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    Preparation of amino(phenyl)boranes
    7.
    发明授权
    Preparation of amino(phenyl)boranes 失效
    氨基（苯基）硼烷的制备

    公开(公告)号：US3079432A

    公开(公告)日：1963-02-26

    申请号：US15694461

    申请日：1961-12-04

    Applicant: UNITED STATES BORAX CHEM

    Inventor： PETTERSON LOWELL L ,  BROTHERTON ROBERT J ,  WIILCOCKSON GEORGE W ,  MCCLOSKEY ALLEN L

    IPC: C07F5/00 ,  C07F5/02 ,  C10L1/30

    CPC classification number: C10M3/00 ,  C07F5/006 ,  C07F5/025 ,  C10L1/303 ,  C10M2227/08 ,  C10N2210/03 ,  C10N2240/08

    Abstract: An amino(phenyl) borane of the formula R1(3-n)B(NR2)n is made by the interaction of an aminohaloborane of the formula (R2N)nBX(3-n), an aromatic halide of the formula R1X and, in a state capable of providing a continuously available active surface, a metal consisting of sodium, lithium, potassium, a sodium-potassium alloy or sodium amalgam, X being chlorine or bromine, R1 being phenyl, m- or p-tolyl, R being an alkyl group of from 1 to 6 carbon atoms, cyclohexyl, benzyl, unsubstituted phenyl or an alkyl-substituted phenyl in which the alkyl substitutent contains from 1 to 4 carbon atoms, and n being 1 or 2. The metal is either dispersed in a very small particle size or in a liquid or molten condition and the reaction is conducted with agitation. Examples of reactants are given and detailed examples describe the preparation of bis(dimethylamino)phenylborane, dimethylamino(diphenyl)borane, bis(diphenylamino) phenylborane and bis(dimethylamino)-p-tolylborane.

    Abstract translation: 式R 1（3-n）B（NR 2）n的氨基（苯基）硼烷是通过式（R2N）nBX（3-n）的氨基卤代硼烷，式R1X的芳族卤化物， 在能够提供连续可用的活性表面的状态下，由钠，锂，钾，钠 - 钾合金或钠汞齐组成的金属，X为氯或溴，R1为苯基，间或对甲苯基，R为 1至6个碳原子的烷基，环己基，苄基，未取代的苯基或烷基取代的苯基，其中烷基取代基含有1至4个碳原子，n为1或2.金属分散在 非常小的粒度或液体或熔融状态，反应在搅拌下进行。 给出了反应物的实例，详细的实施例描述了双（二甲基氨基）苯基硼烷，二甲基氨基（二苯基）硼烷，双（二苯基氨基）苯基硼烷和双（二甲基氨基）对甲苯基硼烷的制备。

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