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91.发明授权Catalyst and process for producing aromatic compounds from C.sub.2 -C.sub.6 失效用于从C2-C6脂族烃生产芳族化合物的催化剂和方法
公开(公告)号：US5169812A
公开(公告)日：1992-12-08
申请号：US760294
申请日：1991-09-16
CPC分类号： B01J29/40 , C07C2/00 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2527/167 , C07C2529/04
摘要： A catalyst for converting C.sub.2 to C.sub.6 aliphatic hydrocarbons to aromatics is described. The catalyst contains a zeolite, an aluminum phosphate binder and a gallium component. Examples of zeolites which can be used are the ZSM family of zeolites, with ZSM-5 being a specific example. The catalyst is characterized in that it is tolerant to exposure to hydrogen at tempertures of about 500.degree. to about 700.degree. C. The catalyst's tolerance to hydrogen exposure is the result of treating the catalyst with an aqueous solution of a weakly acidic ammonium salt or a dilute acid solution at a temperature of about 50.degree. to about 100.degree. C. for a time of about 1 to about 48 hours, followed by calcination. A process for preparing the catalyst is also described.
摘要翻译： 描述了将C2转化为C6脂族烃到芳族化合物的催化剂。 催化剂含有沸石，磷酸铝粘合剂和镓成分。 可以使用的沸石的实例是沸石的ZSM族，ZSM-5是具体的实例。 该催化剂的特征在于它在约500℃至约700℃的温度下耐受暴露于氢气。催化剂对暴露于氢的耐受性是用弱酸性铵盐或 稀酸溶液在约50℃至约100℃的温度下搅拌约1至约48小时，然后煅烧。 还描述了制备催化剂的方法。
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公开(公告)号：US4783567A
公开(公告)日：1988-11-08
申请号：US123828
申请日：1987-11-23
申请人： Joseph A. Kocal
发明人： Joseph A. Kocal
CPC分类号： C07C2/70 , C07C2/62 , C07C2527/054 , C07C2527/1206 , Y02P20/582
摘要： A novel liquid acid catalyzed alkylation process is disclosed which incorporates a fixed bed of contact material to improve the alkylation reaction zone efficiency. The fixed bed of contact material also allows the process to be efficiently operated at lower acid to olefin mole/mole feed ratios than normally used.
摘要翻译： 公开了一种新的液体酸催化的烷基化方法，其包含固定的接触材料床以改善烷基化反应区效率。 接触材料的固定床还允许该方法以比通常使用的更低的酸与烯烃摩尔/摩尔进料比进行有效的操作。
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公开(公告)号：US4783566A
公开(公告)日：1988-11-08
申请号：US90480
申请日：1987-08-28
CPC分类号： B01J29/90 , B01J38/12 , C07C2/76 , C07C2529/40 , Y02P20/584
摘要： A hydrocarbon conversion process is disclosed which extends the useful life of a regenerable zeolite-containing hydrocarbon conversion catalyst. In one aspect of this process, a hydrocarbon feed containing fluorides is passed through a fluoride removal system which reduces the fluoride concentration of the feed to below 100 ppb. The hydrocarbon feed containing less than 100 ppb fluorine is then converted over a regenerable zeolite-containing hydrocarbon conversion catalyst. The zeolite-containing hydrocarbon conversion catalyst is regenerated with an oxygen-containing gas stream as necessary to burn off carbonaceous deposits on the catalyst so as to return the zeolite catalyst to a high level of activity.
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94.发明授权Process for producing aromatic compounds from C.sub.2 -C.sub.6 aliphatic hydrocarbons 失效由C2-C6脂肪族烃制造芳族化合物的方法
公开(公告)号：US4746763A
公开(公告)日：1988-05-24
申请号：US41279
申请日：1987-04-22
申请人： Joseph A. Kocal
发明人： Joseph A. Kocal
CPC分类号： C07C2/76 , B01J29/44 , C07C2521/04 , C07C2523/08 , C07C2529/40
摘要： The present invention relates to a process for producing aromatic compounds from C.sub.2 -C.sub.6 aliphatic hydrocarbons. In this process, a feedstock containing C.sub.2 -C.sub.6 aliphatic hydrocarbons is passed into a reaction zone and into contact with a catalyst zone containing two discrete catalysts. The first catalyst of the discrete catalyst system is comprised in part of a ZSM-5 zeolite component while the second catalyst of the discrete catalyst system is comprised in part of a catalytically active component that is not ZSM-5 which exhibits an acidity lower than that of the first discrete catalyst. A metallic component selected from the Group IIB to IVB Elements of the Periodic Table may be a component of one or both of the discrete catalysts of the instant process as can be a phosphorus-containing alumina component. The discrete catalytic system of the present invention is particularly suited for selectively producing aromatic compounds from C.sub.2 -C.sub.6 aliphatic hydrocarbons while limiting the amount of undesired C.sub.1 and C.sub.2 by-products produced by the process.
摘要翻译： 本发明涉及由C2-C6脂肪族烃制造芳族化合物的方法。 在该方法中，将含有C 2 -C 6脂族烃的原料进入反应区并与含有两个离散催化剂的催化剂区接触。 离散催化剂体系的第一催化剂包含在部分ZSM-5沸石组分中，而离散催化剂体系的第二催化剂是部分催化活性组分，其不是ZSM-5，其表现出比其低的酸度 的第一离散催化剂。 选自元素周期表IIB至IVB族元素的金属组分可以是本发明方法的一种或两种离散催化剂的组分，可以是含磷氧化铝组分。 本发明的离散催化体系特别适用于选择性地从C2-C6脂族烃选择性地生产芳族化合物，同时限制了由该方法产生的不期望的C1和C2副产物的量。
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公开(公告)号：US4665271A
公开(公告)日：1987-05-12
申请号：US887778
申请日：1986-07-21
申请人： Tamotsu Imai , Joseph A. Kocal
发明人： Tamotsu Imai , Joseph A. Kocal
CPC分类号： B01J31/0204 , C07C2/62 , B01J2231/323 , B01J27/12 , C07C2527/1206 , C07C2531/02
摘要： A novel hydrocarbon alkylation catalyst is disclosed comprising a mineral acid and an ether component. A process for utilizing the novel catalyst is also disclosed.
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