Use of 4-nitro-2,1,3,-benzoxadiazole derivatives as dyes in coloring agents for keratin fibres
    96.
    发明授权
    Use of 4-nitro-2,1,3,-benzoxadiazole derivatives as dyes in coloring agents for keratin fibres 有权
    在作为角蛋白纤维的着色剂中使用4-硝基-2,1,3'-苯并恶唑衍生物作为染料

    公开(公告)号:US06749645B2

    公开(公告)日:2004-06-15

    申请号:US10089207

    申请日:2002-03-26

    IPC分类号: A61K713

    CPC分类号: A61Q5/10 A61K8/49 A61Q5/065

    摘要: The object of the present invention is the use of 4-nitro-2,1,3-benzoxadiazole derivatives of general formula (I) as dye in colorants for keratin fibers such as, for example, wool, silk, furs or hair and particularly human hair In formula (I) X denotes oxygen, sulfur or NRa, Ra standing for hydrogen, a (C1-C4)-alkyl group, a monohydroxy-(C1-C4)-alkyl group, a polyhydroxy-(C2-C4)-alkyl group or a mono-(C1 C4)-alkoxy-(C1-C4)-alkyl group, R1 and R2 can be equal or different and independently of each other denote hydrogen, a halogen atom, a (C1-C4)-alkyl group, a halogen-substituted (C1-C4)-alkyl group, a (C1-C4)-alkoxy group, a nitro group or an NRbRc group, the Rb and Rc groups being equal or different and independently of each other denoting hydrogen, a (C1-C4)-alkyl group, an optionally substituted aromatic carbon ring or a (C1-C4)-alkanecarbonyl group, or Rb and Rc together with the nitrogen atom forming a heterocyclic (C3-C6) group, and Q denotes hydrogen, an aliphatic group, an aromatic isocyclic group or an aromatic heterocyclic group.

    摘要翻译: 本发明的目的是通式(I)的4-硝基-2,1,3-苯并二唑衍生物作为染色剂用于角蛋白纤维例如羊毛,丝绸,毛皮或毛发的用途,特别是 式(I)X表示氧,硫或NR a,R 5代表氢,(C 1 -C 4) - 烷基,单羟基 - (C 1 -C 4) - 烷基,多羟基 - (C 2 -C 4) - 烷基或单 - (C 1 -C 4) - 烷氧基 - (C 1 -C 4) - 烷基,R 1和R 2可以相同或不同,彼此独立地表示氢,卤素原子,( C 1 -C 4) - 烷基,卤素取代的(C 1 -C 4) - 烷基,(C 1 -C 4) - 烷氧基,硝基或NR b R c基团,R b (C 1 -C 4) - 烷基,任选取代的芳族碳环或(C 1 -C 4) - 烷基羰基或R b可以相同或不同且彼此独立地表示氢, 和R c与形成杂环(C 3 -C 6)基团的氮原子一起形成,Q表示氢,脂肪族碳 芳香族杂环基或芳香族杂环基。

    Process for dyeing keratin fibers comprising 1,4-diamino-2-methoxymethylbenzene and salts thereof
    98.
    发明授权
    Process for dyeing keratin fibers comprising 1,4-diamino-2-methoxymethylbenzene and salts thereof 有权
    染色包含1,4-二氨基-2-甲氧基甲基的角蛋白纤维及其盐的方法

    公开(公告)号:US06558433B2

    公开(公告)日:2003-05-06

    申请号:US10132352

    申请日:2002-04-25

    IPC分类号: A61K713

    CPC分类号: A61Q5/10 A61K8/411 C07C217/76

    摘要: The method of dyeing keratin fibers includes the steps of providing an oxidation dye precursor composition containing from 0.01 to 10 percent by weight of a total amount of at least one coupler compound and at least one developer compound, mixing the oxidation dye precursor composition with an oxidizing agent and applying the resulting mixture to the keratin fibers. The oxidation dye precursor composition is characterized by containing 1,4-diamino-2-methoxymethylbenzene, or a physiologically compatible salt thereof, either alone as sole developer compound, or in combination with other known developer compounds. The oxidation dye precursor composition can also contain at least one direct-dyeing dye compound and conventional cosmetic additive ingredients.

    摘要翻译: 染色角蛋白纤维的方法包括以下步骤:提供氧化染料前体组合物,其含有0.01至10重量%的总量的至少一种成色剂化合物和至少一种显色剂化合物,将氧化染料前体组合物与氧化 并将所得混合物施加到角蛋白纤维上。 氧化染料前体组合物的特征在于含有1,4-二氨基-2-甲氧基甲基苯或其生理上相容的盐,单独作为唯一的显影剂化合物,或与其它已知的显影剂化合物组合。 氧化染料前体组合物还可以含有至少一种直接染色染料化合物和常规化妆品添加剂成分。

    Means and method for dying keratinic fibers
    99.
    发明授权
    Means and method for dying keratinic fibers 有权
    染色角蛋白纤维的方法和方法

    公开(公告)号:US06503282B1

    公开(公告)日:2003-01-07

    申请号:US09913553

    申请日:2001-08-15

    IPC分类号: A61K713

    摘要: Composition for coloring keratin fibers based on a developer-coupler combination characterized in that it contains as the coupler 3-(2,4-diaminophenoxy)-1-propanol and as the developer a p-phenylenediamine derivative monosubstituted on the benzene ring and having general formula (I)  and/or a 4,5-diamino-1H-pyrazole derivative of general formula (II)  and/or a p-aminophenol derivative of general formula (III)  as well as a method for the oxidative coloring of hair, and the use of said composition.

    摘要翻译: 用于着色基于显色剂 - 成色剂组合的角蛋白纤维的组合物,其特征在于其含有作为3-(2,4-二氨基苯氧基)-1-丙醇的成色剂和作为在苯环上单取代的显影剂对苯二胺衍生物,并具有通式 (I)和/或通式(II)的4,5-二氨基-1H-吡唑衍生物和/或通式(III)的对氨基苯酚衍生物以及用于氧化着色头发的方法,以及使用 的所述组合物。

    Means and method for tinting keratin fibers, particularly human hair
    100.
    发明授权
    Means and method for tinting keratin fibers, particularly human hair 失效
    用于着色角蛋白纤维,特别是人类头发的方法和方法

    公开(公告)号:US06224856B1

    公开(公告)日:2001-05-01

    申请号:US09091090

    申请日:1998-06-11

    IPC分类号: A61K706

    CPC分类号: A61Q5/10 A61K8/411 A61K8/415

    摘要: The dye precursor-containing composition for hair dyeing contains at least one p-aminophenol derivative compound of the formula (I): in which R1 and R2 each can be H, an alkyl, a hydroxyalkyl, an aminoalkyl, a mono- or dialkylaminoalkyl, an acylaminoalkyl, an aryl- or alkylsulfonylaminoalkyl, a carbamidoalkyl, an acyl, an aryl, an alkylsulfonyl or a carbomoyl group, each alkyl group having from 1 to 4 carbon atoms, or R1 and R2 together are part of a heterocyclic, non-aromatic 5- or 6-membered ring, with or without an oxo group; at least one 5-amino-2-methylphenol derivative compound of the formula (II), in which R is H, a C1- to C4-alkyl, a C2- to C4-hydroxyalkyl group or a C2- to C4- polyhydroxyalkyl group; and at least one m-phenylenediamine derivative compound of the formula (III), in which R1 and R2 each can be H, a C1- to C4-alkyl, a C2- to C4-hydroxyalkyl or a C3- to C4-polyhydroxyalkyl group; R3 stands for H, a C1- to C6-alkyl, a C1- to C4-alkoxy, a C2- to C4-hydroxyalkyl or a C3- to C4-polyhydroxyalkyl group; and R4 stands for H, a C1- to C6-alkyl, a C2- to C4-alkoxy, a C2- to C4-hydroxyalkyl or a C3- to C4-polyhydroxyalkyl group.

    摘要翻译: 用于染发染料前体的组合物含有至少一种式(I)的对氨基苯酚衍生物化合物:其中R 1和R 2各自可以是H,烷基,羟烷基,氨基烷基,一或二烷基氨基烷基, 酰基氨基烷基,芳基或烷基磺酰氨基烷基,氨基甲酰氨基烷基,酰基,芳基,烷基磺酰基或甲酰基,每个烷基具有1至4个碳原子,或者R1和R2一起是杂环,非芳族 5-或6-元环,具有或不具有氧代基团; 至少一种式(II)的5-氨基-2-甲基苯酚衍生物化合物,其中R为H,C 1至C 4 - 烷基,C 2至C 4 - 羟基烷基或C 2至C 4 - 多羟基烷基 ; 和至少一种式(III)的间苯二胺衍生物化合物,其中R 1和R 2各自可以是H,C 1 -C 4烷基,C 2 -C 4羟基烷基或C 3 -C 4多羟基烷基 ; R3代表H,C 1至C 6 - 烷基,C 1至C 4 - 烷氧基,C 2至C 4 - 羟基烷基或C 3 -C 4 - 多羟基烷基; 并且R4代表H,C 1至C 6 - 烷基,C 2至C 4 - 烷氧基,C 2至C 4 - 羟基烷基或C 3至C 4 - 多羟基烷基。