RECHARGEABLE LITHIUM ION BATTERY WITH IMPROVED LIFE CHARACTERISTICS

    公开(公告)号:US20210320354A1

    公开(公告)日:2021-10-14

    申请号:US17259662

    申请日:2019-07-10

    Abstract: A secondary Li-ion battery comprising a casing comprising as battery parts: a positive electrode comprising a powderous positive electrode active material, a negative electrode, a separator, and an electrolyte, wherein the casing is provided with means for maintaining the exterior form of the casing, and wherein the positive electrode active material has the general formula Li1+a(NixCoyMz)1−aO2, wherein M=M′1−bAb, M′ being either one or both of Al and Mg, and A being a dopant with b≤0.10, and wherein −0.03≤a≤0.03, 0.80≤×≤0.95, 0.05≤y≤0.20, z≤0.10, with x+y+z=1, and wherein the positive electrode active material has a crystallite size ≤43 nm as determined by the Sherrer equation based on the peak of the (104) plane obtained from the X-ray diffraction pattern using a Cu Kα radiation source, and wherein the positive electrode active material further comprises between 0.4 and 0.6 wt % LiOH.

    A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE LITHIUM-ION BATTERIES

    公开(公告)号:US20240030423A1

    公开(公告)日:2024-01-25

    申请号:US18265630

    申请日:2021-12-17

    Applicant: UMICORE

    CPC classification number: H01M4/405 H01M4/485 H01M10/0525 H01M2004/028

    Abstract: A positive electrode active material for lithium-ion liquid electrolyte rechargeable batteries, whereby the positive electrode active material is a powder which comprises Li, M′, and O, wherein M′ consists of Co in a content x superior or equal to 2.0 mol % and inferior or equal to 35.0 mol %, Mn in a content y superior or equal to 0 mol % and inferior or equal to 35.0 mol %, A in a content m superior or equal to 0 mol % and inferior or equal to 5 mol %, whereby A comprises at least one element of the group consisting of: Al, Ba, B, Mg, Nb, Sr, Ti, W, S, Ca, Cr, Zn, V, Y, Si, and Zr, Ni in a content of 100-x-y-m mol %, a first compound which comprises Li2WO4 and a second compound which comprises WO3, whereby the powder is a single-crystalline powder, whereby the positive electrode active material comprises Li in a molar ratio of Li/(Co+Mn+Ni+A) of at least 0.9 and at most 1.1.

    A POSITIVE ELECTRODE ACTIVE MATERIAL FOR RECHARGEABLE BATTERIES

    公开(公告)号:US20240030408A1

    公开(公告)日:2024-01-25

    申请号:US18265599

    申请日:2021-12-17

    Applicant: UMICORE

    CPC classification number: H01M4/364 H01M4/525 H01M4/485 H01M2004/028

    Abstract: A positive electrode active material for solid state rechargeable batteries, whereby the positive electrode active material is a powder which comprises Li, NI, and 0, wherein M′ consists of Co in a content x superior or equal to 2.0 mol % and inferior or equal to 35.0 mol %, Mn in a content y superior or equal to 0 mol % and inferior or equal to 35.0 mol %, A in a content m superior or equal to 0 mol % and inferior or equal to 5 mol %, whereby A comprises at least one element of the group consisting of: Al, Ba, B, Mg, Nb, Sr, Ti, W, S, Ca, Cr, Zn, V, Y, Si, and Zr, Ni in a content of 100-x-y-m mol %, a first compound which comprises Li2WO4 and a second compound which comprises WO3, whereby the powder is a single-crystalline powder, whereby the positive electrode active material comprises Li in a molar ratio of Li/(Co+Mn+Ni+A) of at least 0.9 and at most 1.1, whereby the positive electrode active material has a tap density which is at least 1.0 gr/cm3 and at most 3.0 g/cm3.

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