公开(公告)号：US20150203422A1

公开(公告)日：2015-07-23

申请号：US14363918

申请日：2011-12-14

Applicant: Dominique Deur-Bert ,  Bertrand Collier ,  Laurent Wendlinger

Inventor： Dominique Deur-Bert ,  Bertrand Collier ,  Laurent Wendlinger

IPC: C07C17/25 ,  C07C17/20

CPC classification number: C07C17/25 ,  B01J23/26 ,  B01J23/866 ,  B01J27/132 ,  B01J37/12 ,  B01J37/24 ,  B01J37/26 ,  C01B7/191 ,  C07C17/206 ,  C07C17/38 ,  C07C17/383 ,  C07C19/08 ,  C07C21/18

Abstract: The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene from 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane, comprising the following steps: (a) catalytic reaction of 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF into a reaction mixture comprising HCl, 2-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, unreacted HF, and optionally 1,1,1,2,2-pentafluoropropane; (b) separating the reaction mixture into a first stream comprising HCl and 2,3,3,3-tetrafluoropropene and a second stream comprising HF, 2-chloro-3,3,3-trifluoropropene and optionally 1,1,1,2,2-pentafluoropropane; (c) catalytic reaction of the second stream into a reaction mixture comprising 2,3,3,3-tetrafluoropropene, HCl, unreacted 2-chloro-3,3,3-trifluoropropene, unreacted HF and optionally 1,1,1,2,2-pentafluoropropane and (d) feeding the reaction mixture of step (c) directly without separation to step (a).

Abstract translation: 本发明提供从1,1,1,2,3-五氯丙烷和/或1,1,2,2,3-五氯丙烷制备2,3,3,3-四氟丙烯的方法，包括以下步骤：（ a）1,1,1,2,3-五氯丙烷和/或1,1,2,2,3-五氯丙烷与HF的催化反应进入包含HCl，2-氯-3,3,3-三氟丙烯的反应混合物 ，2,3,3,3-四氟丙烯，未反应的HF和任选的1,1,1,2,2-五氟丙烷; （b）将反应混合物分离成包含HCl和2,3,3,3-四氟丙烯的第一料流和包含HF，2-氯-3,3,3-三氟丙烯和任选的1,1,1,2 ，2-五氟丙烷; （c）将第二流催化反应成包含2,3,3,3-四氟丙烯，HCl，未反应的2-氯-3,3,3-三氟丙烯，未反应的HF和任选的1,1,1,2 （d）直接进料步骤（c）的反应混合物而不分离步骤（a）。

公开(公告)号：US08389779B2

公开(公告)日：2013-03-05

申请号：US12842737

申请日：2010-07-23

Applicant: Karine Avril ,  Bertrand Collier

Inventor： Karine Avril ,  Bertrand Collier

IPC: C07C17/25

CPC classification number: C07C21/18 ,  C07C17/25 ,  C07C17/354 ,  C07C17/383 ,  C07C19/08

Abstract: A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene comprising the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; (iv) purification of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage; and (v) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene; and (vi) purification of the 2,3,3,3-tetrafluoro-1-propene of the preceding stage.

Abstract translation: 本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3， 3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; （iv）前一阶段获得的1,1,1,2,3-五氟丙烷的纯化; 和（v）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯; 和（vi）前一阶段的2,3,3,3-四氟-1-丙烯的纯化。

公开(公告)号：US20090326284A1

公开(公告)日：2009-12-31

申请号：US12302645

申请日：2007-05-09

Applicant: Bertrand Collier ,  Géraldine Cavallini ,  Béatrice Boussand

Inventor： Bertrand Collier ,  Géraldine Cavallini ,  Béatrice Boussand

IPC: C07C19/08

CPC classification number: C07C19/08 ,  C07C17/206 ,  C07C17/21 ,  Y02P20/582

Abstract: The invention relates to a method for producing pentafluoroethane, and especially to a method comprising (i) a step during which perchloroethylene and optionally 2,2-dichloro-1,1,1-trifluoroethane and/or 2-chloro-1,1,1,2-tetrafluoroethane react(s) with hydrofluoric acid in a gaseous phase in the presence of a catalyst in an adiabatic multi-stage reactor, and optionally (ii) a step of separating the flow produced in step (i) in order to obtain a fraction of light products and a fraction of heavy products.

Abstract translation: 本发明涉及一种生产五氟乙烷的方法，特别涉及一种方法，其包括（i）全氯乙烯和任选的2,2-二氯-1,1,1-三氟乙烷和/或2-氯-1,1， 在绝热多级反应器中，在催化剂存在下，1,2-二氟乙烷与氢氟酸在气相中反应，和任选地（ii）分离步骤（i）中产生的流以便 获得一小部分轻质产品和一部分重质产品。

公开(公告)号：US20090270659A1

公开(公告)日：2009-10-29

申请号：US12302659

申请日：2007-05-09

Applicant: Bertrand Collier ,  Stephanie Amerio ,  Michel Devic

Inventor： Bertrand Collier ,  Stephanie Amerio ,  Michel Devic

IPC: C07C21/18 ,  C07C19/08 ,  B01J12/00

CPC classification number: B01J8/0446 ,  B01J2208/00274 ,  B01J2219/00006 ,  C07C17/206 ,  C07C17/21 ,  C07C17/383 ,  C07C19/08

Abstract: The invention relates to a method for producing hydrofluorocarbons. The method comprises a step of reacting at least one hydro(fluoro)chlorocarbon or chlorocarbon with hydrofluoric acid in a gaseous phase in the presence of a catalyst, and a step of separating fluorination reaction products from the mixture. The method is characterized in that the gaseous flow from the reaction is compressed by means of a compressor before being subjected to the separation step. The invention also relates to a device for implementing the method.

Abstract translation: 本发明涉及一种生产氢氟烃的方法。 该方法包括在催化剂存在下使气态中至少一种氢（氟）氯化碳或氯代烃与氢氟酸反应的步骤和从混合物中分离氟化反应产物的步骤。 该方法的特征在于，在进行分离步骤之前，来自反应的气流通过压缩机被压缩。 本发明还涉及一种用于实现该方法的装置。

公开(公告)号：US5951830A

公开(公告)日：1999-09-14

申请号：US951476

申请日：1997-10-16

Applicant: Rene Bertocchio ,  Andre Lantz ,  Daniel Roland ,  Bertrand Collier

Inventor： Rene Bertocchio ,  Andre Lantz ,  Daniel Roland ,  Bertrand Collier

IPC: C07B61/00 ,  C07C17/395 ,  C07C19/12 ,  C07C1/00 ,  B01D5/00 ,  B01D17/06 ,  B01D53/00

CPC classification number: C07C17/395 ,  Y10S210/915

Abstract: To remove the olefinic impurities from a hydrochlorofluoroethane of formula: CF.sub.3 --CHClX (X=H, F, or Cl), it is subjected to a photochlorination stage.

Abstract translation: 为了从式CF3-CHClX（X = H，F或Cl）的氢氯氟乙烷中除去烯属杂质，将其进行光氯化阶段。

公开(公告)号：US20110021849A1

公开(公告)日：2011-01-27

申请号：US12842737

申请日：2010-07-23

Applicant: Karine Avril ,  Bertrand Collier

Inventor： Karine Avril ,  Bertrand Collier

IPC: C07C21/18 ,  C07C17/38 ,  C07C17/383

CPC classification number: C07C21/18 ,  C07C17/25 ,  C07C17/354 ,  C07C17/383 ,  C07C19/08

Abstract: A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene comprising the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; (iv) purification of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage; and (v) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene; and (vi) purification of the 2,3,3,3-tetrafluoro-1-propene of the preceding stage.

Abstract translation: 本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3， 3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; （iv）前一阶段获得的1,1,1,2,3-五氟丙烷的纯化; 和（v）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯; 和（vi）前一阶段的2,3,3,3-四氟-1-丙烯的纯化。