PRODUCTION METHOD OF POLYVINYL ALCOHOL RESIN, AND POLYVINYL ALCOHOL RESIN

    公开(公告)号:US20210309770A1

    公开(公告)日:2021-10-07

    申请号:US17267267

    申请日:2019-09-03

    申请人: KURARAY CO., LTD.

    IPC分类号: C08F16/06

    摘要: Provided by the present invention is a production method of a polyvinyl alcohol resin in which a content of organic volatiles has been reduced while inhibiting fusing of the resin to itself. The production method includes a step of washing, with a washing liquid, a polyvinyl alcohol obtained by saponifying a polyvinyl ester, wherein the washing liquid contains 50 to 98 parts by mass of methyl acetate, 1 to 49 parts by mass of methanol, and 1 to 10 parts by mass of water with respect to 100 parts by mass being a total of methyl acetate, methanol, and water.

    POLYVINYL ALCOHOL FIBER
    104.
    发明申请

    公开(公告)号:US20210292933A1

    公开(公告)日:2021-09-23

    申请号:US17285163

    申请日:2019-10-25

    申请人: KURARAY CO., LTD.

    IPC分类号: D01F6/50 D01F1/10

    摘要: Polyvinyl alcohol-based fibers contain a polyvinyl alcohol-based polymer and an adsorbent. With respect to 100 parts by mass of the polyvinyl alcohol-based polymer, 30 to 500 parts by mass of the adsorbent is contained. The polyvinyl alcohol-based fibers have a crystallinity of polyvinyl alcohol ranging from 30% to 60%, a diameter ranging from 5 μm to 1000 μm, and a specific surface area ranging from 10 m2/g to 2000 m2/g.

    METHOD FOR PRODUCING 1-ACYLOXY-2-METHYL-2-PROPENE

    公开(公告)号:US20210292268A1

    公开(公告)日:2021-09-23

    申请号:US17259613

    申请日:2019-07-24

    申请人: KURARAY CO., LTD.

    IPC分类号: C07C67/055

    摘要: A method for producing a 1-acyloxy-2-methyl-2-propene represented by the following general formula (II), including reacting a carboxylic acid represented by the following general formula (I), isobutylene, and oxygen, in the presence of a catalyst, in a liquid phase, with an amount of the isobutylene used of more than 1 mol and 50 mol or less per 1 mol of the carboxylic acid.

    Polyvinyl alcohol
    107.
    发明授权

    公开(公告)号:US11111319B2

    公开(公告)日:2021-09-07

    申请号:US16089441

    申请日:2017-03-30

    申请人: KURARAY CO., LTD.

    IPC分类号: C08F16/06 C08F116/06

    摘要: A polyvinyl alcohol has a number-average molecular weight (Mn) from 4,400 to 440,000, a molecular weight distribution (Mw/Mn) from 1.05 to 1.70, a degree of saponification from 80 to 99.99 mol %, and a carbon-carbon double bond content (X) of 0.1 mol % or less based on total monomer units, and satisfying a formula (1) below. A polyvinyl alcohol, having a narrow molecular weight distribution and a high number-average molecular weight with good hue, and a method for producing the same are thus provided. X·Mn≤1000  (1)

    Vinyl alcohol-based polymer having olefin in side chain

    公开(公告)号:US11078309B2

    公开(公告)日:2021-08-03

    申请号:US16619152

    申请日:2018-06-05

    申请人: KURARAY CO., LTD.

    IPC分类号: C08F8/32 C08F16/06

    摘要: There is provided a vinyl alcohol-based polymer having an olefin in side chain, comprising 0.001 to 10 mol % of a structural unit represented by Formula (1) based on the total amount of structural units, wherein the total carbon number of X, R1, R2, R3 and R4 is 2 or more. The vinyl alcohol-based polymer having an olefin in side chain has excellent storage stability, good solubility in water or an organic solvent even after thermal treatment, and excellent reactivity to high energy beam. In Formula (1), X represents an optionally substituted divalent aliphatic hydrocarbon group, an optionally substituted divalent alicyclic hydrocarbon group, an optionally substituted divalent aromatic hydrocarbon group, or a group consisting of two or more of these groups which are linked via at least one bond selected from the group consisting of an amide bond, an ester bond, an ether bond, and a sulfide bond; R1, R2, R3 and R4, independently of each other, represents a hydrogen atom, an optionally substituted aliphatic hydrocarbon group, an optionally substituted alicyclic hydrocarbon group, or an optionally substituted aromatic hydrocarbon group; and X, R1, R2, R3 and R4 can be arbitrarily combined to form a ring structure).

    Method for Producing Ethylene-Vinyl Acetate Copolymer

    公开(公告)号:US20210230314A1

    公开(公告)日:2021-07-29

    申请号:US17059566

    申请日:2019-05-29

    申请人: KURARAY CO., LTD.

    摘要: A method of continuously producing an ethylene-vinyl acetate copolymer in a polymerization vessel containing a reaction liquid containing ethylene, vinyl acetate, a polymerization initiator and methanol, the polymerization vessel being connected via piping to a heat exchanger circulating a coolant, the method includes the steps of: supplying ethylene, the polymerization initiator and methanol to the polymerization vessel; introducing pressurized gas containing ethylene present in a gas phase portion of the polymerization vessel into the heat exchanger; supplying vinyl acetate cooled to between −50° C. and 23° C. to an upper portion of the heat exchanger; flowing vinyl acetate down in the heat exchanger while absorbing ethylene; letting vinyl acetate dissolving ethylene out of a bottom portion of the heat exchanger and adding to the reaction liquid in the polymerization vessel; and taking the reaction liquid out of the polymerization vessel. This provides a method of efficiently removing heat during polymerization of an ethylene-vinyl acetate copolymer.