公开(公告)号：US3591514A

公开(公告)日：1971-07-06

申请号：US3591514D

申请日：1969-04-04

Applicant: TEXACO INC

Inventor： SMETANA RICHARD D ,  DURANIEAU ROGER G ,  ARKELL ALFRED

IPC: C07C409/20 ,  C07D323/02 ,  C10B13/00

CPC classification number: C07D323/02

Abstract: STABILIZED COMPOSITIONS COMPRISING AN ALKALI METAL FLUORIDE AND OZONE DERIVATIVE SELECTED FROM THE GROUP CONSISTING OF OXOLANE OF THE FORMULA:

3-R1,3-R2,5-R3,5-R4-1,2,4-TRIOXOLANE

AND ALKOXYHYDROPEROXIDES OF THE FORMULA:

R1-C(-R2)(-O-R5)-O-OH AND R3-C(-R4)(-O-R5)-O-OH

WHERE R1, R2, R3 AND R4 ARE HYDROGEN OR HYDROCARBYL AND R5 IS ALKYL AND A METHOD OF PRODUCING SAID STABILIZED OXOLANES AND HYDROPEROXIDES COMPRISING CONTACTING IN THE PRESENCE OF AN ALKALI METAL FLUORIDE AND OELFIN OF THE FORMULA

R1R2C=CR3R4

WITH OZONE OR OZONE AND ALKANOL OF THE FORMULA R5OH.

公开(公告)号：US3622647A

公开(公告)日：1971-11-23

申请号：US3622647D

申请日：1969-09-11

Applicant: TEXACO INC

Inventor： MCMAHON MATTHEW A ,  ARKELL ALFRED

IPC: C07C1/36 ,  C07C1/20 ,  C07B3/00 ,  C07F5/04

CPC classification number: C07C1/36 ,  Y10S585/905 ,  Y10S585/931 ,  C07C13/00 ,  C07C11/02

Abstract: Manufacture of alkene from alkane, said alkene of an equal number of carbons as its alkane precursor, comprising contacting alkane with oxygen in the presence of a boric acid at an elevated temperature, spearating the resultant alkylborate esters from the reaction product, pyrolyzing said alkylborates in an inert atmosphere, preferably in the presence of a methanol or trimethylborate and recovering the formed alkene from the pyrolysis mixture, said recovery preferably including contacting said formed alkene with silica gel.

公开(公告)号：US3642832A

公开(公告)日：1972-02-15

申请号：US3642832D

申请日：1969-03-18

Applicant: TEXACO INC

Inventor： SMETANA RICHARD DENIS ,  CHAFETZ HARRY ,  ARKELL ALFRED

IPC: C07C409/20 ,  C07D303/04 ,  C07D1/08 ,  C07D1/12

CPC classification number: C07D303/04

Abstract: A METHOD OF PRODUCING AN EPOXIDE OF THE FORMULA:

2-R1,2-R2,3-R3,3-R4-OXIRANE OR 2,3-(-R5-)OXIRANE

WHERE R1, R2, R3 AND R4 ARE HYDROGEN OR HYDROCARBYL AND R5 IS X,$-ALKYLENE COMPRISING CONTACTING A FIRST OLEFIN OF THE FORMULA:

R1-C(-R2)=C(-R3)-R4 OR R5
WHERE R1 THROUGH R5 IS AS HERETOFORE DEFINED WITH AN ALKOXYHYDROPEROXIDE OF THE FORMULA:

R6-C(-R7)(-O-OH)-O-R10 AND/OR R8-C(-R9)(-O-OH)-O-R10

WHERE R6, R7, R8 AND R9 ARE HYDROGEN OR HYDROCARBYL IN THE PRESENCE OF A MOLYBDENUM, TUNGSTEN OR VANADIUM EPOXIDE PRODUCING CATALYST, SAID HYDROPEROXIDE PREPARED BY CONTACTING A MIXTURE OF A SECOND OLEFIN OF THE FORMULA:

R6R7C=CR8R9

WHERE R6 R7, R8 AND R9 ARE AS HERETOFORE DEFINED, AND AN ALKANOL OF THE FORMULA R10OH WHERE R10 IS ALKYL WITH OZONE.

公开(公告)号：US3642831A

公开(公告)日：1972-02-15

申请号：US3642831D

申请日：1969-03-18

Applicant: TEXACO INC

Inventor： SMETANA RICHARD D ,  CHAFETZ HARRY ,  ARKELL ALFRED ,  MCMAHON MATTHEW A

IPC: C07C409/20 ,  C07D303/04 ,  C07D1/08 ,  C07D1/12

CPC classification number: C07D303/04

Abstract: A METHOD OF PRODUCING AN EPOXIDE OF THE FORMULA:

2-R1,2-R2,3-R3,3-R4-OXIRANE OR 2,3-(-R5-)OXIRANE

WHERE R1, R2, R3 AND R4 ARE HYDROGEN OR HYDROCARBYL AND R5 IS X,$-ALKYLENE, COMPRISING CONTACTING A FIRST OLEFIN OF THE FORMULA:

R1-C(-R2)=C(-R3)-R4 OR R5
WHERE R THROUGH R5 IS AS HERETOFORE DEFINED WITH A HYDROPEROXY ALKANOATE OF THE FORMULA:

R6-C(-R7)(-O-OH)-OOC-R10 AND/OR R8-C(-R9)(-O-OH)-OOC-R10

WHERE R6, R7, R8 AND R9 ARE HYDROGEN OR HYDROCARBYL AND R10 IS ALKYL OF FROM 1 TO 20 CARBONS IN THE PRESENCE OF A MOLYBDENUM TUNGSTEN OR VANADIUM EPOXIDE PRODUCING CATALYST, SAID ALKANOATE PREPARED BY CONTACTING WITH OZONE A MIXTURE OF SECOND OLEFIN OF THE FORMULA:

R6R7C=CR8R9

WHERE R6, R7, R8 AND R9 ARE AS HERETOFORE DEFINED WITH AN ALKANOIC ACID OF THE FORMULA R10COOH WHERE R10 IS AS HERETOFORE DEFINED.

公开(公告)号：US3454369A

公开(公告)日：1969-07-08

申请号：US3454369D

申请日：1965-04-02

Applicant: TEXACO INC

Inventor： ARKELL ALFRED ,  REINHARD RUSSELL R ,  HEISLER ROBERT Y ,  LARSON LEWIS P

IPC: C01B7/24 ,  C06B43/00 ,  C01B7/20

CPC classification number: C01B11/24 ,  C06B43/00