摘要:
The present invention is drawn to the use of blocked maleimide monomers for the preparation of latex particles, including those having active maleimide surface groups. In accordance with this, a method of forming latex particulates can comprise the steps of preparing a monomer emulsion including an aqueous phase and an organic monomer phase, wherein the organic monomer phase includes at least one blocked maleimide monomer; polymerizing the organic monomer phase to form blocked maleimide latex particulates dispersed in the aqueous phase; and unblocking the blocked maleimide latex particulates to form latex particulates with active maleimide groups at least on the surface of the latex particulates.
摘要:
An encapsulated pigment particle includes a pigment particle core and a polymer encapsulation layer established on a surface of the pigment particle core. The polymer encapsulation layer includes a polymer and a hydrophobe integrated with the polymer. The hydrophobe has the following structure: wherein R1 and R2 are independently selected from H, a linear or branched alkyl group with its number of carbons ranging from 1 to 40, and an aryl group with its number of benzene rings ranging from 1 to 10; wherein R3 is H or OH; wherein Y1 is selected from a bond, 0, a linear or branched alkylene group with its number of carbons ranging from 1 to 40, and an arylene group with its number of benzene rings ranging from 1 to 10; and wherein Y2 is selected from a bond and (CH2)n, where n=0 to 40.
摘要:
The present invention is drawn to a surfactant initiator. The surfactant initiator includes a first hydrophilic chemical group bonded to a first hydrophobic chemical group to form a first portion. A second portion is also included, made up of a second hydrophilic chemical group bonded to a second hydrophobic chemical group. A homolytic cleavable group chemically bonds the first and second portions. At least one of the first and second portions is configured to initiate free-radical polymerization upon separation of the homolytic cleavable group. Such surfactant initiators can be used to produce latex particulates and associated suspensions and inks.
摘要:
Disclosed herein are pigment dispersions and inks formulated using the same; including at least one dispersed pigment, an aqueous carrier; and at least one block copolymer dispersant having Structure I and comprising a hydrophobic block (A) and a hydrophilic block (B); at least one block copolymer having Structure I and comprising a hydrophobic block (A) and a hydrophilic block (B);
摘要:
The present disclosure is drawn to methods and compositions directed at encapsulated pigments. As such, an encapsulated pigment can comprise a pigment and a polymer encapsulating the pigment, where the polymer comprises a monomer and a RAFT reagent. Additionally, a method of encapsulating pigments can comprise dispersing a pigment in an aqueous solution to form a pigment dispersion, adding a monomer to the pigment dispersion, adding a RAFT reagent to the pigment dispersion, and polymerizing the monomer using the RAFT reagent in the presence of the pigment to form an encapsulated pigment. Further, the present disclosure provides ink-jet inks comprising the encapsulated pigments.
摘要:
The present invention is drawn to passivated pigment suspensions, methods of forming passivated pigment suspensions, and ink sets based thereupon. The coated pigment suspension can comprise a liquid vehicle and a passivated pigment suspended in the liquid vehicle. The coated pigment can include a pigment core, on which is deposited a passivation layer comprising a polymer precursor synthesized while separate from the pigment. A polymer encapsulation layer may be attached to or deposited on the passivation layer.
摘要:
The present invention is directed to latex particulates having a greater concentration of acid at their surfaces than at their cores. A method of making such particulates can comprise copolymerizing an acidic monomer with a non-acidic monomer so as to yield a copolymer chain having more acidic monomer at one end than at the other.
摘要:
The present invention is drawn to pigment suspensions, methods of forming pigment suspensions, and ink sets. The pigment suspension can comprise an aqueous liquid vehicle and a polymer-encapsulated pigment suspended in the liquid vehicle. The polymer-encapsulated pigment can include a pigment core, a bridging layer deposited on a surface of the pigment core, and a polymer encapsulation layer attached to or deposited on the bridging layer.
摘要:
A latex particle for use in ink-jet inks can comprise a latex polymer core and a latex polymer shell such that the latex polymer shell has a Tg that is at least 10° C. greater than the Tg of the latex polymer core. The latex polymer core can comprise at least one polymerized core monomer. The latex polymer shell can comprise at least two polymerized shell monomers including a urethane acrylate monomer.
摘要:
Disclosed herein are pigment dispersions and inks formulated using the same; including at least one dispersed pigment, an aqueous carrier; and at least one block copolymer dispersant having Structure I and comprising a hydrophobic block (A) and a hydrophilic block (B); at least one block copolymer having Structure I and comprising a hydrophobic block (A) and a hydrophilic block (B);