Fluorinated phenanthrenes and their use in liquid-crystal mixtures

    公开(公告)号:US07399505B2

    公开(公告)日:2008-07-15

    申请号:US11122856

    申请日:2005-05-05

    CPC分类号: C09K19/32 Y10T428/10

    摘要: Compounds of the formula (I) are described in which M1 is, for example, —CO—O— or a single bond A1 is, for example, 1,4-phenylene, R5 has the same possible definitions specified for R1, with the exception of -M1-A1-R5, but independently of the definition of R1 G1-G2 is CH2CH2, CH═CH, CF2CF2, CF═CF, CF═CH, CH═CF X1, X2, X3, X4, X5 are each independently H or F R1, Y1, Y2 are each independently a) H b) F where Y1, R1, (R1 and Y1) or (R1 and Y2) may also have the definitions c) and/or d), but only in each case not more than one of (R1 and Y1) and of (R1 and Y2) may have the definition d) c) is, for example, a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, d) -M1-A1-R5 with the following provisos: a) at least one of X1, X2, X3, X4, X5, G1-G2 is or contains F b1) when at least one of Y1 and X1 is F and/or G1-G2 contains F, it is possible for R1, X2, X3, X4 not to be F b2) when at least one of R1, X2, X3, X4 is F, it is possible for X1 and Y1 not to be F, and for G1-G2 to be CH2CH2 or CH═CH c) it is not possible for Y2 and X5 simultaneously to be F.

    Fluorinated heterocycles and their use in liquid-crystal mixtures
    95.
    发明授权
    Fluorinated heterocycles and their use in liquid-crystal mixtures 有权
    氟化杂环及其在液晶混合物中的应用

    公开(公告)号:US07255900B2

    公开(公告)日:2007-08-14

    申请号:US11117280

    申请日:2005-04-28

    摘要: In the compound of the formula (I), where: R1, R2 are each independently, for example, H or a straight-chain or branched alkyl radical p, q are each independently 0 or 1, i.e. at the value zero, —H is present at the appropriate position instead of —F M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—CO——O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond A1 is, for example, 1,4-phenylene R5 has the same possible definitions as specified for R1 and R2, with the exception of —M1—A1—R5, but independently of the definition of R1 and R2 X is H, F, OF3, CF3, OCF2H with the following provisos: a) at least one of p, q has to be 1 b) R1 and R2 must not at the same time be H c) R2 and X must not at the same time be H.

    摘要翻译: 在式(I)的化合物中,其中:R 1,R 2各自独立地为例如H或直链或支链烷基p, q各自独立地为0或1,即在零值时,-H存在于适当的位置,而不是-FM 1是-CO-O-,-O-CO-,-CH O 2,-O-CH 2 - , - CO 2 -O - , - O-CF 2 -O - , - O-CH 2 - , - CH-CH - , - CFF - , - C≡C - , - CH 2 -CH 2 -CO - O-, - O -CO-CH 2 -CH 2 - , - CH 2 -CH 2 - , - CFF - (CH 2)4 - , - OC(-O)CF-CF-(CH 2)2 - 或单键A 1,例如,1,4-亚苯基R 5具有与R 1和R 2相同的可能定义, R< 2>除了-M 1以上的1〜5,但与定义 R 1,R 2,X 2是H,F 3,CF 3,OCF 3, 2 H,具有以下条件:a)至少 p,q中的一​​个必须为1b)R 1和R 2不能同时为H c)R 2和/或 X不能同时为H.

    Fluorinated heterocycles and their use in liquid-crystal mixtures
    96.
    发明申请
    Fluorinated heterocycles and their use in liquid-crystal mixtures 有权
    氟化杂环及其在液晶混合物中的应用

    公开(公告)号:US20050056812A1

    公开(公告)日:2005-03-17

    申请号:US10903937

    申请日:2004-07-30

    摘要: Compounds of the general formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(═O)O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C≡C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q are each independently 0 or 1 G1-G2 is —CH2CH—, —CH═C—, —CH2CH2CH— or —CH═CH—CH— M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C═C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen atoms may be replaced by CH3 and/or F, 1-cyclohexene-1,4-diyl, where one hydrogen atom may be replaced by CH3 or F, or 1,3-dioxane-2,5-diyl, R5 has the same possible definitions as R1 and R2, with the exception of -M1-A1-R5 with the provisos that: a) at least one of p, q is 1, b) R1 and R2 must not at the same time be H. are used in liquid-crystal mixtures.

    摘要翻译: 通式(I)的化合物其中:R 1,R 2各自独立地为a)H b)-M 1 -A 1 -R 5 c)直链或支链 具有1至16个碳原子的烷基或具有2至16个碳原子的直链或支链烯基,其中c1)一个或多个不相邻和非末端CH2基团可以被-O - , - C(= O )O-,-OC(= O) - , - OC(= O)-O - , - C(= O) - 或-Si(CH 3)2 - 和/或c2)一个CH 2基团可以被 -C = C-,环丙烷-1,2-二基,环丁烷-1,3-二基,环己烷-1,4-二基或亚苯基-1,4-二基,和/或c3)一个或多个氢原子可以是 由F和/或Cl取代,p,q各自独立地为0或1,G 1 -G 2为-CH 2 CH - , - CH = C - , - CH 2 CH 2 CH-或-CH = CH-CH- 1是-CO-O-,-O-CO-,-CH2-O-,-O-CH2-,-CF2-O-,-O-CF2-,-CH = CH-,-CF = CF- ,-C = C-,-CH2-CH2-CO-O-,-O-CO-CH2-CH2-,-CH2-CH2-,-CF2-CF2-, - (CH2)4-,-OC(= O)CF = CF-或单键,A 1是1,4-亚苯基,其中一个或两个氢原子可以被F,Cl,CN和/或OCF 3取代,或多达三个hy 可以用氟,1,4-亚环己基代替氢原子,其中一个或两个氢原子可被CH 3和/或F,1-环己烯-1,4-二基代替,其中一个氢原子可被CH 3或F ,或1,3-二恶烷-2,5-二基,R 5具有与R 1和R 2相同的可能定义,但-M 1 -A 1 -R <5>,条件是:a)p,q中的至少一个为1,b)R 1和R 2不能同时为H.用于液晶混合物中。

    Fluorinated cyclopenta[b]naphthalenes and their use in liquid-crystal mixtures
    97.
    发明授权
    Fluorinated cyclopenta[b]naphthalenes and their use in liquid-crystal mixtures 有权
    氟化环戊二烯并[b]萘及其在液晶混合物中的应用

    公开(公告)号:US06759103B2

    公开(公告)日:2004-07-06

    申请号:US10241881

    申请日:2002-09-12

    IPC分类号: C09K1932

    摘要: The invention relates to compounds of the formula (I) and also liquid-crystal mixtures comprising these compounds, and their use in liquid-crystal displays: in which R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical, R2 is H, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical, M1 and M2 are —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2—, —CF═CF—C(═O)O— or a single bond A1 and A2 are &agr;-1,4-diyl, unsubstituted or mono- or disubstituted by F; where &agr; is: phenylene cyclohexane, 1-cyclohexene, or 1,3-dioxane-2,5-diyl m and n are zero or 1; m+n=0 or 1 L1, L2, L3, L4 and L5 are H or F.

    摘要翻译: 本发明涉及式(I)化合物以及包含这些化合物的液晶混合物及其在液晶显示器中的应用:其中R 1是H,F,CF 3,OCF 3,OCF 2 H,OCFH 2,烷基 自由基或烷氧基或链烯基或烯氧基,R 2是H,烷基或烷氧基或链烯基或烯氧基,M 1和M 2是-C(= O)O - , - OC(= O) - , - CH 2 O - , - OCH 2 - , - OCF 2 - , - CF 2 O - , - C≡C-, - CH 2 CH 2 - , - CF 2 CF 2 - , - CF = O-或单键A 1和A 2是被F取代的未取代或单取代或二取代的α-1,4-二基; 其中α是:亚苯基环己烷,1-环己烯或1,3-二恶烷-2,5-二基,n是0或1; m + n = 0或1L 1,L 2,L 3,L 4和L 5为H或F.

    Tetrahydrothiophene derivatives, and their use in liquid-crystalline mixtures
    100.
    发明授权
    Tetrahydrothiophene derivatives, and their use in liquid-crystalline mixtures 失效
    四氢噻吩衍生物,以及它们在液晶混合物中的应用

    公开(公告)号:US06465060B1

    公开(公告)日:2002-10-15

    申请号:US09708852

    申请日:2000-11-07

    IPC分类号: C09K1934

    摘要: Tetrahydrothiophene derivatives of the formula (I) R1—X—(A1—M1)a—(A2—M2)b—A3—Y—T—Z—R2  (I) where the symbols and indices have the following meanings, for example: T is undirected and is tetrahydrothiophene-2,5-diyl or tetrahydrothiophene-2,4-diyl R1 is hydrogen or a straight-chain or branched C1-20-alkyl or C2-20-alkenyl radical (with or without asymmetric carbon atoms), R2 is hydrogen or a straight-chain or branched alkyl radical (with or without asymmetric carbon atoms) having 1 to 20 carbon atoms, X is a single bond, —O—, OC(═O)—, —C(═O)O— or —OC(═O)O— Y is —OC(═O)—, —SC(═O)—, —OCH2— or —CH2CH2— Z is a single bond or —O— A1, A2 and A3 are undirected different and are each, independently of one another phenylene-1,4-diyl, M1 and M2 are undirected and are each, independently of one another —OC(═O)—, —OCH2—, —CH2CH2—, —OC(═O)CH2CH2—, —OCH2CH2CH2—, —C≡C—, —CH2CH2CH2CH2— or a single bond; a and b are each, independently of one another, 0 or 1, can be used in liquid-crystal mixtures.

    摘要翻译: 其中符号和指数具有以下含义的式(I)的四氢噻吩衍生物,例如:T是无定向的,并且是四氢噻吩-2,5-二基或四氢噻吩-2,4-二基R 1是氢或直链或支链 C 2-20 - 烷基或C 2-20 - 烯基(具有或不具有不对称碳原子),R 2是氢或具有1至20个碳原子的直链或支链烷基(具有或不具有不对称碳原子),X是 单键,-O-,OC(= O) - , - C(= O)O-或-OC(= O)OY是-OC(= O) - , - SC(= O) - , - OCH 2 - 或-CH 2 CH 2 -Z是单键或-O-A 1,A 2和A 3是不同的且各自独立地彼此是亚苯基-1,4-二基,M 1和M 2是无取代的,并且各自独立地为一个 另一个-OC(= O) - , - OCH 2 - , - CH 2 CH 2 - , - OC(= O)CH 2 CH 2 - , - OCH 2 CH 2 CH 2 - , - C≡C-, - CH 2 CH 2 CH 2 CH 2 - 或单键; 彼此独立地是0或1,可以用于液晶混合物中。