公开(公告)号：US07683131B2

公开(公告)日：2010-03-23

申请号：US10579843

申请日：2004-09-15

申请人： Thorsten Goldacker ,  Andreas Spiess ,  Reiner Mueller ,  Klaus Schultes ,  Uwe Numrich

发明人： Thorsten Goldacker ,  Andreas Spiess ,  Reiner Mueller ,  Klaus Schultes ,  Uwe Numrich

IPC分类号： C08J5/18 ,  C08L33/12 ,  C08L51/00 ,  C08L101/00 ,  C08L33/00 ,  C08F265/04 ,  C08F265/06

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08F265/06 ,  C08F279/02 ,  C08L33/12 ,  C08L35/06 ,  C08L55/02 ,  C08L101/00 ,  C08L2205/22 ,  C08L2666/02 ,  C08L2666/04

摘要： The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.

摘要翻译： 本发明涉及一种模塑组合物，其包含a）50-99.9重量％的由热塑性聚合物组成的基质和b）0.1至50重量％的分散在（甲基）丙烯酸酯共聚物形式的消光剂 在基质中，其特征在于，所述消光剂是已经从下列单体制备的，B1）为50〜95重量％的甲基丙烯酸甲酯b2的）从5至50％（重量）C 1 -C的（甲基）丙烯酸酯共聚物 丙烯酸C 6 - 烷基酯b 3）0.01至小于0.5重量％的具有两个或更多个能够进行自由基聚合的烯键式不饱和基团的交联单体和/或接枝交联剂，b4）0至20重量％ 一种或多种能够进行自由基聚合的其它非交联烯键式不饱和单体，其中b1）和b2）和b3）和/或b4）的总体含量为100％（重量），玻璃 消光剂的转变温度Tmg的是至少20 C.

公开(公告)号：US20070066708A1

公开(公告)日：2007-03-22

申请号：US10579843

申请日：2004-09-15

申请人： Thorsten Goldacker ,  Andreas Spiess ,  Reiner Mueller ,  Klaus Schultes ,  Uwe Numrich

发明人： Thorsten Goldacker ,  Andreas Spiess ,  Reiner Mueller ,  Klaus Schultes ,  Uwe Numrich

IPC分类号： C09D11/00

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08F265/06 ,  C08F279/02 ,  C08L33/12 ,  C08L35/06 ,  C08L55/02 ,  C08L101/00 ,  C08L2205/22 ,  C08L2666/02 ,  C08L2666/04

摘要： The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.

摘要翻译： 本发明涉及一种模塑组合物，其包含a）50-99.9重量％的由热塑性聚合物组成的基质和b）0.1至50重量％的分散在（甲基）丙烯酸酯共聚物形式的消光剂 在基质中，其特征在于消光剂是由以下单体制备的（甲基）丙烯酸酯共聚物，b1）50-95重量％的甲基丙烯酸甲酯b2）5-50重量％ 烷基丙烯酸酯b3）0.01至小于0.5重量％的交联单体和/或具有两个或更多个烯属不饱和基团的接枝交联剂 的自由基聚合，b4）0至20重量％的一种或多种能够进行自由基聚合的其它非交联烯键式不饱和单体，其中组分b1）和b2的整体），并且在适当的情况下， b3）和/或b4）给出100重量％，玻璃化转变温度T 消光剂至少为20℃

公开(公告)号：US20060147714A1

公开(公告)日：2006-07-06

申请号：US10539509

申请日：2003-10-18

申请人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

发明人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

IPC分类号： B32B1/00

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08F285/00 ,  C08L33/12 ,  C08L33/20 ,  C08L35/06 ,  C08L51/04 ,  C08L55/005 ,  C08L55/02 ,  Y10T428/2998 ,  C08L2666/02 ,  C08L2666/24

摘要： The present invention relates to a core-shell particle which has a core, a first shell and, where appropriate, a second shell, where: i) the core encompasses, based on its total weight, at least 75.0% by weight of (meth)acrylate repeat units; ii) the first shell has a glass transition temperature below 30° C.; iii) the second shell present where appropriate encompassed, based on its total weight, at lest 75.0% by weight of (meth)acrylate repeat units; iv) the first shell encompasses, based on its total weight, the following constituents; E) from 92.0 to 98.0% by weight of (meth)acrylate repeat units and F) from 2.0 to 8.0% by weight of styrenic repeat units of the general formula (I) where the radicals R1 to R6 are defined according to the Description and the percentages by weight of E) and F) give a total of 100.0% by weight, v) the radius of the core-shell particle inclusive of any second shell present, measured by the Coulter method, is in the range from above 160.0 to 240.0 nm. The present invention further relates to a process for preparing core-shell particles, to a moulding composition comprising core-shell particles, and to the use thereof.

摘要翻译： 本发明涉及一种具有芯，第一壳和适当的第二壳的核 - 壳颗粒，其中：i）芯基于其总重量包含至少75.0重量％的（甲基） ）丙烯酸酯重复单元; ii）第一壳的玻璃化转变温度低于30℃; iii）适当地包含的第二壳基于其总重量至少为75.0重量％的（甲基）丙烯酸酯重复单元; iv）第一壳基于其总重量包含以下组分; E）为92.0〜98.0重量％的（甲基）丙烯酸酯重复单元，F）2.0〜8.0重量％的通式（I）的苯乙烯重复单元，其中R 1〜 根据描述定义R 6，并且E）和F）的重量百分比总计为100.0重量％，v）包含任何第二壳的核 - 壳颗粒的半径 存在，通过库尔特法测量，在160.0至240.0nm之间的范围内。 本发明还涉及一种制备核 - 壳颗粒的方法，涉及包含核 - 壳颗粒的模塑组合物及其用途。

公开(公告)号：US07695813B2

公开(公告)日：2010-04-13

申请号：US10539509

申请日：2003-10-18

申请人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

发明人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

IPC分类号： B32B5/16

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08F285/00 ,  C08L33/12 ,  C08L33/20 ,  C08L35/06 ,  C08L51/04 ,  C08L55/005 ,  C08L55/02 ,  Y10T428/2998 ,  C08L2666/02 ,  C08L2666/24

摘要： The present invention relates to a core-shell particle which has a core, a first shell and, where appropriate, a second shell, where: i) the core encompasses, based on its total weight, at least 75.0% by weight of (meth)acrylate repeat units; ii) the first shell has a glass transition temperature below 30° C.; iii) the second shell present where appropriate encompassed, based on its total weight, at lest 75.0% by weight of (meth)acrylate repeat units; iv) the first shell encompasses, based on its total weight, the following constituents; E) from 92.0 to 98.0% by weight of (meth)acrylate repeat units and F) from 2.0 to 8.0% by weight of styrenic repeat units of the general formula (I)  where the radicals R1 to R6 are defined according to the Description and the percentages by weight of E) and F) give a total of 100.0% by weight, v) the radius of the core-shell particle inclusive of any second shell present, measured by the Coulter method, is in the range from above 160.0 to 240.0 nm; a process for preparing core-shell particles, to a moulding composition comprising core-shell particles, and to the use thereof.

摘要翻译： 本发明涉及一种具有芯，第一壳和适当的第二壳的核 - 壳颗粒，其中：i）芯基于其总重量包含至少75.0重量％的（甲基） ）丙烯酸酯重复单元; ii）第一壳的玻璃化转变温度低于30℃; iii）适当地包含的第二壳基于其总重量至少为75.0重量％的（甲基）丙烯酸酯重复单元; iv）第一壳基于其总重量包含以下组分; E）92.0至98.0重量％的（甲基）丙烯酸酯重复单元，F）2.0至8.0重量％的通式（I）的苯乙烯重复单元，其中基团R 1至R 6根据描述定义， E）和F）的重量百分比总计为100.0重量％，v）通过Coulter法测定的包含任何存在的任何第二壳的核 - 壳颗粒的半径在160.0以上至 240.0nm; 一种制备核 - 壳颗粒的方法，包括核 - 壳颗粒的模塑组合物及其用途。

公开(公告)号：US4649502A

公开(公告)日：1987-03-10

申请号：US665974

申请日：1984-10-29

申请人： Guido Keller ,  Andreas Spiess ,  Hans Ott ,  Rolf Boegli

发明人： Guido Keller ,  Andreas Spiess ,  Hans Ott ,  Rolf Boegli

IPC分类号： B41F33/00 ,  G01N21/88 ,  B41M1/00

CPC分类号： B41F33/0027 ,  B41F33/00 ,  B41F33/0036 ,  B41F33/0045

摘要： The printed sheets are scanned, by image elements, immediately behind the last printing mechanism, with one or several measuring heads. Suitable dimensions of an image element range from approximately 1.times.1 mm.sup.2 to 10.times.10 mm.sup.2. In each image element the reflectance is measured in four spectral ranges (infrared for black, red for cyan, green for magenta and blue for yellow). The measured reflectance values are converted by means of Neugebauer equations into surface coverages in a demasking step and inputted to a computer for evaluation. With the same measuring device, both the reference values associated with OK sheets, and the actual values associated with continuous printing, are measured. The computer compares the measured data, weights them with respect to such factors as surface coverage, foreign color component and the environment of a respective image element, and produces a regulating signal to control the ink feed elements. The color coordinates (X,Y,Z) may be determined from the surface coverage values of the four colors in a parallel computer program. Image elements which are important for the visual appearance of an image are given a high weight. A quality measure may be determined from the weighted comparison of reference and actual values to change the visual appearance. With this process it is possible to control the ink feed elements of a multicolor printing press by direct on-line measurement of the printed image, without using color measuring strips.

摘要翻译： 打印的纸张通过图像元素在最后一个打印机构的后面用一个或多个测量头进行扫描。 图像元件的合适尺寸范围为约1×1mm 2至10×10 2 mm 2。 在每个图像元素中，反射率在四个光谱范围内测量（红色为黑色，红色为青色，绿色为洋红色，蓝色为黄色）。 测量的反射率值通过Neugebauer方程转换为拆卸步骤中的表面覆盖率，并输入计算机进行评估。 使用相同的测量装置，测量与OK纸张相关联的参考值和与连续打印相关联的实际值。 计算机将测量数据进行比较，将它们相对于诸如表面覆盖率，异色成分和相应图像元素的环境等因素进行加权，并产生调节信号以控制供墨元件。 颜色坐标（X，Y，Z）可以从并行计算机程序中的四种颜色的表面覆盖值确定。 对于图像的视觉外观重要的图像元素被赋予了很高的重量。 质量测量可以根据参考值和实际值的加权比较来确定，以改变视觉外观。 通过该处理，可以通过直接在线测量打印图像来控制多色印刷机的供墨元件，而不使用彩色测量条。