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公开(公告)号：US20090242460A1
公开(公告)日：2009-10-01
申请号：US12055901
申请日：2008-03-26
IPC分类号： C10G45/04
CPC分类号： C10G27/04 , C10G2300/202 , C10G2300/206 , C10G2300/802
摘要： A method for purifying a sulfur-containing fuel oil comprising (a) contacting the fuel oil with a supported exogenous binary catalyst and oxygen at a temperature in a range of from about 25° C. to about 150° C., and at a pressure in a range of from about 1 atmosphere to about 150 atmospheres to provide a first oxidized mixture; and (b) separating at least one oxidized sulfur compound from the first oxidized mixture to a provide a purified fuel oil. In one embodiment, the sulfur-containing fuel oil is deasphalted prior to contacting with the supported exogenous binary catalyst and oxygen.
摘要翻译： 一种用于纯化含硫燃料油的方法，包括（a）在约25℃至约150℃的温度和压力下使燃料油与负载的外源二元催化剂和氧接触 在约1大气压至约150大气压的范围内，以提供第一氧化混合物; 和（b）将至少一种氧化的硫化合物从第一氧化混合物中分离出来提供纯化的燃料油。 在一个实施方案中，含硫燃料油在与负载的外源二元催化剂和氧接触之前脱沥青。
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公开(公告)号：US20090242458A1
公开(公告)日：2009-10-01
申请号：US12055916
申请日：2008-03-26
IPC分类号： C10G45/04
摘要： A method for purifying a sulfur-containing fuel oil comprising (a) contacting in a first reaction mixture the sulfur-containing fuel oil with a water-soluble organic acid and oxygen at a temperature in a range of from about 100° C. to about 250° C., and at a pressure in a range of from about 15 pounds per square inch to about 2500 pounds per square inch to provide a first oxidized mixture, (b) adding water to provide a biphasic mixture comprising a water-rich phase and a fuel oil-rich phase, and (c) separating the water-rich phase from the fuel oil-rich phase to provide a purified fuel oil. In one embodiment, the method may further include an oxidation catalyst. In one embodiment, the method may further include a carbonaceous promoter. In one embodiment, the sulfur-containing fuel oil may be deasphalted before contacting with the water-soluble organic acid.
摘要翻译： 一种用于净化含硫燃料油的方法，包括（a）在第一反应混合物中使含硫燃料油与水溶性有机酸和氧在约100℃至约 250℃，压力范围为约15磅/平方英寸至约2500磅/平方英寸，以提供第一氧化混合物，（b）加水以提供包含富水相的两相混合物 和富燃料相，和（c）从富燃相中分离富水相以提供纯化燃料油。 在一个实施方案中，该方法还可以包括氧化催化剂。 在一个实施方案中，该方法可以进一步包括碳质促进剂。 在一个实施方案中，含硫燃料油在与水溶性有机酸接触之前可以脱沥青。
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公开(公告)号：US20080248339A1
公开(公告)日：2008-10-09
申请号：US11766970
申请日：2007-06-22
CPC分类号： H01M8/22 , H01M4/90 , H01M4/92 , H01M4/921 , H01M8/04186 , H01M8/04201 , H01M8/06 , H01M8/186 , H01M2008/1095 , Y02E60/528
摘要： An electrochemical energy conversion system comprises an electrochemical energy conversion device, in fluid communication with a source of liquid carrier of hydrogen and an oxidant, for receiving, catalyzing and electrochemically oxidizing at least a portion of the hydrogen to generate electricity, a hydrogen depleted liquid, and water. A method of electrochemical energy conversion includes the steps of directing a liquid carrier of hydrogen to an electrochemical conversion device and electrochemically dehydrogenating the liquid carrier of hydrogen in the presence of a catalyst to produce electricity.
摘要翻译： 电化学能量转换系统包括电化学能量转换装置，其与氢气和氧化剂的液体载体源流体连通，用于接收，催化和电化学氧化至少一部分氢气以产生电，贫氢液体， 和水。 电化学能量转换的方法包括将氢的液体载体引导到电化学转化装置并在催化剂存在下电化学脱氢氢气以产生电力的步骤。
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公开(公告)号：US07399729B2
公开(公告)日：2008-07-15
申请号：US10743646
申请日：2003-12-22
申请人： Teresa Grocela Rocha , Jonathan Lloyd Male , Jennifer Kathleen Redline , Alison Liana Palmatier , Kaidong Chen , Dan Hancu , Grigorii Lev Soloveichik , Eric Budesheim , Aaron Joseph Simon
发明人： Teresa Grocela Rocha , Jonathan Lloyd Male , Jennifer Kathleen Redline , Alison Liana Palmatier , Kaidong Chen , Dan Hancu , Grigorii Lev Soloveichik , Eric Budesheim , Aaron Joseph Simon
IPC分类号： B01J23/40
CPC分类号： B01J23/66 , B01D53/8628 , B01D2255/20 , B01J23/08 , B01J23/24 , B01J23/825 , B01J23/835
摘要： A catalyst system comprising a catalyst and a reductant is disclosed. The catalyst comprises a metal oxide catalyst support, a catalytic metal oxide, and a promoting metal. The catalytic metal oxide comprises gallium oxide, indium oxide or a combination of the two. The promoting metal comprises at least one of silver, cobalt, vanadium, molybdenum, tungsten, zinc, tin and bismuth. The catalyst comprises about 5 to about 31 mol % catalytic metal oxide and about 0.5 to about 9 mol % promoting metal. The reductant comprises a fluid hydrocarbon having at least 4 carbon atoms. Also disclosed is a process for reducing NOx to N2 using the disclosed catalyst system by mixing NOx with a reductant and passing the mixture through a catalyst of the disclosed catalyst system.
摘要翻译： 公开了一种包含催化剂和还原剂的催化剂体系。 催化剂包括金属氧化物催化剂载体，催化金属氧化物和促进金属。 催化金属氧化物包括氧化镓，氧化铟或两者的组合。 促进金属包括银，钴，钒，钼，钨，锌，锡和铋中的至少一种。 催化剂包含约5至约31摩尔％的催化金属氧化物和约0.5至约9摩尔％的促进金属。 还原剂包括具有至少4个碳原子的流体烃。 还公开了使用公开的催化剂体系通过将NO x x与还原剂混合并使混合物通过的方法将NO 2 x 2还原为N 2 所公开的催化剂体系的催化剂。
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公开(公告)号：US07381390B2
公开(公告)日：2008-06-03
申请号：US11305914
申请日：2005-12-19
IPC分类号： C01B6/21
CPC分类号： C01B6/21
摘要： Disclosed herein is a method comprising reacting a metal borohydride with a metal chloride composition that comprises magnesium chloride in a solvent to form a reaction mixture; wherein either the metal borohydride, the metal chloride composition or both the metal borohydride and the metal chloride composition are soluble in the solvent and a formed metal chloride is insoluble in the solvent; removing the solvent from the reaction mixture to produce a borohydride complex; treating the borohydride complex to obtain magnesium borohydride; extracting magnesium borohydride solvate; and desolvating the magnesium borohydride solvate to form magnesium borohydride.
摘要翻译： 本文公开了一种方法，其包括使金属硼氢化物与金属氯化物组合物反应，所述金属氯化物组合物在溶剂中包含氯化镁以形成反应混合物; 其中金属硼氢化物，金属氯化物组合物或金属硼氢化物和金属氯化物组合物都溶于溶剂中，形成的金属氯化物不溶于溶剂; 从反应混合物中除去溶剂以产生硼氢化物络合物; 处理硼氢化物复合物得到硼氢化镁; 提取硼氢化镁溶剂合物; 并将硼氢化镁溶剂化物脱醇形成硼氢化镁。
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96.发明授权Catalyst composition and method for producing diaryl carbonates, using bisphosphines 失效催化剂组合物和使用双膦生产碳酸二芳基酯的方法公开(公告)号：US06617279B2
公开(公告)日：2003-09-09
申请号：US09780701
申请日：2001-02-12
IPC分类号： B01J3100
CPC分类号： C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphosphine such as 1,3-bis(diphenylphosphino)propane or 1,4-bis(diphenylphosphino)butane. The catalyst system also preferably contains a compound of cerium or lead.
摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碘化物盐，优选碘化钠; 和至少一种有机双膦，例如1,3-双（二苯基膦基）丙烷或1,4-双（二苯基膦基）丁烷。 催化剂体系还优选含有铈或铅的化合物。
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97.发明授权Catalyst composition and method for producing diaryl carbonates, using bisphosphines 失效催化剂组合物和使用双膦生产碳酸二芳基酯的方法公开(公告)号：US06215015B1
公开(公告)日：2001-04-10
申请号：US09550202
申请日：2000-04-17
IPC分类号： C07C6800
CPC分类号： C07C68/005 , C07C69/96
摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an iodide salt, preferably sodium iodide; and at least one organic bisphosphine such as 1,3-bis(diphenylphosphino)propane or 1,4-bis(diphenylphosphino)butane. The catalyst system also preferably contains a compound of cerium or lead.
摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碘化物盐，优选碘化钠; 和至少一种有机双膦，例如1,3-双（二苯基膦基）丙烷或1,4-双（二苯基膦基）丁烷。 催化剂体系还优选含有铈或铅的化合物。
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公开(公告)号：US6160155A
公开(公告)日：2000-12-12
申请号：US301699
申请日：1999-04-29
申请人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Grigorii Lev Soloveichik
发明人： James Lawrence Spivack , Donald Wayne Whisenhunt, Jr. , James Norman Cawse , Grigorii Lev Soloveichik
CPC分类号： B01J31/0231 , B01J31/0239 , B01J31/0251 , B01J31/0271 , B01J31/2234 , B01J2231/34 , B01J2531/16 , B01J2531/38 , B01J2531/46 , B01J2531/54 , B01J2531/62 , B01J2531/72 , B01J2531/824 , B01J2531/842 , B01J2531/847 , C07C68/005 , C07C69/96
摘要： A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing ytterbium. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.
摘要翻译： 用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，本发明提供了一种通过在包含催化量的含有镱的无机助催化剂的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触而使芳族羟基化合物羰基化的方法。 在各种替代实施方案中，羰基化催化剂体系可以包括有效量的钯源和有效量的卤化物组合物。 另外的替代实施方案可以包括催化量的各种无机助催化剂组合。
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