公开(公告)号：US4900872A

公开(公告)日：1990-02-13

申请号：US361775

申请日：1989-05-26

申请人： Giorgio Guglielmo ,  Gian P. Gamberetto

发明人： Giorgio Guglielmo ,  Gian P. Gamberetto

IPC分类号： C07C41/00 ,  C07C41/06 ,  C07C43/12 ,  C07C67/00

CPC分类号： C07C41/06

摘要： Improved process for the preparation of fluorohalogenated ethers by reaction of a fluorinated fluorooxycompound with a halogenated olefin, performed in liquid phase, in the presence of an inert solvent, at low temperature, the fluoroxycompound being continuously fed in form of solution in an inert solvent.

公开(公告)号：US4816599A

公开(公告)日：1989-03-28

申请号：US93041

申请日：1987-09-04

申请人： Guglielmo Gregorio ,  Pierangelo Calini ,  Giorgio Guglielmo

发明人： Guglielmo Gregorio ,  Pierangelo Calini ,  Giorgio Guglielmo

IPC分类号： B01J23/78 ,  B01J27/00 ,  B01J27/12 ,  C07B61/00 ,  C07C67/00 ,  C07C71/00 ,  C07C201/00 ,  C07C143/70

CPC分类号： C07C71/00 ,  B01J23/78 ,  B01J27/12

摘要： The new compound bromofluoroethylhypofluorite, having the formula CF.sub.2 BrCF.sub.2 OF is obtained by starting from ##STR1## by the reaction in gaseous phase with fluorine, in the presence of a catalyst constituted by CsF on a support constituted by copper (or by another metal) in the form of a porous material having a surface area of at least 0.1 m.sup.2 /g.

摘要翻译： 具有式CF2BrCF2OF的新化合物溴氟乙基二氟氟化物通过在气相中与氟反应，在由CsF在由铜（或另一种金属）构成的载体上形成的催化剂存在下，以形式 的表面积至少为0.1m 2 / g的多孔材料。

公开(公告)号：US4729856A

公开(公告)日：1988-03-08

申请号：US864841

申请日：1986-05-20

申请人： Giorgio Bornengo ,  Filippo M. Carlini ,  Michele Pontevivo ,  Giorgio Guglielmo

发明人： Giorgio Bornengo ,  Filippo M. Carlini ,  Michele Pontevivo ,  Giorgio Guglielmo

IPC分类号： C07C59/135 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/58 ,  C07C67/00

CPC分类号： C07C51/58

摘要： Process for the preparation of 2-perfluoropropoxy-perfluoropropionyl fluoride by dimerization of hexafluoropropene epoxide in aprotic polar medium, in the presence of N,N,N',N'-tetrasubstituted diaminodifluoromethane as catalyst, characterized in that the dimerization reaction is carried out in the presence of a co-catalyst constituted by a nitrogenous organic base having structure of aniline, or of pyridine, or of a derivative thereof, wherein the nitrogen atom is not linked to hydrogen atoms and, in the case of the pyridine-type structure, it is sterically hindered by substituent groups on ortho-position relatively to it.

摘要翻译： 在N，N，N'，N'-四取代二氨基二氟甲烷作催化剂存在下，通过在非质子极性介质中二聚六氟丙烯环氧化物制备2-全氟丙氧基 - 全氟丙酰氟的方法，其特征在于二聚反应 存在由具有苯胺结构的含氮有机碱或吡啶或其衍生物构成的助催化剂，其中氮原子不与氢原子连接，并且在吡啶型结构的情况下， 它相对于邻位的取代基被空间位阻。

公开(公告)号：US5457242A

公开(公告)日：1995-10-10

申请号：US148545

申请日：1993-11-08

申请人： Pierangelo Calini ,  Guglielmo Gregorio ,  Giorgio Guglielmo

发明人： Pierangelo Calini ,  Guglielmo Gregorio ,  Giorgio Guglielmo

IPC分类号： C07C43/12 ,  C07C41/06

CPC分类号： C07C43/123

摘要： A process for preparing the novel compound 2-bromo, 1', 2'-dichloroperfluoro diethyl ether of formula:BrCFhd 2--CF.sub.2 --O--CFCl--CF.sub.2 Clwhere BrCF.sub.2 --CF.sub.2 OF is reacted with the olefin CFCl.dbd.CFCl, with bromohypofluorite being introduced into the reaction mixture in the form of a solution in an inert solvent based on chlorofluorohydrocarbon.

摘要翻译： 制备式BrCF2-CF2-O-CFCl-CF2Cl的新化合物2-溴，1'，2'-二氯全氟二乙醚的方法，其中BrCF 2 -CF 2 OF与烯烃CFCl = CFCl与溴二氟化物反应为 在基于氯氟烃的惰性溶剂中以溶液的形式引入反应混合物。

公开(公告)号：US4827024A

公开(公告)日：1989-05-02

申请号：US837133

申请日：1986-03-07

申请人： Giorgio Guglielmo ,  Lino Conte ,  Filippo M. Carlini

发明人： Giorgio Guglielmo ,  Lino Conte ,  Filippo M. Carlini

IPC分类号： C07C71/00 ,  B01J27/12 ,  C07B61/00 ,  C07C20060101 ,  C07C29/62 ,  C07C31/40 ,  C07C41/22 ,  C07C43/12 ,  C07C67/00 ,  C07C69/63 ,  C07C69/96 ,  C07C201/00

CPC分类号： C07C71/00

摘要： Preparation of fluoroxy-halo-compounds by direct reaction between fluorine and organic compounds having a molecular structure in which at least one oxygen atom is directly bound to a carbon atom in the carbonylic form, in the presence of a fluorination catalyst, in gaseous phase, at an absolute pressure of between 50 and 800 kPa and at a temperature between -5.degree. and +100.degree. C., under conditions of a continuous feeding of the reactants and a continuous removal of the reaction product.

摘要翻译： 通过氟和有机化合物之间的直接反应制备氟氧基卤代化合物，所述有机化合物具有分子结构，其中在氟化催化剂存在下，在气相中至少一个氧原子与羰基形式的碳原子直接结合， 在绝对压力为50-800kPa之间，在-5℃至+ 100℃的温度下，在连续进料反应物和连续除去反应产物的条件下进行。

公开(公告)号：US4801409A

公开(公告)日：1989-01-31

申请号：US93700

申请日：1987-09-08

申请人： Antonio Marraccini ,  Giorgio Guglielmo ,  Alessandro Malacrida ,  Lamberto Roberti

发明人： Antonio Marraccini ,  Giorgio Guglielmo ,  Alessandro Malacrida ,  Lamberto Roberti

IPC分类号： B01J27/12 ,  B01J27/00 ,  C07B61/00 ,  C07C20060101 ,  C07C67/00 ,  C07C71/00 ,  C07C201/00 ,  C07C301/00 ,  C07C303/22 ,  C07C309/78 ,  C07C309/80 ,  C07C309/82 ,  C07C143/70

CPC分类号： C07C71/00 ,  C07C309/00

摘要： Mono- and bis-hypofluorites respectively of formula: FO.sub.2 S--R.sub.f --CF.sub.2 OF and FOCF.sub.2 --R'.sub.f --CF.sub.2 OF wherein R.sub.f is perfluoroalkylene or perfluorochloroalkylene and R'.sub.f is a perfluoroalkylene or perfluorooxyalkylene, and process for preparing them, which is conducted continuously, at a temperature from 0.degree. to 60.degree. C. and comprises starting from the respective acyl fluorides ##STR1## by reaction of fluorine in the gas phase in the presence of a catalyst consisting of K, Rb, Cs or Ba fluoride, preferably supported on a metal material.

摘要翻译： 分子式为：FO2S-Rf-CF2OF和FOCF2-R'f-CF2OF的单 - 和二 - 次氟化物，其中Rf是全氟亚烷基或全氟氯亚烷基，R'f是全氟亚烷基或全氟代亚烷基，以及其连续进行的制备方法， 在0℃至60℃的温度下进行，并且包括由相应的酰基氟化物通过氟在气相中在由K，Rb，Cs或Ba氟化物组成的催化剂存在下反应而优选地载于 一种金属材料。