摘要:
The invention provides an optical information recording medium having a recording layer capable of recording information by irradiating the recording layer with a laser beam of 440 nm or less.In the optical information recording medium, the recording layer contains an oxonol dye represented by formula (1), and a counter cation (Yt+) of this dye is a cationic dye having an absorption maximum in a range of longer wavelengths than an absorption maximum of an anionic part of the oxonol dye. In the formula, A, B, C and D each represents an electron-withdrawing group. A and B or C and D may be combined with each other to form a ring. If these are not combined with each other, these are electron-withdrawing groups in which the sum of Hammett's σp values of A and B and the sum of Hammett's σp values of C and D are each greater than 0.6. R represents a substituent group on methine carbon, and m represents an integer of 0 to 1. n represents an integer of 0 to 2m+1. If n is 2 or greater, a plurality of R's may be different from each other, and R and R may be combined together to form a ring. Yt+ represents a t-valent cation, and t represents an integer of 1 to 4.
摘要:
An optical information recording medium, comprising on a substrate a recording layer containing a dye compound having a specific structure. An optical information recording method, comprising recording information on the optical information recording medium by irradiation with laser light of a wavelength of 550 or shorter or 440 nm or shorter.
摘要:
There is provided an optical information-recording medium, comprising a recording layer capable of recording of information by irradiation of a laser beam having a wavelength of 440 nm or less on or above a substrate, the recording layer comprising a dye having two or more independent dye moieties in the molecule that are bound to each other in a manner other than by forming a conjugated bond to the dye moieties, and a method of recording information, comprising recording information by irradiating a laser beam having a wavelength of 440 nm or less on or above the optical information-recording medium according to the present invention described above.
摘要:
There is provided an optical information recording medium including, on a substrate, a recording layer in which information can be recorded by irradiating a laser beam having a wavelength of 440 nm or less, wherein the recording layer includes an oxonol dye that has a maximum absorption wavelength longer than the wavelength of the laser beam. There is also provided an information recording method including irradiating a laser beam having a wavelength of 440 nm or less to the optical information recording medium to record information.
摘要:
A blue laser-ready information recording medium improved in light stability and durability without impairment of record/playback characteristics is provided.The information recording medium is an optical information recording medium having on a substrate a recording layer that permits recording of information by irradiation with laser light of 440 nm or below, and is a heat-mode information recording medium that has a recording layer containing a methine dye and an organic oxidant on a transparent disk-form substrate on which a pregroove having a track pitch of 0.2 to 0.5 μm is formed, and that on the pregroove-formed side of the substrate.
摘要:
The present invention provides an optical information recording medium comprising a substrate having provided thereon a recording layer in which information can be recorded by laser light irradiation, wherein the recording layer contains a dye represented by the following formula (I): wherein Dye represents a dye residue having a molar extinction coefficient of 10000 (cm−1·mol−1) or more for light having a wavelength of 450 nm to 900 nm; L represents a divalent connecting group or a single bond; UV represents a dye residue having a molar extinction coefficient of 10000 (cm−1·mol−1) or more for light having a wavelength of 280 nm to 450 nm; and m denotes an integer from 1 to 8.
摘要:
The present invention provides an optical information recording medium comprising a substrate having provided thereon a recording layer in which information can be recorded by laser light irradiation, wherein the recording layer contains a dye represented by the following formula (I): Formula (I) wherein Dye represents a dye residue having an absorption as high as 10000 (cm−1·mol−1) or more as a molar extinction coefficient for light having a wavelength of 450 nm to 900 nm; L represents a divalent connecting group or a single bond; UV represents a dye residue having an absorption as high as 10000 (cm−1·mol−1) or more as a molar extinction coefficient for light having a wavelength of 280 nm to 450 nm; and m denotes an integer from 1 to 8.
摘要:
An optical information-recording medium comprises a recording layer comprising an oxonol dye represented by formula (1), and its counter cation is a cyanine cation: wherein A, B, C and D each represents an electron attractive group, wherein sum total of Hammett's σp values of A and B, and sum total of Hammett's σp values of C and D are respectively 0.6 or more, and A and B, or C and D may be linked with each other to make a ring; R represents a substituent on carbon of methine; m represents an integer of 0 or 1; n represents an integer of 0 to 2m+1, and when n represents an integer of 2 or more, plural R's may be the same or different, and they may be linked with each other to form a ring; Yt+ represents a t-valent cyanine cation; and t represents an integer of 1 to 10.
摘要翻译:光学信息记录介质包括由式(1)表示的氧杂菁染料的记录层,其抗衡阳离子是花青阳离子:其中A,B,C和D各自表示吸电子基团,其中Hammett's A和B的sigmap值,C和D的Hammett sigmap值的总和分别为0.6以上,A和B或C和D可以相互连接,形成环; R表示次甲基碳上的取代基; m表示0或1的整数; n表示0〜2m + 1的整数,当n表示2以上的整数时,多个R可以相同也可以不同,可以相互连接形成环。 Y + t +表示t价花青阳离子; t表示1〜10的整数。
摘要:
A method of producing a desubstituted compound, including: applying an external stimulation to a compound A-(B)m having a solvent-soluble group B (wherein A represents a residue of a solvent-insoluble compound, B represents a specific solvent-soluble group, and m represents a natural number, and the solvent-soluble group B bonds to a carbon atom of the residue A of a solvent-insoluble compound), to cause desubstitution of the solvent-soluble group B, and converting the compound to a solvent-insoluble compound to which a hydrogen atom bonds in place of the solvent-soluble group B; a method of producing an organic semiconductor film, including: forming a film of a π-conjugated compound having a substituent represented by formula (2-I), on a substrate; and causing desubstitution of the substituent from the compound; and an organic semiconductor film and an organic electronic device each obtained by these methods: wherein R11 represents a substituent other than a hydrogen atom.
摘要:
An aspect of the present invention relates to an optical information recording medium comprising a recording layer on a surface of a support, wherein the surface of the support has pregrooves with a track pitch ranging from 50 to 500 nm, the recording layer comprises an azo metal complex dye being a complex of six azo dyes and seven transition metal ions. A further aspect of the present invention relates to a method of recording information onto the optical information recording medium and a novel azo metal complex dye.