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    Method for producing a lactam
    93.
    发明授权
    Method for producing a lactam 失效
    生产乳酸菌的方法

    公开(公告)号：US5227482A

    公开(公告)日：1993-07-13

    申请号：US870316

    申请日：1992-04-17

    Applicant: Takashi Ushikubo

    Inventor： Takashi Ushikubo

    IPC: B01J23/20 ,  B01J35/10 ,  C07B61/00 ,  C07D201/04 ,  C07D223/10

    CPC classification number: B01J23/20 ,  C07D201/04 ,  Y02P20/52

    Abstract: A method for preparing a lactam, which comprises subjecting a cycloalkanone oxime to a Beckmann rearrangement reaction in a gas phase in the presence of a carrier-supported catalyst containing tantalum, wherein the carrier-supported catalyst is the one prepared by contacting an organic compound containing tantalum to a silica carrier having pores with pore diameters of from to 150,000 .ANG. wherein the pore volume of pores with pore diameters of from 40 to 2,000 .ANG. is at least 80% of the total pore volume of pores with pore diameters of from 40 to 150,000 .ANG..

    Reaction accelerator for rearrangement of oxime to amide and process for producing amides by rearrangement of oximes
    94.
    发明授权
    Reaction accelerator for rearrangement of oxime to amide and process for producing amides by rearrangement of oximes 失效
    用于通过重新排列氧化物将氧化物重新排列到酰胺和生产助剂的方法的反应加速器

    公开(公告)号：US5225547A

    公开(公告)日：1993-07-06

    申请号：US715767

    申请日：1991-06-14

    Applicant: Yusuke Izumi

    Inventor： Yusuke Izumi

    IPC: C07D201/04

    CPC classification number: C07D201/04

    Abstract: A reaction accelerator for rearrangement of an oxime to an amide consisting of an alkylating agent and an N,N-disubstituted formamide or N,N-disubstituted carboxylic acid amide represented by formula (1): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, represent alkyl groups having 1 to 6 carbon atoms or substituted or unsubstituted phenyl groups having 6 to 9 carbon atoms, and R.sup.3 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. An amide can effectively be produced by rearranging a corresponding oxime in the presence of said reaction accelerator.

    Process for producing epsilon-caprolactam
    95.
    发明授权
    Process for producing epsilon-caprolactam 失效
    生产ε-己内酰胺的方法

    公开(公告)号：US4717770A

    公开(公告)日：1988-01-05

    申请号：US19921

    申请日：1987-02-27

    Applicant: Hiroshi Sato ,  Kenichi Hirose ,  Masaru Kitamura ,  Hideto Tojima ,  Norio Ishii

    Inventor： Hiroshi Sato ,  Kenichi Hirose ,  Masaru Kitamura ,  Hideto Tojima ,  Norio Ishii

    IPC: C07B61/00 ,  B01J25/00 ,  B01J29/06 ,  B01J31/00 ,  B01J31/12 ,  C07D201/04

    CPC classification number: C07D201/04 ,  Y02P20/52

    Abstract: .epsilon.-caprolactam is prepared by gas phase catalytic synthesis where cyclohexanone oxime is brought into contact with a crystalline zeolite, for example, aluminosilicate zeolite or metallosilicate zeolite having a constraint index of 1-12 which has been surface treated with an organometallic compound represented by the general formula: R.sub.4-n MX.sub.n wherein R which may be identical or different represent an alkyl group of 1-6 carbon atoms or phenyl group, M represnets Si or Ge, X represents Cl or an alkoxy group of 1-6 carbon atoms and n represents 1 or 2.

    Abstract translation: ε-己内酰胺通过气相催化合成法制备，其中环己酮肟与结晶沸石接触，例如具有1-12的约束指数的铝硅酸盐沸石或金属硅酸盐沸石，其已经用由下式表示的有机金属化合物 通式R4-nMXn其中R可相同或不同，表示1-6个碳原子的烷基或苯基，M表示Si或Ge，X表示C1或1-6个碳原子的烷氧基，n表示 1或2。

    Preparation of caprolactam
    96.
    发明授权
    Preparation of caprolactam 失效
    己内酰胺的制备

    公开(公告)号：US4268440A

    公开(公告)日：1981-05-19

    申请号：US129827

    申请日：1980-03-13

    Applicant: Joachim Werther ,  Hugo Fuchs ,  Uwe Brand ,  Friedrich R. Faulhaber

    Inventor： Joachim Werther ,  Hugo Fuchs ,  Uwe Brand ,  Friedrich R. Faulhaber

    IPC: C07B61/00 ,  C07D201/04

    CPC classification number: C07D201/04

    Abstract: A process for the preparation of caprolactam wherein, in a first stage, cyclohexanone-oxime is vaporized, in the presence of inert gases, by bringing it into contact with a fluidized bed of inert solid particles at from 150.degree. to 250.degree. C., and the mixture of cyclohexanone-oxime vapor and inert gases is passed into a second stage, where the cyclohexanone-oxime is rearranged to caprolactam at from 230.degree. to 450.degree. C. over a supported catalyst, containing boron trioxide, in a fluidized bed.

    Abstract translation: 一种制备己内酰胺的方法，其中在惰性气体存在下，在第一阶段将环己酮 - 肟气化，使其与150℃至250℃的惰性固体颗粒流化床接触， 并将环己酮 - 肟蒸气和惰性气体的混合物进入第二阶段，其中环己酮 - 肟在230℃至450℃下在含有三氧化硼的负载催化剂上在流化床中重排为己内酰胺。

    Catalyst regeneration of boric acid on carbon catalysts
    98.
    发明授权
    Catalyst regeneration of boric acid on carbon catalysts 失效
    硼酸在碳催化剂上的催化剂再生

    公开(公告)号：US4155876A

    公开(公告)日：1979-05-22

    申请号：US831936

    申请日：1977-09-09

    Applicant: Harry Danziger ,  Otto Immel ,  Bernd-Ulrich Kaiser ,  Hans-Helmut Schwarz ,  Klaus Starke

    Inventor： Harry Danziger ,  Otto Immel ,  Bernd-Ulrich Kaiser ,  Hans-Helmut Schwarz ,  Klaus Starke

    IPC: C07D223/10 ,  B01J21/20 ,  B01J38/30 ,  C07D201/04

    CPC classification number: C07D201/04 ,  B01J21/20 ,  Y02P20/584

    Abstract: A process for the regeneration of a granular, supported catalyst of boric acid on carbon, wherein a part of the catalyst is removed from a fluidized bed reactor, in which cyclohexanone oxime is rearranged into caprolactam on this catalyst, when the "differential content in the catalyst of organic nitrogen" is between 0.3 and 2.0% by weight and is replaced by an equal amount of regenerated catalyst so that the differential organic nitrogen content remains in the above-mentioned range, the quantity of catalyst removed is regenerated with air in a fluidized bed at a temperature of from 400.degree. to 700.degree. C. and is returned to the fluidized bed reactor used for rearrangement when a further part of the catalyst is removed therefrom for regeneration.

    Abstract translation: 一种用于再生颗粒状载体上的硼酸催化剂的方法，其中将一部分催化剂从流化床反应器中除去，其中环己酮肟在该催化剂上重排为己内酰胺，当“ 有机氮的催化剂“为0.3-2.0重量％，并由等量的再生催化剂代替，使得差示有机氮含量保持在上述范围内，除去的催化剂的量在流化床中用空气再生 在400〜700℃的温度下进行洗涤，并且当将另一部分催化剂从其中除去再生时，返回到用于重排的流化床反应器。

    Process for the manufacture of lactams
    99.
    发明授权
    Process for the manufacture of lactams 失效
    内酰胺的制造工艺

    公开(公告)号：US4049646A

    公开(公告)日：1977-09-20

    申请号：US261220

    申请日：1972-06-09

    Applicant: Herbert Furkert

    Inventor： Herbert Furkert

    IPC: C01B17/50 ,  C01C1/24 ,  C07D201/16 ,  C07D201/04

    CPC classification number: C07D201/16 ,  C01B17/504 ,  C01C1/24 ,  Y02P20/129

    Abstract: In a process for manufacturing a lactam which includes rearranging a cycloalkanone-oxime with sulfuric acid to form said lactam, neutralizing the rearrangement mixture with ammonia to form ammonium sulfate, and separating said lactam and said ammonium sulfate, the improvement which comprises:A. forming the ammonium sulfate into finely divided particles;B. burning the particles at a temperature of 850.degree. - 1250.degree. C. to form an SO.sub.2 -containing gas;C. oxidizing the SO.sub.2 -containing gas to form sulfuric acid; andD. recycling at least a portion of the sulfuric acid to the cycloalkanone-oxime rearrangement step.No external source of sulfuric acid is required. A portion of the SO.sub.2 -containing gas can be used for the manufacture of hydroxylamine sulfate, in which case no external source of SO.sub.2 need be required.

    Abstract translation: 在制造内酰胺的方法中，其包括用硫酸重排环烷酮肟以形成所述内酰胺，用氨中和重排混合物形成硫酸铵，并分离所述内酰胺和所述硫酸铵，其改进包括：

    Preparation of cephalosporin ethers
    100.
    发明授权
    Preparation of cephalosporin ethers 失效
    头孢菌素醚的制备

    公开(公告)号：US3953438A

    公开(公告)日：1976-04-27

    申请号：US513669

    申请日：1974-10-09

    Applicant: Gary A. Koppel

    Inventor： Gary A. Koppel

    IPC: C07D201/04 ,  C07D501/04

    CPC classification number: C07D201/04

    Abstract: Reaction of 3-hydroxy cephalosporins with alkylfluorosulfonates in the presence of a base provides 3-alkoxy cephalosporins which are useful as intermediates for cephalosporin antibiotic preparation.

    Abstract translation: 在碱存在下，3-羟基头孢菌素与烷基氟磺酸盐的反应提供了可用作头孢菌素抗生素制剂中间体的3-烷氧基头孢菌素。

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