公开(公告)号：US6139958A

公开(公告)日：2000-10-31

申请号：US196819

申请日：1994-02-14

Applicant: Narasimhan Raghupathi ,  Philip L. Schell ,  James C. Watson ,  David T. Melle

Inventor： Narasimhan Raghupathi ,  Philip L. Schell ,  James C. Watson ,  David T. Melle

IPC: C03C25/10 ,  C03C25/26 ,  C03C25/28 ,  C03C25/32 ,  C08J5/08 ,  C08K9/04 ,  C08L31/04 ,  C08L67/00 ,  C08L67/03 ,  C08L77/00 ,  D02G3/00 ,  B32B9/00

CPC classification number: C03C25/323 ,  C03C25/26 ,  C03C25/28 ,  C08J5/08 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/2962 ,  Y10T428/2964

Abstract: Chemically treated glass fibers having good processability are useful in producing fiber reinforced polymeric matrices, wherein the glass fibers have controlled wettability and are not detrimental to the weatherability of the fiber reinforced polymeric matrices. The chemically treated fibers have the dried residue of an aqueous chemical treating composition having a bisphenol A polyester film forming polymer compatible with and soluble in the matrix polymer, poly(vinyl acetate) polymeric film former, acryloxy-containing or methacryloxy-containing organo coupling agent in an effective coupling agent amount, cationic fiberous lubricant in an effective lubricating amount, with or without a cationic organic quaternary ammonium salt having alkoxy moieties, and with water in an amount to give a total solid for the aqueous chemical treating composition in the range of about 1 to about 30 weight percent. In addition, the aqueous chemical treating composition can have one or more amino-containing organofunctional silane coupling agents. The amount of the organic quaternary ammonium agent generally is in the range of from 0.05 to around 0.4 weight percent of the aqueous chemical treating composition. When this agent is not in the aqueous chemical treating composition, a secondary application of an antistatic agent is performed. The chemically treated glass fibers can be produced in any form such as chopped strand or continuous strand for combination with polymeric matrices including both filled and unfilled systems for producing reinforced polymeric matrices such as glass fiber reinforced polymeric panels which can be clear, translucent or pigmented.

Abstract translation: 具有良好加工性能的化学处理玻璃纤维可用于生产纤维增强聚合物基质，其中玻璃纤维具有受控的润湿性，并且不会对纤维增强聚合物基质的耐候性产生不利影响。 化学处理的纤维具有水性化学处理组合物的干燥残余物，其具有与基质聚合物相容并可溶于基质聚合物的双酚A聚酯膜形成聚合物，聚（乙酸乙烯酯）聚合物成膜剂，含丙烯酰氧基或含甲基丙烯酰氧的有机偶联剂 在有效的偶联剂量中，具有有效润滑量的阳离子纤维润滑剂，具有或不具有具有烷氧基部分的阳离子有机季铵盐，以及水的量，其用量为所述水性化学处理组合物的总固体量在 约1至约30重量％。 此外，水性化学处理组合物可以具有一种或多种含氨基的有机官能硅烷偶联剂。 有机季铵化合物的量通常在含水化学处理组合物的0.05至约0.4重量％的范围内。 当该试剂不在水性化学处理组合物中时，进行抗静电剂的二次施用。 化学处理的玻璃纤维可以以任何形式生产，例如短切纤维或连续链，用于与包括填充和未填充体系的聚合物基质组合，用于生产增强的聚合物基质，例如可以是透明，半透明或着色的玻璃纤维增​​强的聚合物面料。

公开(公告)号：US4067265A

公开(公告)日：1978-01-10

申请号：US718181

申请日：1976-08-27

Applicant: James C. Watson

Inventor： James C. Watson

IPC: A47F5/12 ,  B60B33/00 ,  B62B3/00 ,  B62B5/04

CPC classification number: B60B33/0089 ,  A47F5/12 ,  B62B3/006 ,  B62B5/049

Abstract: Display rack having tray supports which tilt from a horizontal transport position to an inclined display position and in which the movement of the racks from the first to the second position actuates a brake to lock the rack in place on the floor.

Abstract translation: 具有从水平运输位置倾斜到倾斜显示位置的托架支架的显示架，其中，架子从第一位置到第二位置的运动致动制动器，以将架子锁定在地板上的适当位置。

公开(公告)号：USD293792S

公开(公告)日：1988-01-19

申请号：US711860

申请日：1985-03-14

Applicant: James C. Watson

Designer： James C. Watson

公开(公告)号：US4487797A

公开(公告)日：1984-12-11

申请号：US557032

申请日：1983-12-01

Applicant: James C. Watson

Inventor： James C. Watson

IPC: C08K9/00 ,  C03C25/10 ,  C03C25/26 ,  C08J5/08 ,  C08L67/00 ,  B32B7/00

CPC classification number: C03C25/26 ,  C08J5/08 ,  Y10T428/2964 ,  Y10T428/31525 ,  Y10T442/2311

Abstract: Chemically treated glass fibers can be produced having improved wet-out and resin demand performance when used for reinforced polymeric matrices which have good strength properties. The treated glass fibers have the dried residue of an aqueous treating composition having a water soluble, dispersible or emulsifiable epoxy novalac type polymer, glass fiber coupling agent, a water soluble, dispersible or emulsifiable poly(oxyalkylene-oxyethylene) polyol copolymer, wherein the ethylene oxide portion is present in an amount in the range of about 10 to about 40 weight percent of the copolymer, and the copolymer is present in an effective lubricating amount, and water in a sufficient amount to allow the aqueous treating composition to be applied to the glass fibers. The epoxy novalac type polymer can be an epoxy novalac polymer or a blend of water soluble, dispersible or emulsifiable epoxy polymer and novalac polymer or a blend of the epoxy novalac polymer and water soluble or dispersible or emulsifiable epoxy polymer or polyvinyl acetate polymer. Also, the aqueous treating composition can have a glass fiber lubricant present in an effective lubricating amount. The treated glass fibers have the dried residue of the aqueous treating composition, wherein the moisture content of the treated glass fibers is in the range of about 1 to about 10 weight percent and the amount of dried residue on the glass fibers is in the range of about 0.1 to about 2 weight percent of the treated glass fiber. The poly(oxyalkylene-oxyethylene) polyol copolymer generally has a molecular weight of greater than around 1500. The treated glass fiber strands are particularly suitable for reinforcing thermosetting polymers like vinyl ester polymeric matrices.

Abstract translation: 当用于具有良好强度性能的增强聚合物基质时，可以制备化学处理的玻璃纤维，其具有改善的浸湿和树脂需求性能。 经处理的玻璃纤维具有水溶性，可分散或可乳化的环氧树脂型聚合物，玻璃纤维偶联剂，水溶性，可分散或可乳化的聚（氧亚烷基 - 氧乙烯）多元醇共聚物的水性处理组合物的干燥残余物，其中乙烯 氧化物部分以共聚物的约10至约40重量％的范围存在，并且共聚物以有效润滑量存在，并且以足够的量存在水，以使水性处理组合物施加到 玻璃纤维。 环氧树脂型聚合物可以是环氧诺瓦克聚合物或水溶性，可分散或可乳化的环氧聚合物和诺瓦克聚合物的混合物或环氧诺瓦克聚合物和水溶性或可分散或可乳化的环氧聚合物或聚乙酸乙烯酯聚合物的共混物。 此外，水性处理组合物可以具有有效润滑量的玻璃纤维润滑剂。 经处理的玻璃纤维具有水处理组合物的干燥残余物，其中经处理的玻璃纤维的水分含量在约1至约10重量％的范围内，玻璃纤维上的干燥残余物的量在 约0.1至约2重量％的经处理的玻璃纤维。 聚（氧化烯 - 氧乙烯）多元醇共聚物通常具有大于约1500的分子量。经处理的玻璃纤维线材特别适用于加强热固性聚合物如乙烯基酯聚合物基质。

公开(公告)号：US4007236A

公开(公告)日：1977-02-08

申请号：US537742

申请日：1974-12-31

Applicant: James J. Duffy ,  Richard D. Carlson ,  James C. Watson

Inventor： James J. Duffy ,  Richard D. Carlson ,  James C. Watson

IPC: C09K21/12 ,  C07F9/24 ,  C07F9/6571 ,  C07F9/6574 ,  C08K5/5399 ,  D06M13/02 ,  D06M13/322 ,  D06M13/44 ,  C07F9/15

CPC classification number: D06M13/44 ,  C07F9/657154 ,  C08K5/5399 ,  Y10T442/268

Abstract: Brominated phosphoramidates of the structure ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from the group consisting of hydrogen, chloro, bromo, and chloro or bromo substituted alkyl of from 1 to 8 carbon atoms;R.sup.3 is selected from the group consisting of hydrogen, alkyl of from 1 to 8 carbon atoms, hydroxy substituted alkyl of from 1 to 8 carbon atoms and chloro or bromo substituted alkyl of from 1 to 8 carbon atoms;R.sup.4 is independently selected from the group consisting of R.sup.3 and a group of the structure ##STR2## wherein R is selected from the group consisting of alkylene of from 2 to 8 carbon atoms; phenylene, biphenylene and dicyclohexylene; provided that at least one of R.sup.1 and R.sup.2 contains a bromine atom and at least one of R.sup.3 and R.sup.4 contains a replaceable hydrogen.The phosphoramidates of the present invention are useful to impart a flame retardant property to combustible materials.