Herbicidal agents based on acetanilides

    公开(公告)号:US4373945A

    公开(公告)日:1983-02-15

    申请号:US209961

    申请日:1980-11-24

    摘要: Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole which is attached via a ring nitrogen atom and is unsubstituted or mono- or poly-substituted by halogen, phenyl, alkyl, alkoxy, alkylthio or perfluoroalkyl, each of a maximum of 4 carbon atoms, cyano, carboxy, carbalkoxy of a maximum of 4 carbon atoms in the alkoxy, or alkanoyl of a maximum of 4 carbon atoms, A also denoting a salt of an azole containing 2 or 3 nitrogen atoms, and a haloacetanilide of the formula ##STR2## where R denotes linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting linear or branched alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-yl or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to haloacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.

    Fungicidal mixtures from benzophenones and n-biphenyl nicotinamides
    103.
    发明授权
    Fungicidal mixtures from benzophenones and n-biphenyl nicotinamides 有权
    来自二苯甲酮和n-联苯烟酰胺的杀真菌混合物

    公开(公告)号:US07358213B2

    公开(公告)日:2008-04-15

    申请号:US10466165

    申请日:2002-01-17

    IPC分类号: A01N43/40

    摘要: Fungicidal mixtures, comprising a) benzophenones of the formula I, in which R1 is chlorine, methyl, methoxy, acetoxy, pivaloyloxy or hydroxyl; R2 is chlorine or methyl; R3 is hydrogen, halogen or methyl; and R4 is C1-C6-alkyl or benzyl, where the phenyl moiety of the benzyl radical may carry a halogen or methyl substituent, and b) amide compounds of the formula II in which R6 and R7 are halogen nitro, cyano, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl or alkylsulfonyl; x is 1, 2, 3 or 4; and y is 1, 2, 3, 4 or 5; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and compositions comprising them are described.

    摘要翻译: 杀真菌混合物,其包含a)式I的二苯甲酮,其中R 1是氯,甲基,甲氧基,乙酰氧基,新戊酰氧基或羟基; R 2是氯或甲基; R 3是氢,卤素或甲基; 且R 4是C 1 -C 6 - 烷基或苄基,其中苄基的苯基部分可带有卤素或甲基取代基 ,和b)其中R 6和R 7的式II的酰胺化合物是卤素硝基,氰基,烷基,烯基,炔基,卤代烷基,卤代烯基,卤代炔基,烷氧基 ,卤代烷氧基,烷硫基,卤代烷硫基,烷基亚磺酰基或烷基磺酰基; x为1,2,3或4; y为1,2,3,4或5; 在协同有效量中,描述了使用化合物I和II的混合物以及包含它们的组合物来控制有害真菌的方法。

    Benzyl amidoxime derivatives, intermediate products and method for their production and use as fungicides
    105.
    发明授权
    Benzyl amidoxime derivatives, intermediate products and method for their production and use as fungicides 失效
    苄基偕胺肟衍生物,中间产物及其生产和用作杀真菌剂的方法

    公开(公告)号:US07101900B2

    公开(公告)日:2006-09-05

    申请号:US11061470

    申请日:2005-02-22

    摘要: Novel benzamidoxime derivatives, processes and intermediates for their preparation and their use as fungicides are described.In the context of the present invention, benzamidoxime derivatives are compounds of the formula I where: A is an aryl or hetaryl radical; Y is a straight-chain or branched C1–C4-alkylene group, where one carbon can be replaced by oxygen, nitrogen or sulfur or by a cyclopropyl group; Rn1 are one to five identical or different radicals from the group consisting of: hydrogen, halogen, C1–C6-alkyl, C1–C6-alkoxy, C1–C4-haloalkyl, C1–C4-haloalkoxy, C1–C4-alkylthio, C1–C4-alkoxyalkoxy; R2 is unsubstituted or substituted phenyl-C1–C6-alkyl, thienyl-C1–C4-alkyl, or pyrazolyl-C1–C4-alkyl, Rp3 are one to five identical or different radicals from the group consisting of: hydrogen, halogen, C1–C6-alkyl, C1–C6-alkoxy, C1–C4-haloalkyl, C1–C4-haloalkoxy, C1–C4-alkylthio, C1–C4-alkoxyalkoxy, C1–C6-alkylcarbonyl; n is 0–5; p is, depending on the number of free valencies, 0–4.

    摘要翻译: 描述了新的苯甲酰胺肟衍生物,其制备方法和中间体及其作为杀真菌剂的用途。 在本发明的上下文中,苯甲酰胺肟衍生物是式I的化合物,其中:A是芳基或杂芳基; Y是直链或支链C 1 -C 4 - 亚烷基,其中一个碳可被氧,氮或硫取代或被环丙基取代; R 1是与以下组成的组中的一至五个相同或不同的基团:氢,卤素,C 1 -C 6 C 1 -C 6烷基,C 1 -C 6 - 烷氧基,C 1 -C 4 - 卤代烷基 ,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷氧基烷氧基; R 2是未取代或取代的苯基-C 1 -C 6 - 烷基,噻吩基-C 1 -C 或 - 吡唑基-C 1 -C 4 - C 1-4 - 烷基,R 3 - (CH 3)3 - / SUP>是与由以下组成的组中的一至五个相同或不同的基团:氢,卤素,C 1 -C 6 - 烷基,C 1 - C 1 -C 6 - 烷氧基,C 1 -C 4 - 卤代烷基,C 1 -C 3 > 4个 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - - 烷氧基烷氧基,C 1 -C 6 - 烷基羰基; n为0-5; p取决于自由价格的数量,0-4。

    Benzyl amidoxime derivatives, intermediate products and method for their production and use as fungicides
    106.
    发明授权
    Benzyl amidoxime derivatives, intermediate products and method for their production and use as fungicides 失效
    苄基偕胺肟衍生物,中间产物及其生产和用作杀真菌剂的方法

    公开(公告)号:US06881742B1

    公开(公告)日:2005-04-19

    申请号:US10089148

    申请日:2000-10-05

    摘要: Novel benzamidoxime derivatives, processes and intermediates for their preparation and their use as fungicides are described.In the context of the present invention, benzamidoxime derivatives are compounds of the formula I where: A is an aryl or hetaryl radical; Y is a straight-chain or branched C1-C4-alkylene group, where one carbon can be replaced by oxygen, nitrogen or sulfur or by a cyclopropyl group; Rn1 are one to five identical or different radicals from the group consisting of: hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkoxyalkoxy; R2 is unsubstituted or substituted phenyl-C1-C6-alkyl, thienyl-C1-C4-alkyl, or pyrazolyl-C1-C4-alkyl, Rp3 are one to five identical or different radicals from the group consisting of: hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkoxyalkoxy, C1-C6-alkylcarbonyl; n is 0-5; p is, depending on the number of free valencies, 0-4.

    摘要翻译: 描述了新的苯甲酰胺肟衍生物,其制备方法和中间体及其作为杀真菌剂的用途。 在本发明的上下文中,苯甲酰胺肟衍生物是式I的化合物,其中:A是芳基或杂芳基; Y是直链或支链C 1 -C 4 - 亚烷基,其中一个碳可被氧,氮或硫取代或被环丙基取代; R 1是与以下组成的组中的一至五个相同或不同的基团:氢,卤素,C 1 -C 6 C 1 -C 6烷基,C 1 -C 6 - 烷氧基,C 1 -C 4 - 卤代烷基 ,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷氧基烷氧基; R 2是未取代或取代的苯基-C 1 -C 6 - 烷基,噻吩基-C 1 -C 或 - 吡唑基-C 1 -C 4 - C 1-4 - 烷基,R 3 - (CH 3)3 - / SUP>是与由以下组成的组中的一至五个相同或不同的基团:氢,卤素,C 1 -C 6 - 烷基,C 1 - C 1 -C 6 - 烷氧基,C 1 -C 4 - 卤代烷基,C 1 -C 3 > 4个 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - - 烷氧基烷氧基,C 1 -C 6 - 烷基羰基; n为0-5; p取决于自由价格的数量,0-4。

    Fungicide mixtures based on pyride amides and morpholine derivatives or piperidine derivatives
    107.
    发明授权
    Fungicide mixtures based on pyride amides and morpholine derivatives or piperidine derivatives 失效
    基于吡啶酰胺和吗啉衍生物或哌啶衍生物的杀菌剂混合物

    公开(公告)号:US06777411B1

    公开(公告)日:2004-08-17

    申请号:US09581906

    申请日:2000-06-19

    IPC分类号: A61K31535

    摘要: Fungicidal mixtures comprising as active components a) an amide compound of the formula I A—CO—NR1R2  I  in which A is an aryl group or an aromatic or non-aromatic, 5- or 6-membered heterocycle which has from 1 to 3 hetero atoms selected from O, N and S; where the aryl group or the heterocycle may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, halogen, CHF2, CF3, alkoxy, haloalkoxy, alkylthio, alkylsulfynyl and alkylsulfonyl; R1 is a hydrogen atom; R2 is a phenyl or cycloalkyl group which may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cyclo-alkenyloxy, phenyl and halogen, where the aliphatic and cycloaliphatic radicals may be partially or fully halogenated and/or the cycloaliphatic radicals may be substituted by from 1 to 3 alkyl groups and where the phenyl group may have from 1 to 5 halogen atoms and/or from 1 to 3 substituents which are selected, independently of one another, from alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and haloalkylthio, and where the amidic phenyl group may or may not be condensed with a saturated 5-membered ring which may or may not be substituted by one or more alkyl groups and/or may have a hetero atom selected from O and S, and b) a morpholine or piperidine derivative II selected from the group of the compounds IIa, IIb, IIc, IId [sic] and IIe [sic] in a synergistically effective amount.

    摘要翻译: 包含作为活性组分的杀真菌混合物a)式Iin的酰胺化合物,其中A是具有1至3个选自O,N和S的杂原子的芳基或芳族或非芳族的5或6元杂环; 其中芳基或杂环可以具有或不具有1,2或3个彼此独立地选自烷基,卤素,CHF 2,CF 3,烷氧基,卤代烷氧基,烷硫基,烷基亚硫炔基和烷基磺酰基的取代基; R 1, R 2是苯基或环烷基,其可以具有或不具有1,2或3个彼此独立地选自烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,环烷基的取代基 ,环烯基,环烷基氧基,环烯基氧基,苯基和卤素,其中脂族和脂环族基团可以被部分或完全卤化和/或脂环族基团可以被1至3个烷基取代,并且其中苯基可以具有1 至5个卤素原子和/ o 1至3个取代基,其彼此独立地选自烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基和卤代烷硫基,并且其中酰胺苯基可以或可以不与饱和五元环缩合, 可以不被一个或多个烷基取代和/或可以具有选自O和S的杂原子,以及b)选自化合物IIa,IIb,IIc,IId和[II]的吗啉或哌啶衍生物II和 IIe [sic]具有协同有效的量。

    Fungicidal agents containing pyrrolidones as their active agents and use thereof for treating plants
    108.
    发明授权
    Fungicidal agents containing pyrrolidones as their active agents and use thereof for treating plants 失效
    含有吡咯烷酮作为其活性剂的杀真菌剂及其用于处理植物的用途

    公开(公告)号:US06586369B1

    公开(公告)日:2003-07-01

    申请号:US10204349

    申请日:2002-08-20

    IPC分类号: C07D20718

    摘要: Agrochemical compositions having fungicidal action and comprising as active compounds compounds of the formula I where R1 is hydrogen, C1-C6-alkyl, C1-C6-alkylcarbonyl, formyl or C1-C6-haloalkylcarbonyl; R2 is halogen, C1-C6-alkylthio, C1-C6-alkoxy, C3-C6-cycloalkyl-C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkyl, halo-C1-C6-alkoxy, C1-C6-alkylsulfonyl, C1-C6-alkylsulfinyl, halo-C1-C6-alkylsulfonyl, cyano or a radical NR13R14; R3-R12 are hydrogen, halogen, C1-C8-cycloalkyl, C1-C6-alkyl, halo-C1-C6-alkyl, C1-C6-alkoxy, halo-C1-C6-alkoxy, C1-C6-alkylsulfonyl, halo-C1-C6-alkylsulfonyl, formyl, C1-C6-alkylcarbonyl, cyano, C1-C6-alkylthio or phenyl, which may be unsubstituted or substituted by halogen, C1-C6-alkyl or halo-C1-C6-alkyl, R13 is hydrogen, C1-C6-alkyl, R14 is C1-C6-alkyl, C1-C8-cycloalkyl or, together with R13 and the nitrogen atom to which they are attached, a saturated or unsaturated heterocyclic five- or six-membered ring which contains one or two heteroatoms selected from the group consisting of nitrogen and oxygen, and their agriculturally useful salts are described.

    摘要翻译: 具有杀真菌作用的农药组合物,包含作为活性化合物的式I化合物,其中R 1是氢,C 1 -C 6烷基,C 1 -C 6烷基羰基,甲酰基或C 1 -C 6卤代烷基羰基; R 2是卤素,C 1 -C 6烷硫基, C 1 -C 6烷氧基,C 1 -C 6烷氧基,C 1 -C 6烷氧基,C 1 -C 6 - 烷基亚磺酰基, C 1 -C 6 - 烷基磺酰基,氰基或NR 13 R 14基; R 3 -R 12是氢,卤素,C 1 -C 8 - 环烷基,C 1 -C 6烷基,卤代-C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基, C 1 -C 6 - 烷基磺酰基,卤代-C 1 -C 6 - 烷基磺酰基,甲酰基,C 1 -C 6 - 烷基羰基,氰基,C 1 -C 6 - 烷硫基或苯基,其可以是未取代的或被卤素取代, 或卤代-C 1 -C 6烷基,R 13是氢,C 1 -C 6烷基,R 14是C 1 -C 6 - 烷基,C 1 -C 8 - 环烷基,或者与R 13和它们所连接的氮原子一起是饱和或 不饱和杂环五元或六元环,其含有一个或两个选自组的杂原子 描述了氮和氧及其农业上有用的盐。

    Fungicidal mixtures based on amide compounds
    109.
    发明授权
    Fungicidal mixtures based on amide compounds 失效
    基于酰胺化合物的杀真菌混合物

    公开(公告)号:US06503932B2

    公开(公告)日:2003-01-07

    申请号:US10012347

    申请日:2001-12-12

    IPC分类号: A01N4340

    摘要: Fungicidal mixtures, comprising A) an amide compound of the formula I in which R1, R2 are identical or different and are halogen, nitro, cyano, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-haloalkyl, C2-C8-haloalkenyl, C2-C8-haloalkynyl, C1-C8-alkoxy, C1-C8-haloalkoxy, C1-C8-haloalkylthio, C1-C8-alkylsulfinyl or C1-C8-alkylsulfonyl; x is 1, 2, 3 or 4; y is 1, 2, 3, 4 or 5; and B) the amino compound of the formula II in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.

    摘要翻译: 杀真菌混合物,其包含A)式Iin的酰胺化合物,其中R 1,R 2相同或不同,为卤素,硝基,氰基,C 1 -C 8 - 烷基,C 2 -C 8 - 烯基,C 2 -C 8 - 炔基,C 1 -C 8 - ,C 2 -C 8 - 卤代链烯基,C 2 -C 8 - 卤代炔基,C 1 -C 8 - 烷氧基,C 1 -C 8 - 卤代烷氧基,C 1 -C 8 - 卤代烷硫基,C 1 -C 8烷基亚磺酰基或C 1 -C 8烷基磺酰基; x是1,2,3 或4; y为1,2,3,4或5;和B)协同有效量的式II的氨基化合物,使用化合物I和II的混合物来控制有害真菌的方法以及使用化合物I和 描述了制备这种混合物的II。

    Fungicidal mixtures
    110.
    发明授权
    Fungicidal mixtures 有权
    杀菌混合物

    公开(公告)号:US06436979B1

    公开(公告)日:2002-08-20

    申请号:US09674542

    申请日:2000-11-02

    IPC分类号: A01N4380

    摘要: A fungicidal mixture, comprising at least one compound selected from a) [sic] carbamates of the formula I,  in which T is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, where the radicals R may be different if n is 2, a2) the oxime ether carboxylate of the formula II  or a3) the oxime ether carboxamide of the formula III,  and b) a compound of the formula IV  where the substituents R1 to R3 have the following meaning: R1 is C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkyl-C3-C7-cycloalkyl, where these radicals may carry substituents selected from halogen, cyano and Cl-C4-alkoxy, R2 is C1-C4-alkyl or C1-C4-haloalkyl, R3 is hydrogen, halogen, Cl-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, N—C1-C4-alkylamino, Cl-C4-haloalkyl or C1-C4-haloalkoxy, Y is O, S, CHR4 or NR5, where R4 and R5 may each have the meanings mentioned for R2, n is 0, 1, 2 or 3, in a synergistically effective amount, and methods for controlling harmful fungi using these mixtures are described.

    摘要翻译: 一种杀真菌混合物,其包含至少一种选自以下的化合物:其中T为CH或N,n为0,1或2,R为卤素,C 1 -C 4烷基或C 1 -C 4的式I的(S) - 卤代烷基,其中如果n是2,基团R可以不同,a2)式II的肟醚羧酸酯ora3)式III的肟醚甲酰胺,和b)式IV化合物,其中取代基R 1至R 3 具有以下含义:R 1是C 1 -C 4 - 烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4烷基-C 3 -C 7 - 环烷基,其中这些基团可以带有选自卤素,氰基和Cl C 1-4 - 烷氧基,R 2是C 1 -C 4烷基或C 1 -C 4卤代烷基,R 3是氢,卤素,C 1 -C 4烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,N-C 1 -C 4烷基氨基 ,C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基,Y是O,S,CHR 4或NR 5,其中R 4和R 5可以各自具有R2,n为0,1,2或3所述的含义, 描述了使用这些混合物来控制有害真菌的量和方法。