摘要:
There is provided a hollow-shaped membrane electrode assembly for a fuel cell capable of improving power density per unit volume, wherein the hollow-shaped membrane electrode assembly for a fuel cell comprises a hollow solid electrolyte membrane, an outer electrode layer formed on the outer circumferential surface of the solid electrolyte membrane and an inner electrode layer formed on the inner circumferential surface of the solid electrolyte membrane, and wherein the hollow-shaped membrane electrode assembly for a fuel cell is formed in the shape of a spiral.
摘要:
A substrate 10 that selectively allows hydrogen to permeate therethrough is formed with a catalyst thin layer 20 on a first side 11 thereof and is heated in a furnace tube 110, which functions as a reactor, of a heating furnace 100 while a raw material gas to the catalyst thin layer 20 is fed. Hydrogen produced on the first side 11 of the substrate 10 as a result of the formation of carbon nanotubes 5 is separated from the raw material gas and is allowed to permeate to a second side 12 thereof.
摘要:
The present invention provides a fuel cell which is capable to improve heat exchange efficiency with a plurality of tubular cells. The fuel cell of the present invention comprises: a plurality of tubular cells; heat exchangers arranged at the outside of the tubular cells, wherein at least a part of the outer circumferential surface of said tubular cells and the peripheral surface of said heat exchangers have face contact with each other.
摘要:
Carbon particles having fine particles deposited thereon which can be used as a substitute for the carbon particles having platinum deposited thereon and metallic platinum particles which are presently in general use as, e.g., a catalyst for electrodes in fuel cells. Compared to the conventional carbon particles having platinum deposited thereon, etc., the carbon particles are effective in greatly reducing the amount of platinum to be used. The carbon particles are characterized by comprising carbon particles and, deposited on the surface of the carbon particles, fine particles of a perovskite type composite metal oxide in each of which fine noble-metal particles are present throughout the whole particle. Also provided is a process for producing the carbon particles.The carbon particles having deposited fine particles have a constitution in which fine particles of a perovskite type composite metal oxide each having fine noble-metal particles present throughout the whole perovskite type oxide particle and having a crystallite size of 1-20 nm are deposited on carbon particles. The process for producing such carbon particles having fine particles deposited thereon comprises preparing a solution containing fine perovskite type composite oxide particles and complex ions of a metal for constituting fine noble-metal particles, subsequently repeating the step of impregnating the solution into carbon particles and dried the particles to thereby adsorb complex ions of the metal onto the carbon particles, and then subjecting the resultant particles to heat treatment.
摘要:
A tubular fuel cell module comprising a tubular fuel cell capable of improving current collection efficiency, and a fuel cell comprising the fuel cell module are provided. A fuel cell module (100) includes a plurality of tubular fuel cells (10A, 10A, . . . ) arranged in parallel and a first current collector (35), wherein the tubular fuel cells (10A, 10A, . . . ) are woven by the first current collector (35) in a direction crossing an axial direction of the tubular fuel cells (10A, 10A, . . . ) in a plan view.
摘要:
A cathode catalyst layer (16) includes electron conducting carbon nanotubes (CNTs) (161) having a hollow space formed at an interior. The CNTs (161) are, in a hollow space forming direction thereof, open at a first end and are closed at a second end. The open end (161a) is disposed so as to be in contact with a gas diffusion layer (22). On the other hand, the closed end (161b) is disposed so as to be in contact with a polymer electrolyte membrane (12). Defects are formed on a surface of the CNTs (161). The defects (161c) are formed so as to communicate between an outer surface of the CNTs (161) and the hollow space. Catalyst particles (162) are provided on the outer surface of the CNTs (161), and an ionomer (163) is provided so as to cover the catalyst particles (162).
摘要:
A catalyst for electrodes in solid-polymer fuel cells which comprises metal oxide particles themselves. The catalyst contains fine transition-metal oxide particles having, in the main phase, a perovskite structure represented by the general formula ABO3 (wherein A represents one or more elements selected among lanthanum, strontium, cerium, calcium, yttrium, erbium, praseodymium, neodymium, samarium, europium, silicon, magnesium, barium, niobium, lead, bismuth, and antimony; and B represents one or more elements selected among iron, cobalt, manganese, copper, titanium, chromium, nickel, and molybdenum), the fine oxide particles having lattice constants satisfying the following relationship (1): 1.402
摘要:
A method for manufacturing a tube-type fuel cell by which a tube-type fuel cell with good adhesion can be produced without blocking a gas flow channel in its inner current collector. The method for manufacturing a tube-type fuel cell may include a filling step of providing a columnar-shaped inner current collector having a gas flow channel on its outer peripheral face and filling the gas flow channel with a removable substance to form a removable portion. Also a functional layer forming step of forming a functional layer on at least the removable portion and a removing step of removing the removable portion after the functional layer forming step may be used.
摘要:
The present invention mainly intends to provide a method for manufacturing a tube-type fuel cell by which a tube-type fuel cell with good adhesion can be produced without blocking gas flow channel in its inner current collector. In order to achieve the object, the present invention provides a method for manufacturing a tube-type fuel cell, comprising: a filling step of providing a columnar-shaped inner current collector having a gas flow channel on its outer peripheral face and filling the gas flow channel with a removable substance to form a removable portion; a functional layer forming step of forming a functional layer on at least the removable portion; and a removing step of removing the removable portion after the functional layer forming step.
摘要:
A fuel cell comprising cell module assemblies connected in series, each of which gathers two or more cell modules comprising a hollow electrolyte membrane in which an electrode is disposed on a bore side and a shell side thereof respectively, wherein each cell module assembly comprises: a cell module array in which two or more cell modules are aligned in parallel; a partition which separates a space outside of the cell module between the open end and a body of the cell module; a bore side gas passage and a shell side gas passage provided by the partition; a current collector for positive electrode provided in the vicinity of one end of the cell module in the cell module array so that the current collector for positive electrode integrally collects power from each current collector on the positive electrode side of each cell module; a current collector for negative electrode provided in the vicinity of the other end so that the current collector for negative electrode integrally collects power from each current collector on the negative electrode side of each cell module; and a positive or negative electrode output connected with the current collector for positive or negative electrode and provided on a contacting surface of an adjacent cell module assembly; and wherein cell module assemblies are attached having the current collector of the same pole in the same direction, in which, as for adjacent cell module assemblies, the positive electrode output is arranged on the contacting surface of one cell module assembly and the negative electrode output is arranged on the contacting surface of the other cell module assembly, and the cell module assemblies are connected in series.