Pesticidal thiadiazole-substituted acrylic acid esters and intermediates
therefor
    104.
    发明授权
    Pesticidal thiadiazole-substituted acrylic acid esters and intermediates therefor 失效
    杀虫噻二唑取代的丙烯酸酯及其中间体

    公开(公告)号:US5322949A

    公开(公告)日:1994-06-21

    申请号:US957328

    申请日:1992-10-06

    摘要: Fungicidal thiadiazole-substituted acrylic acid esters of the formula ##STR1## in which R.sup.1 represents hydrogen, unsubstituted or substituted alkyl or alkenyl, or in each case unsubstituted or substituted aralkyl, aralkenyl, aryl or heteroaryl,R.sup.2 represents alkyl,R.sup.3 represents dialkylamino or a radical --Z--R.sup.4,Y represents oxygen, sulphur or a radical ##STR2## R.sup.4 represents alkyl or unsubstituted or substituted aralkyl, R.sup.5 represents hydrogen or alkyl andZ represents oxygen or sulphur.

    摘要翻译: 式(I)的杀真菌噻二唑取代的丙烯酸酯,其中R 1表示氢,未取代或取代的烷基或烯基,或在每种情况下未取代或取代的芳烷基,芳烯基,芳基或杂芳基,R 2表示烷基,R 3表示 二烷基氨基或基团-Z-R 4,Y表示氧,硫或基团R 4表示烷基或未取代或取代的芳烷基,R 5表示氢或烷基,Z表示氧或硫。

    Fungicidal pyridinylpyrimidines
    105.
    发明授权

    公开(公告)号:US5250533A

    公开(公告)日:1993-10-05

    申请号:US844808

    申请日:1992-03-02

    CPC分类号: C07D401/04 A01N43/54

    摘要: Fungicidal pyridinylpyrimidines of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen, alkoxy, alkylthio, halogenoalkyl, amino or dialkylamino, where, in the case of dialkylamino, the two radicals may, together with the nitrogen to which they are bonded, form a 5- to 7-membered, saturated or unsaturated ring which optionally contains a further hetero atom and which is optionally substituted by 1 or 2 alkyl groups; orR.sup.1 represents in each case optionally substituted aryloxy, arylthio, aralkyloxy or aralkylthio,R.sup.2 and R.sup.3 are independent of one another and are identical or different and in each case represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, alkylthio or alkoxycarbonyl,orR.sup.2 and R.sup.3 together represent anaylene chain having 3 to 6 carbon atoms which are linked via the ring positions 3 and 4 or 4 and 5,R.sup.4 represents hydrogen, halogen, alkyl, halogenoalkyl, hydroxyl, alkoxy, mercapto, alkylthio, amino or (di)alkylamino, where, in the case of dialkylamino, the two radicals may, together with the nitrogen atom to which they are bonded, form a 5- to 7-membered, 4-phenyl-2-(2-pyridyl)-pyrimidine and 4-chloro-6-phenyl-2-(2-pyridyl)-pyrimidine (disclosed in J. Org. Chem. 32 (5), 1591-6 (1967)).Furthermore, it has been found that the new pyridinylpyrimidine derivatives of the formula (I) ##STR2## in which R.sup.1 represents hydrogen, halogen, alkoxy, alkylthio, halogenoalkyl, amino or dialkylamino, where, in the case of dialkylamino, the two radicals may, together with the nitrogen atom to which they are bonded, form a 5- to 7-membered, saturated or unsaturated ring which optionally contains a further hetero atom and which is optionally substituted by 1 or 2 alkyl groups;in which furthermoreR.sup.1 represents in each case optionally substituted aryloxy, arylthio, aralkyloxy or aralkylthio,R.sup.2 and R.sup.3 are independent of one another and are identical or different and in each case represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, alkylthio or alkoxycarbonyl,orR.sup.2 and R.sup.3 together represent an alkylene chain having 3 to 6 carbon atoms which are linked via the ring positionsorR.sup.2 and R.sup.3 together represent an alkylene chain having 3 to 6 carbon atoms which are linked via the ring positions 3 and 4 or 4 and 5,R.sup.5 represents hydrogen or alkyl andAr represents unsubstituted or substituted aryl,