摘要:
The invention provides an optical information recording medium having a recording layer capable of recording information by irradiating the recording layer with a laser beam of 440 nm or less.In the optical information recording medium, the recording layer contains an oxonol dye represented by formula (1), and a counter cation (Yt+) of this dye is a cationic dye having an absorption maximum in a range of longer wavelengths than an absorption maximum of an anionic part of the oxonol dye. In the formula, A, B, C and D each represents an electron-withdrawing group. A and B or C and D may be combined with each other to form a ring. If these are not combined with each other, these are electron-withdrawing groups in which the sum of Hammett's σp values of A and B and the sum of Hammett's σp values of C and D are each greater than 0.6. R represents a substituent group on methine carbon, and m represents an integer of 0 to 1. n represents an integer of 0 to 2m+1. If n is 2 or greater, a plurality of R's may be different from each other, and R and R may be combined together to form a ring. Yt+ represents a t-valent cation, and t represents an integer of 1 to 4.
摘要:
There is provided an optical information-recording medium, comprising a recording layer capable of recording of information by irradiation of a laser beam having a wavelength of 440 nm or less on or above a substrate, the recording layer comprising a dye having two or more independent dye moieties in the molecule that are bound to each other in a manner other than by forming a conjugated bond to the dye moieties, and a method of recording information, comprising recording information by irradiating a laser beam having a wavelength of 440 nm or less on or above the optical information-recording medium according to the present invention described above.
摘要:
An optical information recording medium, comprising on a substrate a recording layer containing a dye compound having a specific structure. An optical information recording method, comprising recording information on the optical information recording medium by irradiation with laser light of a wavelength of 550 or shorter or 440 nm or shorter.
摘要:
There is provided an optical information recording medium including, on a substrate, a recording layer in which information can be recorded by irradiating a laser beam having a wavelength of 440 nm or less, wherein the recording layer includes an oxonol dye that has a maximum absorption wavelength longer than the wavelength of the laser beam. There is also provided an information recording method including irradiating a laser beam having a wavelength of 440 nm or less to the optical information recording medium to record information.
摘要:
A blue laser-ready information recording medium improved in light stability and durability without impairment of record/playback characteristics is provided.The information recording medium is an optical information recording medium having on a substrate a recording layer that permits recording of information by irradiation with laser light of 440 nm or below, and is a heat-mode information recording medium that has a recording layer containing a methine dye and an organic oxidant on a transparent disk-form substrate on which a pregroove having a track pitch of 0.2 to 0.5 μm is formed, and that on the pregroove-formed side of the substrate.
摘要:
The optical information recording medium comprises a recording layer comprising a dye on a support. The recording layer comprises a compound comprising a substituent having a property of producing a gas by thermal decomposition. The method of recording information on the recording layer comprised in the above optical information recording medium by irradiation of a laser beam onto the optical information recording medium. The method of using a compound comprising a substituent having a property of producing a gas by thermal decomposition as an additive in a solution comprising a dye.
摘要:
The optical information recording medium comprises a reflective layer, a recording layer, a barrier layer, and a cover layer in this order on a surface of a support, and a layer formed by curing an ultraviolet radiation-curable composition between the barrier layer and the cover layer, the layer having a glass transition temperature of equal to or lower than 25° C. The surface of the support has pregrooves with a track pitch of 50 to 500 nm. The recording layer ranges in thickness from 1 to 100 nm on the lands and from 5 to 150 nm on the grooves, and comprises at least one azo dye compound selected from the group consisting of an azo compound and an azo metal complex compound comprising an azo compound and a metal ion or metal oxide ion, with an attenuation coefficient of 0.15 to 0.3 at a wavelength of 405 nm.
摘要:
A first write-once type recording layer, on which information can be recorded by being irradiated with a laser beam having a wavelength of not more than 450 nm, is provided on a first substrate of a first optical information-recording medium. A dye compound, which contains boron as a constitutive element, is contained in the first write-once type recording layer. Preferred examples of the dye compound include boronic acid. In particular, it is preferable to use a compound having a boroxin moiety formed by condensation of boronic acid. The condensation of boronic acid can be advanced such that a solution, which is prepared by dissolving boronic acid in a solvent, is applied onto the first substrate to form the first write-once type recording layer, and then the first write-once type recording layer is subjected to an annealing treatment.
摘要:
An optical information-recording medium comprises a recording layer comprising an oxonol dye represented by formula (1), and its counter cation is a cyanine cation: wherein A, B, C and D each represents an electron attractive group, wherein sum total of Hammett's σp values of A and B, and sum total of Hammett's σp values of C and D are respectively 0.6 or more, and A and B, or C and D may be linked with each other to make a ring; R represents a substituent on carbon of methine; m represents an integer of 0 or 1; n represents an integer of 0 to 2m+1, and when n represents an integer of 2 or more, plural R's may be the same or different, and they may be linked with each other to form a ring; Yt+ represents a t-valent cyanine cation; and t represents an integer of 1 to 10.
摘要翻译:光学信息记录介质包括由式(1)表示的氧杂菁染料的记录层,其抗衡阳离子是花青阳离子:其中A,B,C和D各自表示吸电子基团,其中Hammett's A和B的sigmap值,C和D的Hammett sigmap值的总和分别为0.6以上,A和B或C和D可以相互连接,形成环; R表示次甲基碳上的取代基; m表示0或1的整数; n表示0〜2m + 1的整数,当n表示2以上的整数时,多个R可以相同也可以不同,可以相互连接形成环。 Y + t +表示t价花青阳离子; t表示1〜10的整数。
摘要:
A method of producing a desubstituted compound, including: applying an external stimulation to a compound A-(B)m having a solvent-soluble group B (wherein A represents a residue of a solvent-insoluble compound, B represents a specific solvent-soluble group, and m represents a natural number, and the solvent-soluble group B bonds to a carbon atom of the residue A of a solvent-insoluble compound), to cause desubstitution of the solvent-soluble group B, and converting the compound to a solvent-insoluble compound to which a hydrogen atom bonds in place of the solvent-soluble group B; a method of producing an organic semiconductor film, including: forming a film of a π-conjugated compound having a substituent represented by formula (2-I), on a substrate; and causing desubstitution of the substituent from the compound; and an organic semiconductor film and an organic electronic device each obtained by these methods: wherein R11 represents a substituent other than a hydrogen atom.