摘要:
A method for preparation of a printing plate by an electrophotographic process comprising providing a peelable transfer layer (T) containing a resin (A) capable of being removed upon a chemical reaction treatment on an electrophotographic light-sensitive element, forming a toner image on the transfer layer by an electrophotographic process, providing an adhesive layer (M) containing a thermoplastic resin (B) only on the toner image, transferring the toner image together with the transfer layer (T) and the adhesive layer (M) from the electrophotographic light-sensitive element to a primary receptor, transferring the toner image together with the transfer layer (T) and the adhesive layer (M) from the primary receptor to a receiving material having a surface capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and then removing the transfer layer (T) in the non-image portion on the receiving material by the chemical reaction treatment. According to the method of the present invention, printing plates which produce prints of good image qualities having a lage proportion of image areas can be continuously obtained in a stable manner for a long period of time even when a thickness of the transfer layer is reduced or the transfer is conducted under conditions of low temperature, low pressure and high speed irrespective of the kind of toner employed.
摘要:
A method for preparation of a printing plate by an electrophotographic process comprising providing a peelable transfer layer (T) containing a resin (A) capable of being removed upon a chemical reaction treatment on an electrophotographic light-sensitive element, forming a toner image on the transfer layer by an electrophotographic process, providing an adhesive layer (M) containing a thermoplastic resin (B) only on the toner image, transferring the toner image together with the transfer layer (T) and the adhesive layer (M) from the electrophotographic light-sensitive element to a receiving material having a surface capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and then removing the transfer layer (T) on the receiving material by the chemical reaction treatment.According to the method, printing plates which produces prints of good image qualities can be continuously obtained in a stable manner for a long period of time even when the transfer is conducted under conditions of low temperature, low pressure and high speed.
摘要:
Disclosed is a method for preparation of a printing plate by an electrophotographic process comprising forming a toner image on an electrophotographic light-sensitive element by an electrophotographic process. A peelable transfer layer is provided mainly containing a resin (A) capable of being removed upon a chemical reaction treatment on the toner image. The toner image is transferred together with the transfer layer onto a primary receptor. The toner image together with the transfer layer is then transferred from the primary receptor onto a receiving material having a surface which is capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing. The transfer layer on the receiving material is removed by the chemical reaction treatment.
摘要:
A process of producing a nonaqueous resin dispersion, particularly useful for a liquid developer in electrostatic photographic, which comprises subjecting to photopolymerization a system containing at least a monomer (A) having one polymerizable double bond, which is soluble in a nonaqueous solvent but becomes insoluble upon polymerization thereof, and at least a dispersion stabilizing resin (P) which is a polymer having a weight average molecular weight of from 1.times.10.sup.4 to 1.times.10.sup.6 and containing a specific repeating unit represented by formula (I) in an amount of at least 50% by weight based on the weight of the polymer and has a specific functional group represented by formula (II) bonded to the side chain of the polymer and/or only one terminal of the main chain of the polymer, the photopolymerization reaction being carried out in the nonaqueous solvent by irradiating the system with ultraviolet rays having a wavelength of not longer than 400 n.m.: ##STR1##
摘要:
There is disclosed a liquid developer composition for electrostatic photography, which comprises, in a nonaqueous solvent having an electric resistance of 10.sup.9 .OMEGA..cm or over and a dielectric constant of 3.5 or over, a toner particle, a charge-controlling agent or resin, and an acid group containing polymer soluble in said nonaqueous solvent and/or a quaternary ammonium salt.
摘要:
An electrophotographic lithographic printing plate, in which the effect by the hydrophilic property of non-image areas is further improved, and which is stable during storage even under very severe conditions and capable of readily realizing the hydrophilic property in a short time during processing of rendering hydrophilic is provided by a process for the production of an electrophotographic lithographic printing plate, comprising subjecting an electrophotographic photoreceptor to imagewise exposure and forming a toner image, the electrophotographic photoreceptor comprising an electroconductive support having provided thereon at least one photoconductive layer containing photoconductive inorganic compound and a binder resin, the binder resin comprising at least one resin (P) as defined herein, and optionally at least one crosslinking agent, and then subjecting a non-image area of the photoconductive layer to an oil-desensitizing processing with a processing solution containing a hydrophilic compound containing a substituent having a Pearson's nucleophilic constant n of at least 5.5.
摘要:
An electrophotographic light-sensitive material comprising a support having provided thereon at least one photoconductive layer containing an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises at least one resin (A) or (A') and at least one resin (B) as described above. The electrophotographic light-sensitive material according to the present invention is excellent in electrostatic characteristics, moisture resistance and durability.
摘要:
An electrophotographic light-sensitive material having a photoconductive layer containing at least an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (A) at least one AB block copolymer (Resin (A)) having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and composed of an A block comprising at least one polymer component containing at least one acidic group as described herein, and a B block containing at least a polymer component represented by formula (I) described herein, wherein the content of the polymer containing the acidic group in the AB block copolymer is from 0.5 to 20 parts by weight per 100 parts by weight of the AB block copolymer; and (B) at least one copolymer (Resin (B)) having a weight average molecular weight of not less than 3.times.10.sup.4 and formed from at least a monofunctional macromonomer (MB) described herein having a weight average molecular weight of not more than 2.times.10.sup.4 and a monomer represented by general formula (V) described herein.
摘要:
An electrophotographic light-sensitive material comprising a support having provided thereon a photoconductive layer containing at least an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (1) at least one graft type copolymer (Resin (A)) having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and containing, as a copolymerizable component, at least one mono-functional macromonomer (M) comprising an AB block copolymer being composed of an A block comprising at least one polymerizable component containing at least one acidic group selected from --PO.sub.3 H.sub.2, --COOH, --SO.sub.3 H, a phenolic hydroxyl group, ##STR1## (wherein R represents a hydrocarbon group or --OR' (wherein R' represents a hydrocarbon group)) and a cyclic acid anhydride-containing group, and a B block containing at least one polymerizable component represented by the general formula (I) and having a polymerizable double bond group bonded to the terminal of the main chain of the B block polymer ##STR2## and (2) at least one resin (Resin (B)) having a weight average molecular weight of 5.times.10.sup.4 or more, containing a repeating unit represented by the general formula (III) as a copolymerizable component, and having a crosslinked structure made before the preparation of a dispersion for forming the photoconductive layer ##STR3##
摘要:
An electrophotographic light-sensitive material comprising a support having provided thereon at least one photoconductive layer containing an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (A) at least one resin having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and containing not less than 30% by weight of a copolymerizable component corresponding to a repeating unit represented by the general formula (I) described below and from 0.5 to 20% by weight of a copolymerizable component having at least one acidic group selected from the group consisting of --PO.sub.3 H.sub.2, --SO.sub.3 H, --COOH, --OH, ##STR1## (wherein R represents a hydrocarbon group or --OR' (wherein R' represents a hydrocarbon group)) and a cyclic acid anhydride-containing group; ##STR2## wherein a.sub.1 and a.sub.2 each represents a hydrogen atom, a halogen atom, a cyano group or a hydrocarbon group; and R.sub.1 represents a hydrocarbon group; and (B) at least one copolymer having a weight average molecular weight of from 5.times.10.sup.4 to 1.times.10.sup.6 and comprising at least a monofunctional macromonomer (M) and a monomer represented by the general formula (V) described below. ##STR3##