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公开(公告)号：US5560862A
公开(公告)日：1996-10-01
申请号：US486905
申请日：1995-06-07
申请人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
发明人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
CPC分类号： C11D3/3927
摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
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公开(公告)号：US5561235A
公开(公告)日：1996-10-01
申请号：US486904
申请日：1995-06-07
申请人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
发明人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
IPC分类号： B01J31/16 , C11D3/39 , C11D3/395 , C11D7/54 , C07D231/00 , C07D239/00
CPC分类号： C11D3/3927
摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom,, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
摘要翻译： 提供了包含具有至少一个季氮原子的多取代的漂白活化剂的漂白组合物，衣物和自动餐具洗涤剂组合物。 更具体地说，本发明涉及通过选择具有特定离去基团的多取代的季铵漂白活化剂，其中共轭酸水溶液pKa高于13并具有有效比例的过水解速率与水解速率和/ 过水解速率与二酰基过氧化物产生速率有关。 包括优选的活化剂化合物和使用活化剂洗涤织物，硬表面和餐具的方法。
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公开(公告)号：US5460747A
公开(公告)日：1995-10-24
申请号：US298650
申请日：1994-08-31
申请人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
发明人： Eugene P. Gosselink , Gregory S. Miracle , Alan D. Willey , Michael E. Burns , Kevin L. Kott , Mark R. Sivik , Lucille F. Taylor
CPC分类号： C11D3/3927
摘要： Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
摘要翻译： 提供了包含具有至少一个季氮原子的多取代的漂白活化剂的漂白组合物，衣物和自动餐具洗涤剂组合物。 更具体地说，本发明涉及通过选择具有特定离去基团的多取代的季铵漂白活化剂，其中共轭酸水溶液pKa高于13并具有有效比例的过水解速率与水解速率和/ 过水解速率与二酰基过氧化物产生速率有关。 包括优选的活化剂化合物和使用活化剂洗涤织物，硬表面和餐具的方法。
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4.发明授权Automatic dishwashing compositions comprising quaternary substituted bleach activators 失效包含四元取代的漂白活化剂的自动餐具洗涤组合物
公开(公告)号：US5578136A
公开(公告)日：1996-11-26
申请号：US298904
申请日：1994-08-31
申请人： Lucille F. Taylor , Mark R. Sivik , Alan D. Willey , James C. T. Burckett-St. Laurent , Frederick A. Hartman
发明人： Lucille F. Taylor , Mark R. Sivik , Alan D. Willey , James C. T. Burckett-St. Laurent , Frederick A. Hartman
IPC分类号： C07D211/76 , C07D223/10 , C11D3/386 , C11D3/39 , C11D3/28 , C11D3/395 , C11D7/18
CPC分类号： C07D223/10 , C11D3/38609 , C11D3/3927
摘要： Automatic dishwashing detergent compositions, comprising particular quaternary-substituted bleach activators, are provided. More specifically, the invention relates to granular automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the selection of quaternary-substituted bleach activators having specific features, such as caprolactam or valerolactam leaving groups and/or the ability to form particular cationic aliphatic peracid structures in solution. Preferred automatic dishwashing compositions comprise amylase enzymes. Included are preferred activator compounds and methods for washing tableware in domestic automatic dishwashing appliances using the activators.
摘要翻译： 提供了包含特定的四季取代的漂白活化剂的自动餐具洗涤剂组合物。 更具体地，本发明涉及通过选择具有特定特征的季铵取代的漂白活化剂（例如己内酰胺或戊内酰胺离去基团）和/或形成特定的阳离子脂族过酸结构的能力来提供增强的清洁/漂白有益效果的颗粒状自动餐具洗涤剂 在解决方案。 优选的自动餐具洗涤组合物包含淀粉酶。 包括优选的活化剂化合物和在使用活化剂的家用自动洗碗设备中洗餐具的方法。
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5.发明授权Automatic dishwashing detergent having bleach system comprising monopersulfate, cationic bleach activator and perborate or percarbonate 失效具有包含单过硫酸盐，阳离子漂白活化剂和过硼酸盐或过碳酸盐的漂白体系的自动餐具洗涤剂
公开(公告)号：US5599781A
公开(公告)日：1997-02-04
申请号：US508196
申请日：1995-07-27
CPC分类号： C11D3/3935 , C11D17/0039 , C11D3/3927 , C11D3/3932
摘要： Detergents, especially automatic dishwashing detergents, comprising a stain removal system especially adapted for removal of tea stains, coffee stains and the like. The compositions comprise monopersulfate bleach such as 2KHSO.sub.5 .cndot.KHSO.sub.4 .cndot.K.sub.2 SO.sub.4 in combination with perborate or percarbonate at specific ratios, in combination with certain cationic or quaternary-substituted bleach activators.
摘要翻译： 洗涤剂，特别是自动洗碗洗涤剂，其包含特别适用于去除茶渍，咖啡污渍等的去污系统。 组合物包含单过硫酸盐漂白剂，例如2KHSO 5·KHSO 4·K 2 SO 4与特定比例的过硼酸盐或过碳酸盐组合，与某些阳离子或季取代的漂白活化剂组合。
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6.发明授权Automatic dishwashing compositions comprising multiquaternary bleach activators 失效包含多季铵漂白活化剂的自动餐具洗涤组合物
公开(公告)号：US5520835A
公开(公告)日：1996-05-28
申请号：US438126
申请日：1995-05-08
IPC分类号： C07D211/76 , C07D223/10 , C11D3/386 , C11D3/39 , C11D3/395 , C11D7/54 , C07C101/02
CPC分类号： C07D223/10 , C11D3/38609 , C11D3/3927
摘要： Improved detergent compositions, especially granular automatic dishwashing detergents, comprising multiquaternary bleach activators are provided. The bleach activators contain multiple quaternary nitrogen groups, preferably at least three such groups and preferably have at least one quaternary nitrogen group in the peracid-forming portion of the bleach activator as well as at least one quaternary nitrogen group in the leaving-group portion.
摘要翻译： 提供了改进的洗涤剂组合物，特别是颗粒自动餐具洗涤剂，其包含多季度漂白活化剂。 漂白活化剂含有多个季氮基团，优选至少三个这样的基团，并且优选在漂白活化剂的过酸形成部分中具有至少一个季氮基团以及离去基团部分中的至少一个季氮基团。
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7.发明授权
公开(公告)号：US5559089A
公开(公告)日：1996-09-24
申请号：US442912
申请日：1995-05-17
申请人： Frederick A. Hartman , Ronald J. Rice , James C. T. R. Burckett-St. Laurent , Lucille F. Taylor , Donna J. Haeggberg
发明人： Frederick A. Hartman , Ronald J. Rice , James C. T. R. Burckett-St. Laurent , Lucille F. Taylor , Donna J. Haeggberg
CPC分类号： C11D3/3942 , C11D17/065 , C11D3/3761 , C11D3/38609 , C11D3/394
摘要： Automatic dishwashing detergents are provided in convenient, compact form without chlorine bleaches or phosphate builders. Thus, monopersulfate bleach such as 2KHSO.sub.5.KHSO.sub.4.K.sub.2 SO.sub.4 is used in combination with protease or amylase enzymes and acrylate organic dispersants to provide good cleaning of tableware. Weak builders such as citrate and pH-adjusting agents such as carbonate, bicarbonate and silicate can be present in the composition.
摘要翻译： 自动餐具洗涤剂以方便，紧凑的形式提供，不含氯漂白剂或磷酸盐助洗剂。 因此，单硫酸盐漂白剂如2KHSO5.KHSO4.K2SO4与蛋白酶或淀粉酶和丙烯酸酯有机分散剂组合使用，以提供餐具的良好清洁。 较弱的助洗剂如柠檬酸盐和pH调节剂如碳酸盐，碳酸氢盐和硅酸盐可以存在于组合物中。
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8.发明授权Method for using solid particulate fabric softener in automatic dosing dispenser 失效固体颗粒织物柔软剂在自动计量分配器中的使用方法
公开(公告)号：US5536421A
公开(公告)日：1996-07-16
申请号：US261317
申请日：1994-06-16
CPC分类号： C11D17/046 , C11D1/835 , C11D3/001 , C11D1/62 , C11D1/72
摘要： A method of softening fabrics where the consumer adds an effective amount of a particulate fabric softening composition comprising fabric softener agent to an automatic dosing dispenser with water, seals the dispenser, and places the automatic dosing dispenser into a washing machine at the beginning of the wash process. The mechanical agitation and/or heat of the wash cycle aids in forming a finely divided emulsion/dispersion of fabric softener agent which is then released from the dispenser during the rinse cycle.
摘要翻译： 软化织物的方法，其中消费者将有效量的包含织物柔软剂的微粒织物柔软组合物添加到具有水的自动计量分配器中，密封分配器，并且在洗涤开始时将自动计量分配器放入洗衣机中 处理。 洗涤循环的机械搅拌和/或热量有助于形成织物柔软剂的细分乳液/分散体，然后在漂洗循环期间从分配器中释放。
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9.发明授权Concentrated fabric softener compositions containing biodegradable fabric softeners 失效含有可生物降解织物软化剂的浓缩织物柔软剂组合物
公开(公告)号：US5545350A
公开(公告)日：1996-08-13
申请号：US333902
申请日：1994-11-03
申请人： Ellen S. Baker , Jean-Francois Bodet , Hugo J. M. Demeyere , Frederick A. Hartman , Bruno A. Hubesch , Robert Mermelstein , Lucille F. Taylor , Errol H. Wahl
发明人： Ellen S. Baker , Jean-Francois Bodet , Hugo J. M. Demeyere , Frederick A. Hartman , Bruno A. Hubesch , Robert Mermelstein , Lucille F. Taylor , Errol H. Wahl
IPC分类号： D06M13/46 , C11D1/62 , C11D1/645 , C11D1/72 , C11D1/835 , C11D3/00 , C11D11/00 , D06M13/02 , D06M13/188 , D06M13/192 , D06M13/224 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/35 , D06M13/352 , D06M13/463
CPC分类号： C11D1/835 , C11D1/62 , C11D1/645 , C11D11/0082 , C11D11/0094 , C11D3/001 , C11D3/0015 , C11D1/72
摘要： Compositions are disclosed containing fabric softener compound having two hydrophobic groups attached to the remainder of the compound through ester linkages (DEQA), said compositions being concentrated and containing viscosity/dispersibility modifiers which are single long chain cationic surfactants, highly ethoxylated nonionic surfactants and/or mixtures thereof. Premixes of the DEQA and viscosity modifiers to lower the viscosity of the molten DEQA are disclosed. Processes for making aqueous liquid compositions from solid particulate compositions containing the DEQA are also disclosed.
摘要翻译： 公开了包含具有通过酯键（DEQA）连接到化合物的其余部分的两个疏水基团的织物柔软剂组合物，所述组合物被浓缩并且包含粘度/分散性改性剂，其是单长链阳离子表面活性剂，高度乙氧基化的非离子表面活性剂和/或 其混合物。 公开了DEQA的预混物和降低熔融DEQA粘度的粘度调节剂。 还公开了从含有DEQA的固体颗粒组合物制备含水液体组合物的方法。
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10.发明授权Granular fabric softener compositions which form aqueous emulsion concentrates 失效形成水性乳液浓度的颗粒织物肥皂组合物
公开(公告)号：US5185088A
公开(公告)日：1993-02-09
申请号：US689406
申请日：1991-04-22
IPC分类号： D06M13/46 , C11D1/04 , C11D1/40 , C11D1/62 , C11D1/66 , C11D1/68 , C11D1/72 , C11D1/74 , C11D1/835 , C11D3/00 , D06M13/02 , D06M13/144 , D06M13/148 , D06M13/224 , D06M13/322 , D06M13/325 , D06M13/463 , D06M13/47 , D06M23/00
CPC分类号： C11D3/001 , C11D1/835 , C11D3/0015 , C11D1/04 , C11D1/40 , C11D1/62 , C11D1/667 , C11D1/72 , C11D1/74
摘要： A granular fabric softening composition, which can be added to water to form an aqueous concentrated emulsion, comprising nonionic fabric softener, preferably a fatty alkyl ester of a polyhydric alcohol, and a mono-long-chain alkyl cationic surfactant. In particular, the use of a sorbitan ester with a mono-long-chain alkyl cationic surfactant provides a granular softening agent which can be used to form a highly dispersed, concentrated, aqueous composition which, when added to, e.g., a rinse cycle of a typical washing process, effectively deposits onto fabric from the aqueous bath.
摘要翻译： 一种粒状织物软化组合物，其可以加入到水中以形成水性浓缩乳液，其包含非离子织物柔软剂，优选多元醇的脂肪烷基酯和单长链烷基阳离子表面活性剂。 特别地，使用脱水山梨糖醇酯与单长链烷基阳离子表面活性剂提供了一种颗粒软化剂，其可用于形成高度分散，浓缩的水性组合物，当将其加入到例如漂洗循环 典型的洗涤过程有效地从水浴中沉积到织物上。
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