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公开(公告)号：US5693866A
公开(公告)日：1997-12-02
申请号：US635247
申请日：1996-04-12
IPC分类号： C07C213/10 , C07C215/08 , C07C209/90
CPC分类号： C07C213/10
摘要： In the thermal processing of crude alkanolamines, a method of inhibiting color formation in the alkanolamines comprising adding an amount, effective for the purpose, of an alkali metal hydroxide or sulfite, or mixtures thereof.
摘要翻译： 在粗链烷醇胺的热加工中，抑制链烷醇胺中颜色形成的方法包括向碱金属氢氧化物或亚硫酸盐或其混合物中加入一定量的，有效的。
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公开(公告)号：US5220104A
公开(公告)日：1993-06-15
申请号：US898976
申请日：1992-06-15
申请人： Cato R. McDaniel , Paul V. Roling
发明人： Cato R. McDaniel , Paul V. Roling
摘要： The present invention is directed to the use of a solution of a percarbonate compound to prevent fouling during the basic washing of hydrocarbons containing oxygenated compounds. More specifically, oxygenated compounds such as carbonyl containing organics have a tendency to polymerize, producing fouling elements when such are contained in hydrocarbons being washed with basic materials. Solutions of percarbonate compounds are quite effective in reducing the fouling tendencies due to these specific mechanisms.
摘要翻译： 本发明涉及过碳酸盐化合物溶液在含有氧化化合物的烃的基本洗涤过程中防止结垢的用途。 更具体地，含羰基的有机物的氧化化合物具有聚合的倾向，当用碱性材料洗涤的烃中含有这些化合物时，产生结垢元素。 过碳酸盐化合物的解决方案对于减少由于这些特定机制导致的结垢倾向是非常有效的。
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公开(公告)号：US5194620A
公开(公告)日：1993-03-16
申请号：US871372
申请日：1992-04-20
IPC分类号： C10G9/16
CPC分类号： C10G9/16
摘要： Phosphorus derivatives of polyalkenylsuccinimides and methods of use of such derivatives as antifoulants in liquid hydrocarbonaceous mediums, such as crude oil, during processing at elevated temperatures are disclosed. The derivatives are formed via reaction of a polyalkenylsuccinimide intermediate with formaldehyde and a phosphorus compound having at least one acidic hydrogen P-H bond. The intermediate is first formed via reaction of polyalkenylsuccinic anhydride and polyamine.
摘要翻译： 公开了聚链烯基琥珀酰亚胺的磷衍生物和在液体烃类介质（如原油）中在高温加工过程中使用这些衍生物作为防污剂的方法。 衍生物通过聚烯基琥珀酰亚胺中间体与甲醛和具有至少一个酸性氢P-H键的磷化合物的反应形成。 中间体首先通过聚烯基琥珀酸酐和多胺的反应形成。
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公开(公告)号：US5100532A
公开(公告)日：1992-03-31
申请号：US622456
申请日：1990-12-05
申请人： Paul V. Roling , John E. Martin
发明人： Paul V. Roling , John E. Martin
摘要： 2'-hydroxy-4' or 5'-alkylacetophenone oximes and 2-hydroxy-4 or 5-alkylbenzaldehyde oximes are used to deactivate iron species contained in hydrocarbon fluids. Left untreated, iron leads to decomposition of the hydrocarbon, resulting in the formation of gummy, polymer masses in the hydrocarbon liquid.
摘要翻译： 2'-羟基-4'或5'-烷基苯乙酮肟和2-羟基-4或5-烷基苯甲醛肟用于使包含在烃流体中的铁物质失活。 未经处理，铁导致烃的分解，导致在烃液体中形成胶状的聚合物质量。
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15.发明授权Enhancement of aromatic amine inhibition of acrylate monomer polymerization by addition of mannich products 失效通过加入甘露醇产物增强芳香胺抑制丙烯酸酯单体聚合
公开(公告)号：US4912247A
公开(公告)日：1990-03-27
申请号：US299484
申请日：1989-01-19
申请人： Paul V. Roling
发明人： Paul V. Roling
IPC分类号： C07C67/62 , C07C253/32
CPC分类号： C07C253/32 , C07C67/62
摘要： A composition and method of use for inhibiting the polymerization of acrylate esters during elevated temperature processing and during storage and handling thereafter.It comprises the combination of a Mannich reaction product, which is prepared from a substituted phenol, an aldehyde and ethylenediamine, and either phenylenediamine or derivatives thereof and/or phenothiazine or derivatives thereof.
摘要翻译： 用于抑制丙烯酸酯在高温处理期间以及之后的储存和处理期间聚合的组合物和方法。 它包括由取代的酚，醛和乙二胺以及苯二胺或其衍生物和/或吩噻嗪或其衍生物制备的曼尼希反应产物的组合。
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公开(公告)号：US4435518A
公开(公告)日：1984-03-06
申请号：US444287
申请日：1982-11-24
CPC分类号： C08F10/00 , Y10S526/901
摘要： Catalyst compositions which are particularly useful for the preparation of ethylene polymers having a narrow molecular weight distribution are obtained by (1) drying an inorganic oxide having surface hydroxyl groups, e.g., silica, alumina, magnesia, etc., to remove adsorbed water, (2) reacting the surface hydroxyl groups with at least a stoichiometric amount of an organometallic compound having at least one alkyl group attached to a Group III metal, e.g., a trialkylaluminum, (3) reacting the thus-treated inorganic oxide with a vanadium halide, such as (a) VOCl.sub.3, VOBr.sub.3, and/or mono-, di-, and/or trihydrocarbyloxy derivatives thereof and/or (b) VCl.sub.4, VBr.sub.4, and/or mono-, di-, tri-, and/or tetrahydrocarbyloxy derivatives thereof, and (4) reacting that reaction product with at least about 0.1 mol, per mol of organometallic compound, of an alcohol containing 1 to 18 carbon atoms.
摘要翻译： 特别可用于制备具有窄分子量分布的乙烯聚合物的催化剂组合物通过以下方法获得：（1）干燥具有表面羟基的无机氧化物，例如二氧化硅，氧化铝，氧化镁等，以去除吸附的水（ 2）使表面羟基与至少一种化学计量量的具有至少一个与III族金属连接的烷基的有机金属化合物反应，例如三烷基铝，（3）使经过处理的无机氧化物与卤化钒反应， 例如（a）VOCl 3，VOBr 3和/或其单 - ，二 - 和/或三氢氧羰基衍生物和/或（b）VCl4，VBr4和/或单 - ，二 - ，三 - 和/ 其衍生物，和（4）使该反应产物与每摩尔有机金属化合物至少约0.1摩尔含有1至18个碳原子的醇反应。
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公开(公告)号：US06328943B1
公开(公告)日：2001-12-11
申请号：US09112882
申请日：1998-07-09
申请人： Paul V. Roling , Wiley L. Parker , Alan E. Goliaszewski , Timothy S. Williams , Bernard C. Groce , Quincy K. A. Sintim
发明人： Paul V. Roling , Wiley L. Parker , Alan E. Goliaszewski , Timothy S. Williams , Bernard C. Groce , Quincy K. A. Sintim
IPC分类号： C01B1716
CPC分类号： C01G49/12
摘要： Methods for inhibiting pyrophoric iron sulfide activity are disclosed. Methods are disclosed for inhibiting the sulfidation of iron oxides to iron sulfides and/or the oxidation of iron sulfide to inhibit pyrophoric activity. The methods comprise contacting iron oxides and/or iron sulfide with a liquid, solution, aerosol, or gaseous inhibitor comprising alkylamines, arylamines, imines; oxygen-containing compounds such as alcohols, aldehydes, esters, acids and ketones; mixed nitrogen-containing and oxygen-containing compounds such as alkanolamines, non-polymeric amides, hydroxylamines, Mannich products, polyisobutylenesuccinimides, oximes; sulfur-containing compounds and phosphorus-containing compounds.
摘要翻译： 公开了抑制自发性硫化铁活性的方法。 公开了用于抑制铁氧化物硫化成铁硫化物和/或硫化铁的氧化以抑制发火活性的方法。 所述方法包括使铁氧化物和/或硫化铁与包含烷基胺，芳基胺，亚胺的液体，溶液，气溶胶或气体抑制剂接触; 含氧化合物如醇，醛，酯，酸和酮; 混合的含氮和含氧化合物如烷醇胺，非聚合酰胺，羟胺，曼尼希产品，聚异丁烯琥珀酰亚胺，肟; 含硫化合物和含磷化合物。
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公开(公告)号：US5391781A
公开(公告)日：1995-02-21
申请号：US137646
申请日：1993-10-15
IPC分类号： C01B17/02 , C07C381/00
CPC分类号： C01B17/0248 , Y10S516/01 , Y10S516/02 , Y10S516/06
摘要： Disclosed are methods for dispersing sulfur in aqueous systems comprising adding an alkylcarboxylic acid compound to the system. This prevents fouling of the aqueous system by the precipitated sulfur.
摘要翻译： 公开了在含水体系中分散硫的方法，包括向体系中加入烷基羧酸化合物。 这样可以防止沉淀的硫污染水性体系。
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公开(公告)号：US5221764A
公开(公告)日：1993-06-22
申请号：US837519
申请日：1992-02-18
申请人： Paul V. Roling
发明人： Paul V. Roling
IPC分类号： C07C67/62
CPC分类号： C07C67/62
摘要： Methods and compositions are provided for inhibiting the polymerization of acrylic acid monomers during elevated temperature processing thereof or during storage or shipment of acrylic acid product. The compositions comprise a combination of a cerium source compound and an aromatic amine compound. The methods comprise adding from about 1 to about 10,000 parts per million to the particular acrylic acid containing medium for which such polymerization inhibition is desired, per million parts of the acrylic acid medium.
摘要翻译： 提供了用于在高温处理过程中或在丙烯酸产品的储存或运输过程中抑制丙烯酸单体聚合的方法和组合物。 组合物包含铈源化合物和芳族胺化合物的组合。 该方法包括每百万份丙烯酸介质中加入约1至约10,000份/百万份至需要这种聚合抑制的特定含丙烯酸的培养基。
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20.发明授权Phosphorus derivatives of polyalkenylsuccinimides and methods of use thereof 失效聚链烯基琥珀酰亚胺的磷衍生物及其使用方法
公开(公告)号：US5139643A
公开(公告)日：1992-08-18
申请号：US668548
申请日：1991-03-13
IPC分类号： C10G9/16
CPC分类号： C10G9/16 , Y10S585/95
摘要： Phosphorus derivatives of polyalkenylsuccinimides and methods of use of such derivatives as antifoulants in liquid hydrocarbonaceous mediums, such as crude oil, during processing at elevated temperatures are disclosed. The derivatives are formed via reaction of a polyalkenylsuccinimide intermediate with formaldehyde and a phosphorus compound having at least one acidic hydrogen P--H bond. The intermediate is first formed via reaction of polyalkenylsuccinic anhydride and polyamine.
摘要翻译： 公开了聚链烯基琥珀酰亚胺的磷衍生物和在液体烃类介质（如原油）中在高温加工过程中使用这些衍生物作为防污剂的方法。 衍生物通过聚烯基琥珀酰亚胺中间体与甲醛和具有至少一个酸性氢P-H键的磷化合物的反应形成。 中间体首先通过聚烯基琥珀酸酐和多胺的反应形成。
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