公开(公告)号：US06740378B1

公开(公告)日：2004-05-25

申请号：US09645721

申请日：2000-08-24

Applicant: Mark Rule ,  Yu Shi ,  Horst Ehrich

Inventor： Mark Rule ,  Yu Shi ,  Horst Ehrich

IPC: B29D2200

CPC classification number: C08J7/045 ,  B65D1/0215 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31678

Abstract: The coated multilayer structure comprising a polymeric base layer, a zero valent material barrier layer, and a top coat on the zero valent material barrier layer, the top coat comprising a soluble compound capable of reducing the permeability of the multilayer structure to gas or vapor. The zero valent material barrier layer can also enhance barrier to UV light. A method for enhancing the gas or vapor barrier properties or the UV light barrier properties of a multilayer polymeric/inorganic structure is also disclosed. According to one embodiment, Si coated polyethylene terephthalate containers are coated with a gas or vapor barrier enhancing top coat. A method for recycling containers coated with a zero valent material barrier layer is also disclosed.

Abstract translation: 涂层的多层结构包括聚合物基层，零价阻挡层和零价材料阻挡层上的顶涂层，顶涂层包含能够降低多层结构对气体或蒸汽的渗透性的可溶性化合物。 零价材料阻挡层还可以增强对UV光的屏障。 还公开了一种用于增强多层聚合物/无机结构的气体或蒸气阻隔性或UV光阻隔性的方法。 根据一个实施方案，Si涂覆的聚对苯二甲酸乙二醇酯容器涂覆有气体或蒸气阻隔增强顶涂层。 还公开了一种用于回收涂覆有零价阻挡层的容器的方法。

公开(公告)号：US06599569B1

公开(公告)日：2003-07-29

申请号：US09909919

申请日：2001-07-20

Applicant: Heinz Humele ,  Herbert Pickel ,  George Plester ,  Horst Ehrich ,  Mark Rule

Inventor： Heinz Humele ,  Herbert Pickel ,  George Plester ,  Horst Ehrich ,  Mark Rule

IPC: B05D722

CPC classification number: C23C14/10 ,  B29B17/0026 ,  B29K2709/08 ,  B29K2995/0067 ,  B29L2031/7158 ,  Y02W30/62

Abstract: A coated plastic container provides for low permeability to gases and vapors. A method and system for coating plastic containers includes applying a thin inorganic oxide layer to the external surface of the containers with plasma-assisted vacuum vapor deposition. For example, the coating can include silica which is bonded to the external surface of the container. This coating is flexible and can be applied regardless of the container's internal pressure or lack thereof. The coating firmly adheres to the container and possess an enhanced gas barrier effect after pressurization even when the coating is scratched, fractured, flexed and/or stretched. Moreover, this gas barrier enhancement will be substantially unaffected by filling of the container. A method of recycling coated plastic containers and a method and system for packaging a beverage using the coated containers are also disclosed.

Abstract translation: 涂覆的塑料容器提供对气体和蒸气的低渗透性。 用于涂覆塑料容器的方法和系统包括使用等离子体辅助真空气相沉积将薄的无机氧化物层施加到容器的外表面。 例如，涂层可以包括结合到容器外表面的二氧化硅。 该涂层是柔性的，并且可以施加，而不管容器的内部压力或其不足。 即使当涂层被刮伤，断裂，弯曲和/或拉伸时，涂层牢固地粘附到容器上并且在加压之后具有增强的阻气效果。 此外，这种阻气增强将基本上不会通过填充容器而受到影响。 还公开了一种回收涂覆的塑料容器的方法和用于使用涂覆的容器包装饮料的方法和系统。

公开(公告)号：US06274212B1

公开(公告)日：2001-08-14

申请号：US09510014

申请日：2000-02-22

Applicant: Mark Rule ,  Yu Shi ,  Xiaoyan Huang

Inventor： Mark Rule ,  Yu Shi ,  Xiaoyan Huang

IPC: B29D2200

CPC classification number: C08G63/88 ,  Y10T428/1352 ,  Y10T428/1397

Abstract: A method for decreasing acetaldehyde content of melt processed polyester comprising combining with melted polyester an organic additive compound which scavenges acetaldehyde from the polyester without imparting discoloration to the polyester. The organic additive compound comprises at least two hydrogen substituted heteroatoms bonded to carbons of the organic additive compound such that the organic additive compound is reactive with acetaldehyde in the polyester to form water and a resulting organic compound comprising an unbridged five or six member ring including the at least two heteroatoms. The reduced acetaldehyde content polyester is particularly useful for making containers such as for packaging beverages.

Abstract translation: 一种用于降低熔融加工聚酯的乙醛含量的方法，其包括与熔融聚酯结合的有机添加剂化合物，其从聚酯中清除乙醛而不会使聚酯变色。 有机添加剂化合物包含与有机添加剂化合物的碳键合的至少两个氢取代的杂原子，使得有机添加剂化合物与聚酯中的乙醛反应形成水，得到的有机化合物包括未桥连的五或六元环，包括 至少两个杂原子。 还原的乙醛含量的聚酯对于制造用于包装饮料的容器特别有用。

公开(公告)号：US5106941A

公开(公告)日：1992-04-21

申请号：US719444

申请日：1991-06-24

Applicant: Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

Inventor： Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

IPC: C08G63/88 ,  C08K3/34

CPC classification number: C08G63/88 ,  C08K3/34

Abstract: A process for preparing a crystalline poly(cyclohexanedimethylene terephthalate) comprising(A) preparing an admixture of molten poly(cyclohexanedimethylene terephthalate) and a 4A zeolite, and(b) cooling the admixture at a rate less than about 1000.degree. C. per minute to a temperature less than about 80.degree. C.

Abstract translation: 一种制备结晶聚（环己烷二亚甲基对苯二甲酸酯）的方法，其包括（A）制备熔融的聚（环己烷二亚甲基对苯二甲酸酯）和4A沸石的混合物，和（b）以低于约1000℃/分钟的速率将该混合物冷却至 温度低于约80℃

公开(公告)号：US5064937A

公开(公告)日：1991-11-12

申请号：US534338

申请日：1990-06-06

Applicant: David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

Inventor： David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

IPC: C08G75/14

CPC classification number: C08G75/14

Abstract: A process for preparing a polymer having repeating units corresponding to the structure ##STR1## wherein y is in the range of 0.005 to 0.15, x is in the range of 0.02 to 0.25, n is at least 200, and R a divalent aromatic radial. The polymer is prepared by reacting a diiodoaromatic compound and elemental sulfur.

Abstract translation: 制备具有对应于结构图像的重复单元的聚合物的方法，其中y在0.005至0.15的范围内，x在0.02至0.25的范围内，n至少为200，R为二价芳族的径向。 聚合物是通过使二碘代芳族化合物与元素硫反应来制备的。

公开(公告)号：US5026824A

公开(公告)日：1991-06-25

申请号：US522495

申请日：1990-05-14

Applicant: Mark Rule ,  Jerry S. Fauver ,  David R. Fagerburg ,  Paul B. Lawrence ,  Joseph J. Watkins

Inventor： Mark Rule ,  Jerry S. Fauver ,  David R. Fagerburg ,  Paul B. Lawrence ,  Joseph J. Watkins

IPC: C08G75/02 ,  C08G75/14

CPC classification number: C08G75/0236 ,  C08G75/0263 ,  C08G75/14

Abstract: A process for preparing a polymer having repeating units corresponding to the structure ##STR1## wherein R is ##STR2## y is in the range of 0.005 to 0.10, x is in the range of 0.01 to 0.50 when R is ##STR3## x is in the range of 0.01 to 0.30 when R is ##STR4## and n is at least 200. The polymer is prepared by reacting a diiodoaromatic compound and elemental sulfur.

Abstract translation: 制备具有对应于结构> TR图像的重复单元的聚合物的方法，其中R为0.005至0.10，x在0.01至0.50的范围内，当 当R为且n为至少200时，R为，x为0.01至0.30的范围。聚合物通过使二碘代芳族化合物与元素硫反应制备。

公开(公告)号：US4885423A

公开(公告)日：1989-12-05

申请号：US350667

申请日：1989-05-11

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C07C17/26

CPC classification number: C07C17/269

Abstract: A process for preparation of an aromatic dimer compound corresponding to the structureIxAr-ArIxwherein x is 0, 1, 2, 3, 4, or 5 and Ar is a divalent aromatic radical containing 6 to 14 carbon atoms comprising contacting, at a sufficient temperature and pressure in the absence of carbon monoxide and in the absence of an alkali metal compound or an alkaline earth metal compound, platinum and an aromatic iodide compound corresponding to the structureAr-Ixwhere Ar is a monovalent aromatic radical and x is 1, 2, 3, 4, 5, or 6.

Abstract translation: 制备对应于结构IxAr-ArIx的芳族二聚体化合物的方法，其中x为0,1,2,3,4或5，Ar为含有6至14个碳原子的二价芳基，包括以足够的 在不存在一氧化碳的情况下，在不存在碱金属化合物或碱土金属化合物的情况下，对应于结构Ar-Ix的铂和芳香族碘化合物，其中Ar是一价芳族基，x是1， 2，3，4，5或6。

公开(公告)号：US4859762A

公开(公告)日：1989-08-22

申请号：US308924

申请日：1989-02-13

Applicant: Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins

Inventor： Mark Rule ,  David R. Fagerburg ,  Joseph J. Watkins

IPC: C08G75/02

CPC classification number: C08G75/0263 ,  C08G75/0222

Abstract: A process for preparing a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein x is in the range of 0.5 to 0.001 by reacting a mixture of a diiodoaromatic compound and elemental sulfur in the absence of a basic material and in the presence of a catalytic amount of an organic amine-containing compound.

Abstract translation: 制备对应于[（-AS-）1-x（-ASS-）x] n结构的共聚（亚芳基硫醚）的方法，其中x为0.5至0.001的范围内，通过使二碘代芳族化合物和 在不存在碱性物质的情况下和在催化量的含有机胺化合物存在下的元素硫。

公开(公告)号：US4855514A

公开(公告)日：1989-08-08

申请号：US232964

申请日：1988-08-17

Applicant: Mark Rule ,  Regina M. Moncier

Inventor： Mark Rule ,  Regina M. Moncier

IPC: C07C29/38 ,  C07C37/62

CPC classification number: C07C37/62

Abstract: A process for producing iodophenols which comprises contacting phenol, a source of iodine and molecular oxygen in an aqueous medium to produce an iodophenol.

Abstract translation: 一种生产碘酚的方法，其包括使苯酚，碘源和分子氧在水性介质中接触以产生碘苯酚。

公开(公告)号：US4851564A

公开(公告)日：1989-07-25

申请号：US158973

申请日：1988-02-22

Applicant: Guy R. Steinmetz ,  Mark Rule

Inventor： Guy R. Steinmetz ,  Mark Rule

IPC: C07C69/76

CPC classification number: C07C69/76

Abstract: Disclosed is a process for the co-production of aromatic carboxylates and alkyl iodides by the carbonylation of aromatic iodides in the presence of an alkanol and a rhodium catalyst.

Abstract translation: 公开了在烷醇和铑催化剂存在下通过芳族碘化物的羰基化共同生产芳族羧酸盐和烷基碘化物的方法。