVE ADHESIVES AND PROCESS FOR PREPARING THEM 审中-公开
    压敏粘合剂及其制备方法

    公开(公告)号：US20150148444A1

    公开(公告)日：2015-05-28

    申请号：US14611461

    申请日：2015-02-02

    Applicant: tesa SE

    Inventor： Alexander PRENZEL ,  Jennifer BESCHMANN

    IPC: C09J133/08

    CPC classification number: C09J133/08

    Abstract: The invention relates to a process for preparing a dispersion-based or hotmelt pressure-sensitive adhesive based on at least one polymer, which involves crosslinking the at least one polymer, the polymer having functional groups Y, the polymer additionally being admixed with at least one kind of functionalized particles which have at least one polymeric base unit, characterized in that the particles have a monomer as base unit, the monomer having at least one kind of functional groups Z which are not able to enter into any reaction with the functional group Y and which, by thermal energy, electromagnetic radiation, particulate radiation and/or sound energy, are converted into the group X, the crosslinking of the polymer being brought about at least in part by a reaction of the functional groups X of the particles and of the functional groups Y of the polymer, and additionally to pressure-sensitive adhesives based on at least one crosslinked polymer component, wherein the crosslinking of the polymer component is brought about at least partly through incorporation of functionalized particles, the particles having at least one polymeric base unit and also a monomer with one kind of functional groups Z, these groups Z, following conversion into the groups X by means of thermal energy, electromagnetic radiation, particulate radiation and/or sound energy, being capable of reacting with functional groups Y that are present in the polymer component, and also to the use of surface-modified functionalized particles having a polymeric base unit as crosslinking reagents for the crosslinking of polymers for preparing pressure-sensitive adhesives.

    Abstract translation: 本发明涉及一种制备基于至少一种聚合物的基于分散体或热熔粘合剂的方法，所述聚合物包括交联至少一种聚合物，具有官能团Y的聚合物，该聚合物另外与至少一种聚合物混合 具有至少一个聚合碱基单元的官能化颗粒的种类，其特征在于，所述颗粒具有作为基单元的单体，所述单体具有至少一种不能与官能团Y进行任何反应的官能团Z 并且通过热能，电磁辐射，颗粒辐射和/或声能转换成组X，聚合物的交联至少部分地通过颗粒的官能团X和 聚合物的官能团Y，以及基于至少一种交联聚合物组分的压敏粘合剂，其中交联 聚合物组分至少部分地通过引入官能化颗粒而产生，所述颗粒具有至少一个聚合物基体单元，并且还具有一种官能团Z（这些基团Z）的单体，在通过 热能，电磁辐射，颗粒辐射和/或声能，能够与存在于聚合物组分中的官能团Y反应，以及使用具有聚合物基团单元的表面改性官能化颗粒作为交联剂， 用于制备压敏粘合剂的聚合物的交联。

    ADHESIVE TAPE
    10.
    发明公开
    ADHESIVE TAPE 审中-公开

    公开(公告)号：US20240010876A1

    公开(公告)日：2024-01-11

    申请号：US18038620

    申请日：2021-11-24

    Applicant: tesa SE

    Inventor： Felix Stephan VON LAMEZAN ,  Jan AUGENSTEIN ,  Alexander PRENZEL

    IPC: C09J7/25 ,  C09J7/38

    CPC classification number: C09J7/255 ,  C09J7/385

    Abstract: The invention relates to an adhesive tape comprising a backing consisting of a film, to at least one side of which backing an adhesive mass is applied. The film is a film that is monoxially stretched in the longitudinal direction and contains at least 90 wt. %, preferably 95 wt. %, more preferably 99 wt. % of polyester polymers.

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