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公开(公告)号：US06824948B1
公开(公告)日：2004-11-30
申请号：US09759362
申请日：2001-01-16
申请人： Toshiaki Aoai , Yutaka Adegawa , Morio Yagihara
发明人： Toshiaki Aoai , Yutaka Adegawa , Morio Yagihara
IPC分类号： G03F7004
CPC分类号： G03F7/0045 , G03F7/038
摘要： A negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B) a resin which is insoluble in water and soluble in an alkali aqueous solution, (C) a crosslinking agent causing crosslinking with the resin of component (B) by the action of an acid, and (D) a compound having at least one unsaturated bond capable of being polymerized by an acid and/or a radical, and a negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B′) a resin having at least one unsaturated bond polymerizable by an acid and/or an alkali, which is insoluble in water but soluble in an alkali aqueous solution, and (C) a crosslinking agent causing crosslinking with the resin (B′) by the action of an acid are disclosed.
摘要翻译： 一种用于电子束或X射线的负性抗蚀剂组合物，包括（A）通过电子束或X射线的照射产生酸和/或自由基的化合物，（B）不溶于水和可溶的树脂 在碱性水溶液中，（C）通过酸的作用与成分（B）的树脂交联的交联剂，（D）具有至少一个能够被酸和/ 或用于电子束或X射线的负性抗蚀剂组合物，其包含（A）通过照射电子束或X射线产生酸和/或自由基的化合物，（B'）具有 至少一个不溶于水但可溶于碱性水溶液的酸和/或碱可聚合的不饱和键，和（C）通过酸的作用与树脂（B'）交联的交联剂 被披露。
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92.发明授权公开(公告)号：US06379863B1
公开(公告)日：2002-04-30
申请号：US09620899
申请日：2000-07-20
IPC分类号： G03F709
CPC分类号： B41C1/1025 , B41C1/10 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/06 , B41C2210/10 , B41C2210/22 , B41C2210/24 , B41M5/36 , B41M5/368
摘要： A planographic printing plate precursor obtained by laminating on a substrate, a layer composed of a hydrophobic polymer which can be made hydrophilic by heating, and a layer of which exposed portions can be removed by heat mode exposure.
摘要翻译： 平版印刷版原版通过层叠在基板上，由疏水性聚合物构成的层，其可以通过加热而使其亲水化，以及通过热模式曝光可以去除暴露部分的层。
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公开(公告)号：US5395732A
公开(公告)日：1995-03-07
申请号：US893945
申请日：1992-06-04
申请人： Kazunobu Katoh , Morio Yagihara , Takahiro Goto
发明人： Kazunobu Katoh , Morio Yagihara , Takahiro Goto
CPC分类号： G03C7/30511 , G03C1/061 , Y10S430/158
摘要： A silver halide photographic material is disclosed, which comprises (a) at least one light-sensitive silver halide emulsion layer containing a hydrazine derivative and (b) a hydrophilic colloid layer which is different from the light-sensitive silver halide emulsion layer and which contains a redox compound capable of releasing a development inhibitor as a result of oxidation.
摘要翻译： 公开了一种卤化银照相材料，其包含（a）至少一种含有肼衍生物的感光卤化银乳剂层和（b）与感光卤化银乳剂层不同的亲水胶体层， 能够由于氧化而释放显影抑制剂的氧化还原化合物。
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公开(公告)号：US5374499A
公开(公告)日：1994-12-20
申请号：US161451
申请日：1993-12-06
申请人： Senzo Sasaoka , Morio Yagihara
发明人： Senzo Sasaoka , Morio Yagihara
CPC分类号： G03C1/061 , G03C1/34 , G03C1/42 , Y10S430/167
摘要： A silver halide photographic material comprising a support having thereon at least one of a surface latent image type silver halide emulsion layer and other hydrophilic colloid layers is disclosed, in which said at least one of the emulsion layer and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein X represents ##STR2## R.sub.1 represents a hydrogen atom or a group capable of being converted to a hydrogen atom on hydrolysis; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent group; R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted arylcarbonyl group, or a substituted or unsubstituted carbamoyl group; Y represents a group which accelerates adsorption onto silver halide grains; L represents a divalent linking group; and m represents 0 or 1.The photographic material has suitability for rapid processing and markedly improved abrasion resistance without undergoing reduction in sensitivity.
摘要翻译： 公开了一种卤化银照相材料，其包含其上具有表面潜像型卤化银乳剂层和其它亲水胶体层中的至少一种的载体，其中乳液层和其它亲水胶体层中的至少一种含有表示的化合物 通式（I）表示：其中X表示R 1表示氢原子或在水解时能够转化为氢原子的基团。 R 2，R 3和R 4可以相同或不同，表示氢原子或取代基; R 5和R 6可以相同或不同，表示氢原子，取代或未取代的烷基，取代或未取代的芳基，取代或未取代的烷基磺酰基，取代或未取代的芳基磺酰基，取代或未取代的 烷基羰基，取代或未取代的芳基羰基，或取代或未取代的氨基甲酰基; Y表示加速吸附到卤化银颗粒上的基团; L表示二价连接基团; m表示0或1.照相材料适用于快速加工，并且显着提高耐磨性，而不会降低灵敏度。
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公开(公告)号：US5290661A
公开(公告)日：1994-03-01
申请号：US921134
申请日：1992-07-29
申请人： Yoshio Idota , Makoto Ishihara , Morio Yagihara
发明人： Yoshio Idota , Makoto Ishihara , Morio Yagihara
摘要： A method for sorting images by silver salt diffusion transfer comprisingimagewise exposing a light-sensitive element comprising a light-sensitive silver halide emulsion layer,developing the light-sensitive element in the presence of a silver halide solvent using an alkaline processing composition to turn at least a part of unexposed silver halide of the light-sensitive silver halide emulsion layer into a transfer silver halide complex salt, andtransferring at least a part of the silver halide complex salt to an image receiving layer comprising a silver precipitating agent to form images on the image receiving layer,wherein at least one compound represented by formula (I) is added to at least one of the light-sensitive element, an image receiving element comprising the image receiving layer, and the processing composition in an amount of at least 1.times.10.sup.-6 and less than 1.times.10.sup.-2 mol based on one mol of silver applied per unit area (m.sup.2): ##STR1## wherein Q represents an atomic group for forming a quinone ring; R represents a monovalent group which may be substituted or unsubstituted; and n is an integer of 0 to 4, whereby the maximum density can be increased for a short time.
摘要翻译： 一种通过银盐扩散转印来分选图像的方法，其包括使包含感光卤化银乳剂层的感光元件成像曝光，使用碱处理组合物在卤化银溶剂的存在下显影所述感光元件， 将感光卤化银乳剂层的未曝光的卤化银的至少一部分转移到转移卤化银络合物盐中，并将至少一部分卤化银配盐转移到包含银沉淀剂的图像接收层上以形成图像 图像接收层，其中至少一种由式（I）表示的化合物被添加到至少一种光敏元件，包含图像接收层的图像接收元件和至少1的量的加工组合物 * 10-6且小于1×10-2摩尔，相对于每单位面积施加的1摩尔银（m2）：（*化学结构*）（I）其中Q表示 n原子团，用于形成醌环; R表示可以被取代或未取代的一价基团; n为0〜4的整数，能够在短时间内增加最大密度。
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公开(公告)号：US5230992A
公开(公告)日：1993-07-27
申请号：US877398
申请日：1992-04-30
申请人： Keiji Miyahashi , Morio Yagihara
发明人： Keiji Miyahashi , Morio Yagihara
IPC分类号： G03C7/392
CPC分类号： G03C7/39224
摘要： A silver halide color photographic material composed of a support having thereon at least one silver halide emulsion layer sensitive to red light containing a cyan coupler; at least one silver halide emulsion layer sensitive to green light containing a magenta coupler; at least one silver halide emulsion layer sensitive to blue light containing a yellow coupler; and at least one non-light-sensitive layer; at least one layer thereof containing at least one nondiffusible, non-color-forming compound represented by formula (I): ##STR1## wherein R.sup.11, R.sup.12 and R.sup.13, which may be the same or different, each represents hydrogen, an aliphatic group or an aromatic group; R.sup.14 represents hydrogen, an alkyl group, an aralkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group, an alkoxycarbonyl group, an aryloxycarbonyl group or a carbamoyl group; G.sup.11 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a ##STR2## group, or an iminomethylene group; and n is 0 or 1.
摘要翻译： 一种卤化银彩色照相材料，由其上具有至少一种对含有青色成色剂的红色光敏感的卤化银乳剂层组成; 至少一种对包含品红色成色剂的绿色光敏感的卤化银乳剂层; 至少一种对含有黄色成色剂的蓝色光敏感的卤化银乳剂层; 和至少一个非感光层; 至少一层含有由式（I）表示的至少一种不可扩散的非成色颜料：其中R 11，R 12和R 13可以相同或不同，各自表示氢， 脂族基团或芳族基团; R 14表示氢，烷基，芳烷基，芳基，杂环基，烷氧基，芳氧基，氨基，烷氧基羰基，芳氧基羰基或氨基甲酰基。 G11表示羰基，磺酰基，亚磺酰基，IMA基或亚氨基亚甲基; n为0或1。
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公开(公告)号：US5175074A
公开(公告)日：1992-12-29
申请号：US784737
申请日：1991-10-29
申请人： Morio Yagihara , Kazunobu Katoh
发明人： Morio Yagihara , Kazunobu Katoh
CPC分类号： G03C1/061 , G03C7/30511 , Y10S430/158
摘要： A silver halide photographic material suitable for photomechanical process is disclosed, which has at least one silver halide photographic emulsion hydrophilic colloid layer and contains at least one redox compound capable of releasing a development inhibitor by oxidation and at least one compound of general formula (I') in the photographic emulsion layer or in at least one other hydrophilic colloid layer: ##STR1## wherein the variable terms are as defined in the specification.
摘要翻译： 公开了一种适用于光机械方法的卤化银照相材料，其具有至少一种卤化银照相乳剂亲水胶体层，并含有至少一种能通过氧化释放显影抑制剂的氧化还原化合物和至少一种通式（I' ）在照相乳剂层或至少一个其它亲水胶体层中：其中可变项如说明书中所定义。
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公开(公告)号：US5066573A
公开(公告)日：1991-11-19
申请号：US480348
申请日：1990-02-12
申请人： Tetunori Matushita , Morio Yagihara , Kei Sakanoue
发明人： Tetunori Matushita , Morio Yagihara , Kei Sakanoue
CPC分类号： G03C7/39228 , G03C7/30511 , Y10S430/127 , Y10S430/156 , Y10S430/16
摘要： A silver halide color photographic material is described, comprising a support having thereon at least one of a silver halide emulsion layer and other hydrophilic colloid layer, wherein the silver halide emulsion layer or a hydrophilic colloid layer contains at least one compound represented by formula (II): ##STR1## wherein R.sub.2 represents a hydrogen atom or a group that can be substituted, Y.sub.1 represents ##STR2## R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, which may be the same or different, each represents a hydrogen atom or a group that can be substituted; X.sub.1 represents a divalent linking group containing a hetero atom connected to the carbon atom; m is 0 or 1; A represents a bleach accelerating agent moiety represented by ##STR3## wherein R.sub.9, L, X.sub.2 R.sub.10 B, l.sub.1 and L.sub.2 are defined in the specification.The compound represented by formula (II) is a bleach accelerating agent having an active group of adsorptive group.The silver halide color photographic material has a high blocked speed and can be used in rapid processing.
摘要翻译： 描述了一种卤化银彩色照相材料，其包括其上具有卤化银乳剂层和其它亲水胶体层中的至少一种的载体，其中所述卤化银乳剂层或亲水胶体层含有至少一种由式（II ）：其中R 2表示氢原子或可被取代的基团，其中R 1表示可以被取代的基团，R 1，R 2，R 3，R 3和R 8可以相同或不同，表示 氢原子或可被取代的基团; X1表示含有与碳原子连接的杂原子的二价连接基团; m为0或1; A表示由说明书中定义的由R9，L，X2 R10B，11和L2表示的漂白促进剂部分。 由式（II）表示的化合物是具有吸附基团活性基团的漂白促进剂。 卤化银彩色照相材料具有较高的封闭速度，可用于快速加工。
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公开(公告)号：US4994364A
公开(公告)日：1991-02-19
申请号：US394386
申请日：1989-08-15
申请人： Noriyuki Inoue , Morio Yagihara
发明人： Noriyuki Inoue , Morio Yagihara
CPC分类号： G03C1/48561 , Y10S430/141
摘要： A direct positive image forming method comprising development processing an imagewise exposed direct positive photographic light-sensitive material which comprises a support having thereon at least one layer containing internal latent image type silver halide grains not having been previously fogged after fogging treatment or while fogging treatment, wherein the fogging treatment is conducted in the presence of a compound represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2 both represent a hydrogen atom or one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a sulfonyl group or an acyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; L.sub.1 represents a divalent linkage group; X.sub.1 represents --O-- or ##STR3## wherein R.sub.4 represents a hydrogen atom, an alkyl group or an aryl group); Y.sub.1 represents ##STR4## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, a heterocyclic group, --OR.sub.5 or --NR.sub.5 R.sub.6 (wherein R.sub.5 represents an aliphatic group, an aromatic group or a heterocyclic group; and R.sub.6 represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group); and R.sub.3 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aralkyl group, an aryloxy group or an amino group.In accordance with the method of the present invention direct positive images having a high maximum image density and a low minimum image density and being stable even when preserved under high temperature and high humidity conditions.
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公开(公告)号：US4956267A
公开(公告)日：1990-09-11
申请号：US200268
申请日：1988-05-31
申请人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
发明人： Shinji Ueda , Tatsuo Heki , Noriyuki Inoue , Takatoshi Ishikawa , Nobutaka Ohki , Morio Yagihara , Kiyoshi Morimoto , Hiroshi Fujimoto , Kazuto Andoh
CPC分类号： G03C7/413 , G03C1/48538
摘要： A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represents --CO--, --SO.sub.2 -- or ##STR2## and R.sup.1 and R.sup.2 represents various familiar group; ##STR3## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent various familiar groups; ##STR4## wherein R.sup.7 and R.sup.8 represent various familiar groups; ##STR5## wherein Y represents a trivalent atomic group necessary for completing a condensed ring, m represents an integer of 0 to 4, and n represents an integer of 1 to 5.Stability of the color developing solutions with time lapse is excellent, which makes stable continuous process of color photographic light-sensitive materials possible over a long period.
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