公开(公告)号：US20190218339A1

公开(公告)日：2019-07-18

申请号：US16282406

申请日：2019-02-22

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Motoshi AOYAMA ,  Kiyotaka TAKAO

IPC: C08G65/336 ,  C09D171/02 ,  C09D5/00

CPC classification number: C08G65/336 ,  C08G65/337 ,  C08G2150/00 ,  C09D5/00 ,  C09D171/02

Abstract: Processes for producing a fluorinated ether compound are provided by which fluorinated ether compound capable of imparting excellent water/oil repellency, to a substrate surface or a hard coat layer can be easily produced in high yield. A process comprising reacting Rf(CF2)a—CF2OC(═O)Rf4 or Rf(CF2)a—C(═O)X1 with HN(—R1CH═CH2)2 to obtain Rf(CF2)a—C(═O)N(—R1CH2═CH2)2 and a process comprising obtaining the above product and reacting the product with HSiR2nL3-n to obtain Rf(CF2)a—C(═O)N(—R1CH2CH2SiR2nL3-n)2 wherein Rf is a linear polyfluoroalkyl group having at least two carbon atoms and at least one etheric oxygen atom between carbon atoms, Rf4 is a C1-30 perfluoroalkyl group or the like, X1 is a halogen atom, R1 is an alkylene group, a is an integer of from 1 to 5, R2 is a monovalent hydrocarbon group, L is a hydrolyzable group, and n is an integer of from 0 to 2.

公开(公告)号：US20200165273A1

公开(公告)日：2020-05-28

申请号：US16776559

申请日：2020-01-30

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Eisuke MUROTANI ,  Keigo MATSUURA ,  Makoto UNO

IPC: C07F7/08 ,  C09D183/12 ,  C09D5/00 ,  C10M107/50

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer, and a method for producing it.A fluorinated ether compound represented by A-O—(Rf1O)m—Rf2—SO2N(R1)(R2), wherein A is a C1-20 perfluoroalkyl group, Rf1 is a fluoroalkylene group, m is an integer of from 2 to 500, Rf2 is a fluoroalkylene group, R1 is a monovalent organic group having at least one hydrolyzable silyl group, R2 is a hydrogen atom, a monovalent organic group or a monovalent organic group having at least one hydrolyzable group, and the total number of the hydrolyzable silyl group(s) in R1 and the hydrolyzable group(s) in R2 is at least 2.

公开(公告)号：US20210403402A1

公开(公告)日：2021-12-30

申请号：US17469008

申请日：2021-09-08

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Makoto UNO ,  Masahiro ITO

IPC: C07C43/12 ,  C09D7/63 ,  C09D5/00

Abstract: To provide a fluorinated ether compound capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance; a fluorinated ether composition and a coating liquid containing the fluorinated ether compound; an article having a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance and a method for producing it. A fluorinated ether compound having a poly(oxyperfluoroalkylene) chain having a unit (a) which is an oxyperfluoroalkylene unit having 5 or 6 carbon atoms, and a unit (P) which is an oxyperfluoroalkylene unit having at most 4 carbon atoms, and having at least one of a hydrolysable silyl group and a silanol group on at least one terminal of the poly(oxyperfluoroalkylene) chain via a linking group.

公开(公告)号：US20210095160A1

公开(公告)日：2021-04-01

申请号：US17118665

申请日：2020-12-11

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Kiyotaka TAKAO ,  Kazue TODA ,  Kenji ISHIZEKI ,  Akira ISOBE

IPC: C09D201/04 ,  C09D171/00 ,  C09D201/10 ,  C08G65/329 ,  C08G65/336 ,  B32B33/00 ,  C08F259/08 ,  C08G65/00 ,  C07F7/18

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US20200165385A1

公开(公告)日：2020-05-28

申请号：US16776609

申请日：2020-01-30

Applicant: AGC Inc

Inventor： Makoto UNO ,  Hiromasa YAMAMOTO ,  Taiki HOSHINO ,  Keigo MATSUURA ,  Eiichiro ANRAKU

IPC: C08G65/00 ,  C09D171/02 ,  C08G65/336 ,  B05D1/18 ,  B05D1/00 ,  B05D5/08

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance, light resistance and chemical resistance, an article having a surface layer and a method for producing it.A fluorinated ether compound represented by A-O—(Rf1O)m-Q1(R1)b, wherein A is a C1-20 perfluoroalkyl group, Rf1 is a perfluoroalkylene group, m is an integer of from 2 to 500, (Rf1O)m may consist of two or more types of Rf1O differing in the number of carbon atoms, Q1 is a (b+1) valent perfluorohydrocarbon group which may have a hydroxy group, R1 is a monovalent organic group having at least one hydrolyzable silyl group, b is an integer of at least 2, and the b R1 may be the same or different.

公开(公告)号：US20200115589A1

公开(公告)日：2020-04-16

申请号：US16715155

申请日：2019-12-16

Applicant: AGC Inc.

Inventor： Taiki HOSHINO ,  Kiyotaka TAKAO ,  Kazue TODA ,  Kenji ISHIZEKI ,  Akira ISOBE

IPC: C09D201/04 ,  C09D201/10 ,  C08F259/08 ,  B32B33/00 ,  C09D171/00 ,  C07F7/18 ,  C08G65/329 ,  C08G65/00 ,  C08G65/336

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1—O—(Rf1O)m1-Q1[C(O)N(R1)]p1—R11C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; ml is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.