公开(公告)号：US06887838B2

公开(公告)日：2005-05-03

申请号：US10854696

申请日：2004-05-26

申请人： Robert Richard Dykstra ,  Gregory Scot Miracle

发明人： Robert Richard Dykstra ,  Gregory Scot Miracle

IPC分类号： C07D223/16 ,  C07D243/14 ,  C07D245/06 ,  C11D3/39 ,  C11D3/26 ,  C11D3/395

CPC分类号： C07D223/16 ,  C07D243/14 ,  C07D245/06 ,  C11D3/392 ,  C11D3/3927

摘要： Formulation components such as bleach boosting compounds selected from the group consisting of bleach boosters comprising quaternary imine cations, zwitterions, polyions having a net charge of from about +3 to about 3 and mixtures thereof, bleaching species comprising oxariridinium cations, zwitterions, polyions having a net charge of from about +3 to about −3 and mixtures thereof, and mixtures thereof are disclosed. The bleach boosting compounds increase bleaching effectiveness even in lower temperature solutions and provides improved stability toward unwanted boosting compound decomposition. The bleach boosting compounds are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a method for laundering a fabric employing the bleach compounds, a laundry additive product employing the bleach boosting compounds.

摘要翻译： 配制组分，例如选自包含季铵阳离子的漂白增强剂，两性离子，净电荷为约+3至约3的漂白剂，其混合物的混合物的漂白助剂化合物，包含氧杂环脒阳离子的漂白物质，两性离子，具有 净电荷为约+3至约-3及其混合物及其混合物。 漂白助剂化合物即使在较低温度的溶液中也能增加漂白效果，并提供改善的不利于加强化合物分解的稳定性。 漂白助剂化合物理想地适用于漂白组合物，包括具有去污表面活性剂和酶的组合物。 还提供了使用漂白化合物洗涤织物的方法，使用漂白助剂化合物的衣物添加剂产品。

公开(公告)号：US20040142844A1

公开(公告)日：2004-07-22

申请号：US10737427

申请日：2003-12-16

申请人： The Procter & Gamble Company

发明人： Greogory Scot Miracle

IPC分类号： C11D003/00

CPC分类号： C07C255/25 ,  C07C309/14 ,  C11D3/3925 ,  C11D3/3927

摘要： This invention relates to organic activators having the following formula: 1 wherein Z is a charge equalizing ion and one or more of the moieties R1, R2, R3, R4 and R5 are modified such that the one or more of the drawbacks associated with this class of molecule are essentially eliminated, cleaning compositions comprising such activators; and processes for making and using such activators and cleaning products.

摘要翻译： 本发明涉及具有下式的有机活化剂：其中Z是电荷均衡离子和一个或多个R 1，R 2，R 3，R 4和R 5的部分是 被修饰，使得与该类分子相关的一个或多个缺点基本上被消除，包含这种激活剂的清洁组合物; 以及制造和使用这种活化剂和清洁产品的方法。

公开(公告)号：US06417151B1

公开(公告)日：2002-07-09

申请号：US09402404

申请日：1999-10-04

申请人： Marita Grothus ,  Albrecht Weiss ,  Beatrix Kottwitz ,  Ulrich Pegelow ,  Guenter Uphues ,  Inken Prueser

发明人： Marita Grothus ,  Albrecht Weiss ,  Beatrix Kottwitz ,  Ulrich Pegelow ,  Guenter Uphues ,  Inken Prueser

IPC分类号： C11D300

CPC分类号： C11D3/38654 ,  C11D3/3927 ,  D06L4/12

摘要： A detergent or disinfectant composition comprising is presented having 0.5 to 10 percent by weight of an activator compound which under perhydrolysis conditions forms a percarboxylic acid, and releases a leaving group capable of being used as a substrate for enzymes, and up to 50 percent by weight of a peroxygen compound. The composition increases the oxidation of peroxide compounds in oxidation, bleaching, detergent, cleaning and disinfecting solutions, especially at low temperatures.

摘要翻译： 含有洗涤剂或消毒剂组合物的组合物含有0.5至10重量％的活化剂化合物，其在过水解条件下形成过羧酸，并释放出能够用作酶底物的离去基团，最高达50重量％ 的过氧化合物。 该组合物增加了氧化，漂白，洗涤剂，清洁和消毒溶液中过氧化物化合物的氧化，特别是在低温下。

公开(公告)号：US20010046951A1

公开(公告)日：2001-11-29

申请号：US09770287

申请日：2001-01-29

申请人： Kao Corporation

发明人： Nobuyuki Ogura ,  Muneo Aoyagi

IPC分类号： C11D007/54 ,  C11D007/18 ,  C11D003/48 ,  C11D009/42

CPC分类号： C11D3/3927 ,  C11D3/10 ,  C11D3/3925

摘要： The present invention provides a bleaching detergent composition exhibiting a wide bleaching effect for various stains including hydrophilic stains and olephilic stains, as well as an high bleaching effect and dye-transfer inhibiting effect in a wide range of temperature from a low to a high temperature of laundry water. That is, the present invention provides a bleaching detergent composition comprising (a) an alkannitrile compound having a quaternary ammonium group bondeded to a carbon atom to which the nitrile group is bonded, (b) an inorganic peroxide and (c) an alkali metal carbonate and further comprising component (d-i) an alkanoyloxybenzenesulfonic acid having an alkanoyl group of 6 to 14 carbon atoms or an alkanoyloxybenzenecarboxylic acid having an alkanoyl group of 6 to 14 carbon atoms or a salt thereof and/or (d-ii) tetraacetylethylenediamine.

摘要翻译： 本发明提供了一种漂白洗涤剂组合物，其在各种污渍（包括亲水性染色剂和亲油性染料）上显示出宽泛的漂白效果，并且在宽温度范围内具有高漂白效果和染料转移抑制效果，从低温到高温 洗衣水。 也就是说，本发明提供了一种漂白洗涤剂组合物，其包含（a）具有与腈基键合的碳原子键合的季铵基的烷腈化合物，（b）无机过氧化物和（c）碱金属碳酸盐 并且还含有具有6-14个碳原子的烷酰基的链烷酰氧基苯磺酸组分（二）或具有6-14个碳原子的烷酰基的烷酰氧基苯甲酸或其盐和/或（d-ii）四乙酰基乙二胺。

公开(公告)号：US5939373A

公开(公告)日：1999-08-17

申请号：US28633

申请日：1998-02-24

申请人： Donna Jean Haeggberg ,  William Michael Scheper

发明人： Donna Jean Haeggberg ,  William Michael Scheper

IPC分类号： C11D3/02 ,  C11D1/722 ,  C11D3/06 ,  C11D3/16 ,  C11D3/36 ,  C11D3/39 ,  C11D3/395 ,  C11D17/00 ,  C11D7/16 ,  C11D7/18 ,  C11D7/42

CPC分类号： C11D1/722 ,  C11D17/0039 ,  C11D3/06 ,  C11D3/3927 ,  C11D3/3932 ,  C11D3/3935

摘要： Automatic dishwashing detergent compositions comprising phosphate builder and metal-containing bleach catalyst, preferably catalysts containing manganese and/or selected from selected cobalt/ammonia catalysts. Preferred compositions comprise cobalt bleach catalyst having the formula:�Co(NH3).sub.n (M).sub.m (B).sub.b !T.sub.ywherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0); and when b=0, then m+n 6, and when b=1, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, wherein y is an integer to obtain a charge-balanced salt (preferably y is 1-3; most preferably 2 when T is a -1 charged anion); and wherein further the catalyst has a base hydrolysis rate constant of less than 0.23M.sup.-1 s.sup.-1 at 25.degree. C. Preferred automatic dishwashing compositions further comprise amylase and/or protease.

摘要翻译： 包括磷酸盐助洗剂和含金属的漂白催化剂的自动餐具洗涤剂组合物，优选含有锰和/或选自选择的钴/氨催化剂的催化剂。 优选的组合物包含具有下式的钴漂白催化剂：[Co（NH 3）n（M）m（B）b]其中钴处于+3氧化态; n为4或5（优选5）; M是通过一个位点与钴配位的一种或多种配体; B是通过两个位点与钴配位的配体; b为0或1（优选0）; 当b = 0时，m + n 6，当b = 1时，m = 0，n = 4; 并且T是存在于数y中的一个或多个适当选择的余离子，其中y是获得电荷平衡盐的整数（优选地，y为1-3;当T为带负电荷的阴离子时，最优选为2）。 并且其中所述催化剂在25℃下的碱水解速率常数小于0.23M-1s -1。优选的自动餐具洗涤组合物还包含淀粉酶和/或蛋白酶。

公开(公告)号：US5882355A

公开(公告)日：1999-03-16

申请号：US835246

申请日：1997-04-07

申请人： Jean Hypolites Koek

发明人： Jean Hypolites Koek

IPC分类号： C11D3/20 ,  C11D3/39 ,  C11D11/00 ,  D06L3/00

CPC分类号： C11D3/3927 ,  C11D11/0017 ,  C11D3/2072 ,  C11D3/3945 ,  C11D3/3947

摘要： A process is disclosed for cleaning of a substrate, comprising the steps of (1) adding a molecular oxygen activating system (as defined herein) to an aqueous wash liquor, containing a sufficient amount of molecular oxygen for obtaining observable cleaning, and (2) cleaning the substrate with the thus-formed wash liquor. When using said process, significant substrate cleaning results could even be obtained in the absence of any usually applied active oxygen ingredient such as perborate or percarbonate.

摘要翻译： 公开了一种用于清洁基底的方法，其包括以下步骤：（1）将含有足够量的分子氧的分子氧活化系统（如本文所定义）加入到含水洗涤液中以获得可观察到的清洁，和（2） 用如此形成的洗涤液清洗基材。 当使用所述方法时，甚至在没有任何通常使用的活性氧成分例如过硼酸盐或过碳酸盐的情况下甚至可以获得显着的底物清洗结果。

公开(公告)号：US5709815A

公开(公告)日：1998-01-20

申请号：US771493

申请日：1996-12-23

申请人： Robert Joseph Heffner ,  Robert John Steltenkamp

发明人： Robert Joseph Heffner ,  Robert John Steltenkamp

IPC分类号： C11D3/39 ,  C11D7/54

CPC分类号： C11D3/3927 ,  C11D3/392

摘要： Bleaching compositions comprising a bleaching compound and an oxopiperidinium salt each preferably present in a range of about 1 to about 75% by weight. Additives, such as, surfactants, anti-foaming agents, fabric softeners, stabilizers, inorganic builder salts, buffers, enzymes and the like may also be present. The compositions can be formulated as dry concentrated mixtures encapsulated or in loose powder form, aqueous solutions, aqueous solutions containing non-aqueous solvents and like forms. The compositions are effective as bleaching agents from below room temperature to higher temperatures, are biodegradable and are environmentally safe.

摘要翻译： 包含漂白化合物和氧代​​哌啶鎓盐的漂白组合物各自优选以约1至约75重量％的范围存在。 还可以存在添加剂，如表面活性剂，消泡剂，织物软化剂，稳定剂，无机助洗剂盐，缓冲剂，酶等。 组合物可以配制成包封的或以松散粉末形式的干燥浓缩混合物，水溶液，含有非水溶剂和类似形式的水溶液。 该组合物作为漂白剂在低于室温至较高温度下是有效的，是可生物降解的并且是环境安全的。

公开(公告)号：US5686015A

公开(公告)日：1997-11-11

申请号：US298903

申请日：1994-08-31

申请人： Alan David Willey ,  Gregory Scot Miracle ,  Kevin Lee Kott ,  Michael Eugene Burns ,  Gerard Marcel Abel Baillely ,  Nour-Eddine Guedira ,  Frederick Edward Hardy ,  Lucille Florence Taylor ,  Mark Robert Sivik

发明人： Alan David Willey ,  Gregory Scot Miracle ,  Kevin Lee Kott ,  Michael Eugene Burns ,  Gerard Marcel Abel Baillely ,  Nour-Eddine Guedira ,  Frederick Edward Hardy ,  Lucille Florence Taylor ,  Mark Robert Sivik

IPC分类号： C07D223/10 ,  C07D233/06 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  C09K3/00 ,  C01B15/055

CPC分类号： C07D223/10 ,  C07D233/06 ,  C11D3/3927

摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising particular quaternary-substituted bleach activators, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of quaternary-substituted bleach activators having specific leaving groups with a conjugate acid pKa above 13 and with specific ratios of the rate of perhydrolysis to the rate of hydrolysis and the rate of perhydrolysis to the rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.

摘要翻译： 提供漂白组合物，洗衣和自动洗碗洗涤剂组合物，其包含特定的四价取代的漂白活化剂。 更具体地说，本发明涉及通过选择具有特异离去基团的季取代漂白活化剂，其中共轭酸pKa高于13并具有比例的过水解速率与水解速率的比例，提供增强的清洁/漂白效果 过水解速率与二酰基过氧化物产生速率有关。 包括优选的活化剂化合物和使用活化剂洗涤织物，硬表面和餐具的方法。

公开(公告)号：US5662827A

公开(公告)日：1997-09-02

申请号：US393063

申请日：1995-02-23

申请人： Philip H. Steiger ,  Shaun F. Clancy ,  Owen Portwood

发明人： Philip H. Steiger ,  Shaun F. Clancy ,  Owen Portwood

IPC分类号： C07C219/06 ,  C11D1/62 ,  C11D3/39 ,  C11D7/32 ,  C11D7/54 ,  D06L3/02 ,  C09K3/00 ,  C01B15/10 ,  C07C67/02

CPC分类号： D06L3/025 ,  C07C219/06 ,  C11D3/3927

摘要： Disclosed are bleaching compositions comprising diquaternary ammonium esters which are useful as bleach activators with a peroxygen compound to yield peroxide in solution.

摘要翻译： 公开了包含二季铵盐的漂白组合物，其可用作具有过氧化合物的漂白活化剂以在溶液中产生过氧化物。

公开(公告)号：US5561235A

公开(公告)日：1996-10-01

申请号：US486904

申请日：1995-06-07

申请人： Eugene P. Gosselink ,  Gregory S. Miracle ,  Alan D. Willey ,  Michael E. Burns ,  Kevin L. Kott ,  Mark R. Sivik ,  Lucille F. Taylor

发明人： Eugene P. Gosselink ,  Gregory S. Miracle ,  Alan D. Willey ,  Michael E. Burns ,  Kevin L. Kott ,  Mark R. Sivik ,  Lucille F. Taylor

IPC分类号： B01J31/16 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  C07D231/00 ,  C07D239/00

CPC分类号： C11D3/3927

摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom,, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.

摘要翻译： 提供了包含具有至少一个季氮原子的多取代的漂白活化剂的漂白组合物，衣物和自动餐具洗涤剂组合物。 更具体地说，本发明涉及通过选择具有特定离去基团的多取代的季铵漂白活化剂，其中共轭酸水溶液pKa高于13并具有有效比例的过水解速率与水解速率和/ 过水解速率与二酰基过氧化物产生速率有关。 包括优选的活化剂化合物和使用活化剂洗涤织物，硬表面和餐具的方法。