公开(公告)号：US07531582B2

公开(公告)日：2009-05-12

申请号：US11466687

申请日：2006-08-23

申请人： Eniko Toma ,  Peter G. Odell ,  C. Geoffrey Allen ,  Jennifer Lynne Belelie

发明人： Eniko Toma ,  Peter G. Odell ,  C. Geoffrey Allen ,  Jennifer Lynne Belelie

IPC分类号： C09D11/00 ,  G01D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： Ink vehicles having improved gellant solubility and ink compositions including such ink vehicles are provided. Exemplary ink vehicles include first and second co-monomers, and a gellant that includes that includes a curable epoxy-polyamide composite gellant; in which the first and second co-monomers are radiation curable are different from each other. Additional exemplary ink vehicles include at least two chemically distinct gellants. The chemically distinct gellant materials include a first gellant that includes a curable epoxy-polyamide composite gellant, and a second gellant that includes an amide gellant. Methods for making and using these ink vehicles and ink compositions are also provided.

摘要翻译： 提供具有改善的胶凝剂溶解性的油墨载体和包括这种油墨载体的油墨组合物。 示例性油墨载体包括第一和第二共聚单体，和包含可固化环氧 - 聚酰胺复合胶凝剂的胶凝剂; 其中第一和第二共聚单体是可辐射固化的彼此不同。 另外的示例性油墨载体包括至少两种化学上不同的胶凝剂。 化学不同的胶凝剂材料包括包含可固化环氧 - 聚酰胺复合胶凝胶的第一胶凝剂和包含酰胺胶凝剂的第二胶凝剂。 还提供了制造和使用这些油墨载体和油墨组合物的方法。

公开(公告)号：US07449515B2

公开(公告)日：2008-11-11

申请号：US11289883

申请日：2005-11-30

申请人： Jennifer L. Belelie ,  Rina Carlini ,  Eniko Toma

发明人： Jennifer L. Belelie ,  Rina Carlini ,  Eniko Toma

IPC分类号： C08G18/08 ,  C09D11/00

CPC分类号： C08G18/755 ,  C08G18/2865 ,  C08G18/3206 ,  C08G18/6715 ,  C08G18/6735 ,  C09D175/16

摘要： Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a first isocyanate-derived compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an alcohol having at least one ethylenic unsaturation; (b) an amine having at least one ethylenic unsaturation; (c) an acid having at least one ethylenic unsaturation; or (d) mixtures thereof, (B) a second isocyanate-derived compound which is the reaction product of (1) a diisocyanate; (2) a monoalcohol having exactly one hydroxyl group and having at least one ethylenic unsaturation; and (3) a polyol having two or more hydroxyl groups, (C) an optional phase change inducing component, said phase change inducing component containing at least one hydroxyl group, said phase change inducing component having a melting point of about 40° C. or higher, and (D) an optional curable viscosity modifying ester, said ink being curable upon exposure to ultraviolet radiation.

摘要翻译： 公开了一种相变油墨，其包含着色剂，引发剂和相变油墨载体，所述载体包含（A）第一异氰酸酯衍生化合物，其为包含（1）异氰酸酯的混合物的反应产物; 和（2）包含（a）具有至少一个烯属不饱和度的醇的组分; （b）具有至少一个烯属不饱和度的胺; （c）具有至少一个烯属不饱和度的酸; 或（d）其混合物，（B）第二异氰酸酯衍生化合物，其为（1）二异氰酸酯的反应产物; （2）具有正好一个羟基并具有至少一个烯属不饱和度的一元醇; 和（3）具有两个或多个羟基的多元醇，（C）任选的相变诱导组分，所述相变诱导组分含有至少一个羟基，所述相变诱导组分的熔点约为40℃。 或更高，和（D）任选的可固化粘度改性酯，所述油墨在暴露于紫外线辐射下是可固化的。

公开(公告)号：US20080000384A1

公开(公告)日：2008-01-03

申请号：US11427172

申请日：2006-06-28

申请人： Jennifer L. BELELIE ,  Peter G. ODELL ,  Eniko TOMA ,  Christopher A. WAGNER ,  C. Geoffrey ALLEN ,  Stephan V. DRAPPEL

发明人： Jennifer L. BELELIE ,  Peter G. ODELL ,  Eniko TOMA ,  Christopher A. WAGNER ,  C. Geoffrey ALLEN ,  Stephan V. DRAPPEL

IPC分类号： C09D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： Radiation curable phase change ink comprising an ink vehicle that includes at least one curable carrier, at least one gellant, at least one curable wax and at least one photoinitiator. In a method of forming an image with the ink, the radiation curable phase change ink is melted, then jetted onto an image receiving substrate, wherein the radiation curable phase change ink forms a gel state, and exposed to ultraviolet light to cure the curable components of the radiation curable phase change ink. The wax cures into the structure of the ink, thereby generating a robust image of excellent gloss.

摘要翻译： 包含油墨载体的可辐射固化相变油墨，其包含至少一种可固化载体，至少一种胶凝剂，至少一种可固化蜡和至少一种光引发剂。 在用油墨形成图像的方法中，将可辐射固化相变油墨熔化，然后喷射到图像接收基板上，其中可辐射固化相变油墨形成凝胶状态，并暴露于紫外光以固化可固化组分 的可辐射固化相变油墨。 蜡固化成油墨的结构，从而产生具有优异光泽的坚固的图像。

公开(公告)号：US07271284B2

公开(公告)日：2007-09-18

申请号：US11289882

申请日：2005-11-30

申请人： Eniko Toma ,  Adela Goredema ,  Jennifer L. Belelie ,  Peter G. Odell

发明人： Eniko Toma ,  Adela Goredema ,  Jennifer L. Belelie ,  Peter G. Odell

IPC分类号： C07C229/00

CPC分类号： C08F290/06 ,  C08F220/14 ,  C08F290/061 ,  C08F290/067 ,  C08G69/26 ,  C08G69/28

摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the presence of a catalyst, a solvent, and a coupling agent to form an oligoamide intermediate; and (b) reacting the oligoamide intermediate with an alcohol of the formula R1—OH to form the product.

摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 R 1，R 2，R 3和R 3各自独立地是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 4， 各自独立地是氢原子或烷基，n是表示重复酰胺单元数的整数，并且至少为1，所述方法包括： （a）使式（Ⅳ）的二酸与式-I-in-line-formula中的二酸反应， 在存在催化剂，溶剂和偶联剂的情况下，使式II的化合物描述=“内联式”末端=“尾”→，形成低聚酰胺中间体; 和（b）使低聚酰胺中间体与式（Ⅳ）的醇反应，其中式（Ⅳ）中，式 -line-formula description =“In-Line Formulas”end =“tail”？>来形成产品。

公开(公告)号：US07259275B2

公开(公告)日：2007-08-21

申请号：US11290328

申请日：2005-11-30

申请人： Jennifer L. Belelie ,  Adela Goredema ,  Peter G. Odell ,  Eniko Toma

发明人： Jennifer L. Belelie ,  Adela Goredema ,  Peter G. Odell ,  Eniko Toma

IPC分类号： C07C229/00

CPC分类号： C07C231/02 ,  C08G69/26 ,  C08G69/28 ,  C09D11/34 ,  C07C233/34 ,  C07C233/36

摘要： Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the absence of a solvent while removing water from the reaction mixture to form an acid-terminated oligoamide intermediate; and (b) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a coupling agent and a catalyst to form the product.

摘要翻译： 公开了一种制备下式化合物的方法，其中R 1是具有至少一个烯属不饱和键的烷基，具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 烯键式不饱和键，R 2和R 3各自独立地为亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，n为代表 重复酰胺单元的数目并且至少为1，所述方法包括：（a）使式Ⅳ的二酸与-in-line-formula description =“In-Line Formulas”end =“lead”→> HOOC-R' 在不存在溶剂的情况下，在从反应混合物中除去水的情况下，使用下式所示的二胺，在线式描述=“In-line Formula”中， 以形成酸封端的低聚酰胺中间体; 和（b）使酸封端的低聚酰胺中间体与下式的一元醇反应：式中：=“引入”→R 1 -OH 在偶联剂和催化剂的存在下，<？in-line-formula description =“In-line formula”end =“tail”？>以形成产物。

公开(公告)号：US20070123723A1

公开(公告)日：2007-05-31

申请号：US11290207

申请日：2005-11-30

申请人： Peter Odell ,  Eniko Toma ,  Jennifer Belelie

发明人： Peter Odell ,  Eniko Toma ,  Jennifer Belelie

IPC分类号： C07C237/02

CPC分类号： C07C233/34 ,  C07C233/36 ,  C08G69/26 ,  C08G69/28 ,  C09D11/101 ,  C09D11/34

摘要： Disclosed is a compound of the formula wherein R1 is an alkylene, arylene, arylalkylene, or alkylarylene group, R2 and R2′ each independently of the other, are alkylene, arylene, arylalkylene, or alklarylene groups, R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provide that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, or an alkylaryl group.

摘要翻译： 公开了下式的化合物其中R 1是亚烷基，亚芳基，芳基亚烷基或烷基亚芳基，R 2和R 2各自 独立于亚烷基，亚芳基，芳基亚烷基或亚烷基，R 3 3各自独立地为（a）光引发基团，或（b）基团，其为烷基， 芳基，芳烷基或烷基芳基，提供R 3和R 3'中的至少一个是光引发基团，X和X'各自独立地为其它 是氧原子或式-NR 4 - - 的基团，其中R 4是氢原子，烷基，芳基或烷基芳基 。

公开(公告)号：US07153349B2

公开(公告)日：2006-12-26

申请号：US11004451

申请日：2004-12-04

申请人： Rina Carlini ,  Eniko Toma ,  Peter G. Odell ,  Jeffrey H. Banning

发明人： Rina Carlini ,  Eniko Toma ,  Peter G. Odell ,  Jeffrey H. Banning

IPC分类号： C09D11/02 ,  G01D11/00

CPC分类号： C09D11/34 ,  C09D11/101

摘要： Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R′1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 are hydrogen atoms or alkyl groups, R4 and R′4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

公开(公告)号：US20060122416A1

公开(公告)日：2006-06-08

申请号：US11004682

申请日：2004-12-04

申请人： Adela Goredema ,  Rina Carlini ,  Marcel Breton ,  Jeffrey Banning ,  Eniko Toma

发明人： Adela Goredema ,  Rina Carlini ,  Marcel Breton ,  Jeffrey Banning ,  Eniko Toma

IPC分类号： C07C275/26

CPC分类号： C09D11/34 ,  C07C275/26

摘要： Disclosed are trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R′2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R′3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R′4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

摘要翻译： 公开了下式的反式1,2-环己烷双（脲 - 氨基甲酸酯）化合物，其中R 1和R 2各自独立地是亚烷基 基团，亚芳基，芳基亚烷基或烷基亚芳基，R 2和R'2各自独立地是烷基，芳基 ，芳基烷基或烷基芳基，R 3和R'3各自独立地是氢原子或烷基，R 1， 4和R'4各自独立地是氢原子，氟原子，烷基或苯基，n是0,1或2的整数， 2,3或4，并且R 5是烷基，芳基，芳基烷基，烷基芳基或除烷基，芳基，芳基烷基或烷基芳基以外的取代基。

公开(公告)号：US20060122354A1

公开(公告)日：2006-06-08

申请号：US11004761

申请日：2004-12-04

申请人： Rina Carlini ,  Eniko Toma ,  Peter Odell ,  Jeffrey Banning

发明人： Rina Carlini ,  Eniko Toma ,  Peter Odell ,  Jeffrey Banning

IPC分类号： C08G18/00

CPC分类号： C08G18/8166 ,  C08G18/3234 ,  C08G18/8175 ,  C08L75/16 ,  C09D11/34

摘要： Curable trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 each, independently of the other, are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 each, independently of the other, are hydrogen atoms or alkyl groups, R4 and R′4 each, independently of the other, are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.

摘要翻译： 具有下式的可固化的反式-1,2-环己烷双（脲 - 氨基甲酸酯）化合物其中R 1和R 1'各自独立地为亚烷基，亚芳基 ，芳基亚烷基或烷基亚芳基，R 2和R“2各自独立地是烷基，芳基，芳基烷基或烷基芳基，R 3 各自独立地为氢原子或烷基，R 4和R 4各自独立地为氢原子或烷基 独立地是氢原子，氟原子，烷基或苯基，n是0,1,2,3或4的整数，R 5是烷基， 芳基，芳烷基或烷基芳基，或除烷基，芳基，芳基烷基或烷基芳基以外的取代基，条件是R 1，R'1， R 2，R 3，R 3，R'3，R 4， R 5，R 4，或R 5中的一个或多个是烷基，亚烷基，芳基烷基，芳基亚烷基，烷基芳基或烷基 含有烯属不饱和键的化合物，使得化合物在暴露于热和/或光化辐射下可固化。

公开(公告)号：US07501015B2

公开(公告)日：2009-03-10

申请号：US11289620

申请日：2005-11-30

申请人： Peter Gordon Odell ,  Paul F. Smith ,  Jennifer Lynne Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Geoffrey Allen ,  Rina Carlini ,  Christopher A. Wagner

发明人： Peter Gordon Odell ,  Paul F. Smith ,  Jennifer Lynne Belelie ,  Eniko Toma ,  Stephan Drappel ,  C. Geoffrey Allen ,  Rina Carlini ,  Christopher A. Wagner

IPC分类号： C09D11/00

CPC分类号： C09D11/101 ,  C09D11/34

摘要： The phase change ink a viscosity of from about 4 mPa-s to about 50 mPa-s at a first temperature and has a viscosity of from 104 mPa-s to about 109 mPa-s at a second lower temperature. The second temperature may be below the first temperature by at least 10° C. but by no more than 50° C. The first temperature may be from about 60° C. to about 110° C. and the second temperature may be from about 20° C. to about 70° C. A curve of log10 viscosity of the phase change ink plotted against temperature in degrees Celsius may have a slope having an absolute value less than 0.02 at the first temperature and have a slope having an absolute value greater than 0.08 for at least a region second temperatures.

摘要翻译： 相变墨在第一温度下的粘度为约4mPa·s至约50mPa·s，并且在第二较低温度下的粘度为104mPa·s至约109mPa·s。 第二温度可以低于第一温度至少10℃，但不超过50℃。第一温度可以为约60℃至约110℃，第二温度可以为约 20℃至约70℃。相变油墨的log 10粘度与温度相对于摄氏度的曲线可以具有在第一温度下具有小于0.02的绝对值的斜率，并且具有绝对值更大的斜率 至少一个区域第二温度高于0.08。