Polyglycidyl compounds containing N-heterocyclic structure

    公开(公告)号:US4052366A

    公开(公告)日:1977-10-04

    申请号:US582041

    申请日:1975-05-29

    CPC分类号: C07D233/72 C08G59/3245

    摘要: The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which (1) n denotes 2, 3 or 4, (2) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, (3) either D denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or D denotes the radical ##STR3## and m denotes O, and (4) R.sup.1 represents a divalent radical, which contains at least one hydantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

    Linear polyesters based on s-triazinedicarboxylic acids
    13.
    发明授权
    Linear polyesters based on s-triazinedicarboxylic acids 失效
    基于s-三嗪二羧酸的线性聚酯

    公开(公告)号:US4034018A

    公开(公告)日:1977-07-05

    申请号:US597609

    申请日:1975-07-21

    申请人: Jurgen Habermeier

    发明人: Jurgen Habermeier

    CPC分类号: C08G63/6856

    摘要: Linear, thermoplastic polyesters formed from certain s-triazinedicarboxylic acids, N-heterocyclic diols, and, if appropriate, alkanediols. The polyesters are thermoplastic materials from which moulded materials having valuable thermo-mechanical properties can be manufactured by the customary shaping processes, such as casting, injection moulding and extrusion. They are suitable for use as engineering plastic materials and for coating objects.

    摘要翻译: 由某些三 - 三嗪二羧酸,N-杂环二醇和适当的烷二醇形成的线性热塑性聚酯。 聚酯是热塑性材料,其中具有有价值的热机械性能的模制材料可以通过常规成型工艺制造,例如铸造,注模和挤出。 它们适合用作工程塑料材料和涂料。

    Polyglycidyl compounds containing hydantoin structure
    14.
    发明授权
    Polyglycidyl compounds containing hydantoin structure 失效
    含有HYDANTOIN结构的聚硅氧烷化合物

    公开(公告)号:US3998837A

    公开(公告)日:1976-12-21

    申请号:US590550

    申请日:1975-06-26

    IPC分类号: C08G59/32 C07D405/14

    CPC分类号: C08G59/3245

    摘要: The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which (1) n denotes 2, 3 or 4, (2) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, (3) either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes O, and (4) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

    Unsaturated linear polyesters
    15.
    发明授权
    Unsaturated linear polyesters 失效
    不饱和线性聚酯

    公开(公告)号:US3997511A

    公开(公告)日:1976-12-14

    申请号:US521128

    申请日:1974-11-05

    CPC分类号: C08G63/6858 Y10S260/24

    摘要: Unsaturated, linear polyesters having flame-retarding properties are obtained by polycondensing unsaturated dicarboxylic acids, optionally mixed with aromatic dicarboxylic acids and aliphatic diols, with brominated and/or chlorinated 1,3-di-(hydroxyalkyl)-benzimidazolone compounds. The new, unsaturated polyesters can be polymerized easily, also when mixed with other polymerizable monomers, and give moulding materials having flame-retarding properties.

    摘要翻译: 通过将任选与芳族二羧酸和脂族二醇混合的不饱和二羧酸与溴化和/或氯化的1,3-二(羟烷基) - 苯并咪唑酮化合物缩聚得到具有阻燃性能的不饱和直链聚酯。 当与其它可聚合单体混合时,新的不饱和聚酯可以容易地聚合,并得到具有阻燃性的成型材料。

    Dicarboxylic acids and dicarboxylic acid esters containing a
benzimidazolone radical
    18.
    发明授权
    Dicarboxylic acids and dicarboxylic acid esters containing a benzimidazolone radical 失效
    含有苯并咪唑酮基团的二羧酸和二羧酸酯

    公开(公告)号:US4161603A

    公开(公告)日:1979-07-17

    申请号:US794694

    申请日:1977-05-06

    申请人: Jurgen Habermeier

    发明人: Jurgen Habermeier

    摘要: Dicarboxylic acids or dicarboxylic acid esters, containing a N,N-heterocyclic radical, of the formula ##STR1## in which the two R.sub.1 independently of one another each denote hydrogen, an alkyl with 1 to 4 C atoms or a phenyl, the two R.sub.2 independently of one another each denote hydrogen or an alkyl with 1 to 10 C atoms, the two n represent identical or different numbers from 2 to 12 and X denotes a divalent monocyclic N,N-heterocyclic radical of benzimidazolone, parabanic acid, 2,2-dimethylimidazolidine-4,5-dione, 6-ethyluracil or barbituric acid are prepared by reacting 1 mol of the corresponding N,N-heterocyclic compounds with 2 mols of a compound of the formula ##STR2## wherein Y.sub.1 denotes a chlorine or bromine atom. The dicarboxylic acid compounds have a high stability to heat and therefore are very suited for the manufacture of polycondensates by the melt condensation process.

    摘要翻译: 含有式(IMAGE)的N,N-杂环基的二羧酸或二羧酸酯,其中两个R 1彼此独立地表示氢,具有1-4个C原子的烷基或苯基,二个R2 彼此独立地表示氢或具有1至10个C原子的烷基,两个n表示2至12个相同或不同的数字,X表示苯并咪唑酮的二价单环N,N-杂环基,对苯乙酸,2,2 - 二甲基咪唑烷-4,5-二酮,6-乙基尿嘧啶或巴比妥酸是通过使1摩尔相应的N,N-杂环化合物与2摩尔下式化合物反应制备的,其中Y1表示氯或溴原子 。 二羧酸化合物对热的稳定性高,因此非常适用于通过熔融缩合方法制备缩聚物。

    Polyglycidyl compounds containing N-heterocyclic structure
    19.
    发明授权
    Polyglycidyl compounds containing N-heterocyclic structure 失效
    含有N-杂环结构的多缩水甘油基化合物

    公开(公告)号:US4007199A

    公开(公告)日:1977-02-08

    申请号:US593916

    申请日:1975-07-07

    IPC分类号: C08G59/32 C07D49/32

    CPC分类号: C08G59/3245

    摘要: The polyglycidyl compounds according to the invention can be manufactured by reacting epihalogenohydrin with compounds of the formula IV ##STR1## or the formula V ##STR2## in which 1.) n denotes 2, 3 or 4, 2.) A represents a 2-valent, 3-valent or 4-valent organic radical which either contains a N-heterocyclic or cycloaliphatic ring or 2 N-heterocyclic rings or 2 phenylene rings, 3.) either B denotes the --CH.sub.2.O.CO-- radical and m denotes the number 1, or B denotes the radical ##STR3## and m denotes 0, and 4.) R.sup.1 represents a divalent radical, which contains at least one hydrantoin ring or uracil ring. During the reaction hydrogen halide splits off. From curable mixtures containing polyglycidyl compounds according to the invention and a curing agent such as hexahydrophthalic anhydride or phthalic anhydride are obtained products with good mechanical and electrical properties.

    摘要翻译: 根据本发明的多缩水甘油化合物可以通过使表卤代醇与式IV(IV)或式V(VI)的化合物反应制备,其中1.)n表示2,3或4,2。 )A表示2-价,3价或4价有机基团,其含有N-杂环或脂环族环或2个N-杂环或2个亚苯基环。3)B表示-CH 2 O. CO-基,m表示数1,或B表示基团,且m表示0和4.)R1表示含有至少一个环氨基环或尿嘧啶环的二价基团。 反应期间卤化氢分解。 由含有本发明的聚缩水甘油基化合物和固化剂如六氢邻苯二甲酸酐或邻苯二甲酸酐的可固化混合物得到具有良好机械和电学性能的产品。

    Linear copolyesters based on terephthalic acid and/or isophthalic acid,
a process for their manufacture and their use
    20.
    发明授权
    Linear copolyesters based on terephthalic acid and/or isophthalic acid, a process for their manufacture and their use 失效
    基于对苯二甲酸和/或间苯二甲酸的线性共聚酯,其制备方法及其用途

    公开(公告)号:US4002600A

    公开(公告)日:1977-01-11

    申请号:US629154

    申请日:1975-11-05

    申请人: Jurgen Habermeier

    发明人: Jurgen Habermeier

    CPC分类号: C08G63/6856 C08G69/44

    摘要: New linear copolyesters containing amide groups are obtained by polycondensing certain dicarboxylic acid diamides which are obtained by reaction of 1 mol of an aromatic, cycloaliphatic or cycloaliphatic-aliphatic diamine with 2 mols of terephthalic acid, isophthalic acid or their polyester-forming derivatives, together with terephthalic acid, isophthalic acid or their polyester-forming derivatives and with alkanediols to a relative viscosity greater than 1.2. The new copolyesters containing amide groups are valuable engineering thermoplastic materials which are easily processible and give moulding materials with good thermo-mechanical properties.

    摘要翻译: 通过将某些二羧酸二酰胺缩合得到,通过将1摩尔芳族,脂环族或脂环族脂肪族二胺与2摩尔对苯二甲酸或间苯二甲酸或其聚酯形成衍生物反应而得到的新的线性共聚酯与 对苯二甲酸,间苯二甲酸或它们的聚酯形成衍生物和链烷二醇,其相对粘度大于1.2。 含有酰胺基团的新型共聚酯是有价值的工程热塑性材料,其易于加工并且具有良好的热机械性能的成型材料。