公开(公告)号：US5840217A

公开(公告)日：1998-11-24

申请号：US417390

申请日：1995-04-05

Applicant: Donald Lupo ,  Josef Salbeck ,  Hermann Schenk ,  Thomas Stehlin ,  Roland Stern ,  Arno Wolf

Inventor： Donald Lupo ,  Josef Salbeck ,  Hermann Schenk ,  Thomas Stehlin ,  Roland Stern ,  Arno Wolf

IPC: C07D307/79 ,  C07C13/72 ,  C07C211/61 ,  C07D213/06 ,  C07D263/32 ,  C07D263/56 ,  C07D271/10 ,  C07D271/107 ,  C07D307/80 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14 ,  G02F1/00 ,  H01B1/00 ,  H01J1/62

CPC classification number: H01L51/0052 ,  C07C13/72 ,  C07D271/107 ,  C07D307/80 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  H01L51/0062 ,  H05B33/14 ,  C07C2103/18 ,  C07C2103/94 ,  H01L2251/308 ,  H01L51/0059 ,  H01L51/0069 ,  H01L51/007 ,  H01L51/0071 ,  H01L51/0073

Abstract: Use of spiro compounds of the formula (I) ##STR1## where K.sup.1 and K.sup.2 are, independently of one another, conjugated systems, in electroluminescence devices. Preferred compounds of the formula (I) are 9,9'-spirobifluorene derivatives of the formula (II) ##STR2## where the benzo groups can be substituted independently of one another. Compounds of the formula (I) have a good solubility in customary organic solvents, improved film-forming properties and a significantly reduced tendency to crystallize. The production of electroluminescence devices is thereby made easier and their service life is increased.

Abstract translation: 在电致发光器件中使用式（I）的化合物（I）其中K1和K2彼此独立地是共轭体系。 优选的式（I）化合物是式（Ⅱ）的9,9'-螺二芴衍生物，其中苯并基可彼此独立地取代。 式（I）化合物在常规有机溶剂中具有良好的溶解性，改善的成膜性能和显着降低的结​​晶倾向。 因此，电致发光器件的制造变得更容易并且其使用寿命增加。

公开(公告)号：US5712361A

公开(公告)日：1998-01-27

申请号：US496202

申请日：1995-06-28

Applicant: Roland Stern ,  Donald Lupo ,  Josef Salbeck ,  Hermann Schenk ,  Thomas Stehlin ,  Klaus Mullen ,  Ullrich Scherf ,  Joachim Huber

Inventor： Roland Stern ,  Donald Lupo ,  Josef Salbeck ,  Hermann Schenk ,  Thomas Stehlin ,  Klaus Mullen ,  Ullrich Scherf ,  Joachim Huber

IPC: C08G61/00 ,  C08G61/02 ,  C09K11/06 ,  H01L51/50 ,  H05B33/14 ,  C08G61/12

CPC classification number: H05B33/14 ,  C08G61/02 ,  C09K11/06 ,  Y10S428/917

Abstract: Conjugated polymers containing ansa substructures and their use as electroluminescence materials. Conjugated polymers containing ansa substructures, which contain aromatic groups and in which adjacent aromatic groups are connected to one another in such a way that one ring atom of one aromatic group is directly linked to one ring atom of the other aromatic group and any further linkages of these two aromatic groups are possible only via a bridge containing at least one tetravalent carbon atom and/or heteroatom. The polymers of the invention having ansa substructures are outstandingly suitable as electroluminescence materials, since they have a very high color purity.

Abstract translation: 含有ansa亚结构的共轭聚合物及其作为电致发光材料的用途。 含有芳族基团的共轭聚合物，其中相邻芳族基团彼此连接，其中一个芳族基团的一个环原子直接与另一个芳族基团的一个环原子连接， 这两个芳族基团仅通过含有至少一个四价碳原子和/或杂原子的桥可能。 具有ansa子结构的本发明的聚合物非常适合作为电致发光材料，因为它们具有非常高的色纯度。