公开(公告)号：US06693124B1

公开(公告)日：2004-02-17

申请号：US09445313

申请日：1999-12-06

申请人： Wassilios Grammenos ,  Herbert Bayer ,  Thomas Grote ,  Hubert Sauter ,  Andreas Gypser ,  Reinhard Kirstgen ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Volker Harries

发明人： Wassilios Grammenos ,  Herbert Bayer ,  Thomas Grote ,  Hubert Sauter ,  Andreas Gypser ,  Reinhard Kirstgen ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Volker Harries

IPC分类号： A01N4380

CPC分类号： A01N43/653 ,  A01N43/80 ,  C07D249/12 ,  C07D261/12

摘要： Bisimino-substituted phenyl compounds of the formula I where the substituents have the following meanings: X is a group A or B  where # denotes the bond with the phenyl ring and Ra is halogen, alkyl or alkoxy; Y is halogen, alkyl, haloalkyl or alkoxy; n is 0, 1 or 2, it being possible for the radicals Y to be different if n=2; R1 is alkyl; R2 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl; R3 is hydrogen, alkyl, haloalkyl or substituted or unsubstituted phenyl; R4 is ═CRbRc or ═N—ORd where Rb, Rc independently of one another are hydrogen, alkyl or substituted or unsubstituted phenyl; and Rd is one of the radicals mentioned under R2. Processes and intermediates for their preparation, and their use.

摘要翻译： 式I的双亚胺取代的苯基化合物，其中取代基具有以下含义：X为A或B，其中＃表示与苯环的键，R 5为卤素，烷基或烷氧基; Y为卤素，烷基，卤代烷基或 烷氧基; n为0,1或2，如果n = 2，则基团Y可能不同; R 1是烷基; R 2是烷基，卤代烷基，烯基，卤代烯基，炔基或卤代炔基; R 3是氢，烷基，卤代烷基或取代或未取代的苯基; R 4是= CR R c或= N-OR d，其中R c，R c彼此独立地 是氢，烷基或取代或未取代的苯基; 和R 是R 2所提及的基团之一。它们的制备方法和中间体及其用途。

公开(公告)号：US06372766B1

公开(公告)日：2002-04-16

申请号：US09529806

申请日：2000-04-20

申请人： Wassilios Grammenos ,  Klaus Oberdorf ,  Hubert Sauter ,  Andreas Gypser ,  Herbert Bayer ,  Markus Gewehr ,  Thomas Grote ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gerhard Hamprecht ,  Norbert Götz ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann

发明人： Wassilios Grammenos ,  Klaus Oberdorf ,  Hubert Sauter ,  Andreas Gypser ,  Herbert Bayer ,  Markus Gewehr ,  Thomas Grote ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gerhard Hamprecht ,  Norbert Götz ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann

IPC分类号： A01N4340

CPC分类号： C07D213/64 ,  A01N43/40

摘要： Substituted 2-(2′-pyridyloxy)phenylacetamides I, where R1 is fluorine, chlorine, CH3 or halomethyl; R2 is fluorine, bromine, alkyl or halomethyl; R3 is hydrogen or one of the radicals mentioned under R2; and R2 is 6-chloro if R3 is hydrogen, R3 is 5-chloro if R2 is fluorine and the compound in which R1, R2 and R3 are each chlorine with the proviso that R1 may not be chlorine if R2 is 5-trifluoromethyl and R3 is hydrogen, and processes for their preparation and their use for controlling harmful fungi and animal pests are described.

摘要翻译： 取代的2-（2'-吡啶基氧基）苯基乙酰胺I，其中R 1是氟，氯，CH 3或卤代甲基; R 2是氟，溴，烷基或卤代甲基; R 3是氢或在R 2下提及的一个基团; 如果R 3为氢，R 2为6-氯，如果R 2为氟，则R 3为5-氯，并且其中R 1，R 2和R 3各自为氯的化合物，条件是如果R 2为5-三氟甲基并且R 3为氢，则R 1可不为氯， 并描述了其制备方法及其用于控制​​有害真菌和动物害虫的用途。

公开(公告)号：US06537989B1

公开(公告)日：2003-03-25

申请号：US09806608

申请日：2001-04-02

申请人： Markus Gewehr ,  Wassilios Grammenos ,  Hubert Sauter ,  Herbert Bayer ,  Andreas Gypser ,  Bernd Müller ,  Arne Ptock ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  Volker Harries

发明人： Markus Gewehr ,  Wassilios Grammenos ,  Hubert Sauter ,  Herbert Bayer ,  Andreas Gypser ,  Bernd Müller ,  Arne Ptock ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  Volker Harries

IPC分类号： A61K3155

CPC分类号： C07D273/00 ,  A01N43/88

摘要： The present invention relates to azadioxacycloalkenes of the formula I in which the substituents R1 to R5 and X, the index n and the bridge member W have the following meanings: R1 is C1-C4-alkyl, halogen, C1-C4-haloalkyl, C3-C6-cycloalkyl; R2 is C1-C4-alkyl, C1-C4-haloalkyl, C3-C4-alkenyl, C3-C4-haloalkenyl, C3-C4-alkynyl or C3-C4-haloalkynyl; R3 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl or unsubstituted or substituted phenyl; R4 is ═CRaRb, —CRd═CRaRb or ═N—ORc, where Ra, Rb, Rc and Rd are each as defined in claim 1; R5 is nitro, cyano, halogen, C1-C6-alkyl or, in the case that n is 2, additionally a bridge which is attached to two adjacent ring atoms; n is 0, 1, 2, 3 or 4, where the substituents R1 may be different if n is greater than 1; X is C1-C4-alkoxy-N═, C1-C4-alkoxy-CH═ or R6—CH═, where R6 is as defined in claim 1 W is unsubstituted or substituted C1-C3-alkylene.

摘要翻译： 本发明涉及取代基R1至R5和X，指数n和桥连构件W具有以下含义的式Iin的二恶唑环烯烃：R1为C1-C4烷基，卤素，C1-C4卤代烷基，C3- C6-环烷基; R2是C1-C4-烷基，C1-C4卤代烷基，C3-C4-烯基，C3-C4-卤代烯基，C3-C4-炔基或C3-C4-卤代炔基; R3是氢，C1-C4- 烷基，C1-C4卤代烷基或未取代或取代的苯基; R4是= CRaRb，-CRd = CRaRb或= N-ORc，其中Ra，Rb，Rc和Rd分别如权利要求1中所定义; R5是硝基，氰基， 卤素，C 1 -C 6 - 烷基，或在n为2的情况下，另外是连接到两个相邻环原子上的桥; n为0,1,2,3或4，其中如果n 大于1; X为C 1 -C 4 - 烷氧基-N =，C 1 -C 4 - 烷氧基-CH =或R 6 -CH =，其中R 6如权利要求1W中所定义，为未取代或取代的C 1 -C 3 - 亚烷基。

公开(公告)号：US06232317B1

公开(公告)日：2001-05-15

申请号：US09463435

申请日：2000-01-27

申请人： Wassilios Grammenos ,  Herbert Bayer ,  Hubert Sauter ,  Thomas Grote ,  Andreas Gypser ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Norbert Götz ,  Eberhard Ammermann ,  Volker Harries ,  Gisela Lorenz ,  Siegfried Strathmann

发明人： Wassilios Grammenos ,  Herbert Bayer ,  Hubert Sauter ,  Thomas Grote ,  Andreas Gypser ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Norbert Götz ,  Eberhard Ammermann ,  Volker Harries ,  Gisela Lorenz ,  Siegfried Strathmann

IPC分类号： A01N43653

CPC分类号： A01N43/80 ,  A01N43/653 ,  C07D249/12

摘要： Imino-substituted phenyl compounds of the formula I where the substituents have the following meanings: z is a group A or B  where  # denotes the bond with the phenyl ring and  Ra is halogen, alkyl or alkoxy; y is halogen, alkyl, haloalkyl or alkoxy; n is 0, 1 or 2, it being possible for the radicals Y to be different if n=2; R1 is halogen, haloalkyl or alkoxy; R2 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl; R3 is cyano, alkyl, haloalkyl, alkoxy, cycloalkoxy, alkoxyalkyl;  unsubstituted or substituted cycloalkyl, aryl, aryloxy or arylmethylene, heteroaryl, heterocyclyl,  C(R3a)═N—OR3b or C(R3a)═CR3cR3d, where R3a, R3b, R3c, R3d independently of one another are hydrogen, alkyl or unsubstituted or substituted phenyl, processes for their preparation, and their use.

摘要翻译： 取代基具有以下含义：Z是A或B基团，其中＃表示与苯环的键，Ra是卤素，烷基或烷氧基; y是卤素，烷基，卤代烷基或烷氧基 n为0,1或2，如果n = 2，则基团Y可能不同; R1为卤素，卤代烷基或烷氧基; R2为烷基，卤代烷基，烯基，卤代烯基，炔基或卤代炔基; R3为氰基， 烷基，卤代烷基，烷氧基，环烷氧基，烷氧基烷基; 未取代或取代的环烷基，芳基，芳氧基或芳基亚甲基，杂芳基，杂环基，C（R3a）= N-OR3b或C（R3a）= CR3cR3d，其中R3a，R3b，R3c，R3d彼此独立地为氢，烷基或未取代或取代的 苯基，其制备方法及其用途。

公开(公告)号：US06469195B1

公开(公告)日：2002-10-22

申请号：US09830365

申请日：2001-04-25

申请人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Oliver Cullmann ,  Markus Gewehr ,  Bernd Müller ,  Arne Ptock ,  Norbert Götz ,  Roland Götz ,  Thorsten Volk ,  Eberhard Ammermann ,  Thomas Grote ,  Gisela Lorenz ,  Siegfried Strathmann

发明人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Oliver Cullmann ,  Markus Gewehr ,  Bernd Müller ,  Arne Ptock ,  Norbert Götz ,  Roland Götz ,  Thorsten Volk ,  Eberhard Ammermann ,  Thomas Grote ,  Gisela Lorenz ,  Siegfried Strathmann

IPC分类号： C07C22900

CPC分类号： C07C251/48 ,  C07C69/738

摘要： 2-Phenoxyphenylacetic acid derivatives of the formula I where the substituents and the index have the following meanings: A is  where R1 is halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C4-haloalkoxy, formyl, C(═O)NRaRb or C(Ra)═NORb; Ra is hydrogen or C1-C4-alkyl; Rb is C1-C4-alkyl; n is 1, 2, 3 or 4, where the groups R1 may be different if n is not 1; R2 is halogen, CH3 or CF3; m is 0 or 1; and X is OCH3 or NHCH3; processes and intermediates for preparing the compounds I and the use of the compounds I for controlling harmful fungi are described.

摘要翻译： 式I的2-苯氧基苯基乙酸衍生物，其中取代基和指数具有以下含义：A是其中R 1是卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，CF 3，C 1 -C 4 - 卤代烷氧基，甲酰基，C（= O）NR a R b或C（R a）= NOR b; R a是氢或C 1 -C 4烷基; R b是C 1 -C 4 - 烷基; n是1,2,3或4，其中如果n不是 1; R2是卤素，CH3或CF3; m是0或1; 和X是OCH 3或NHCH 3;描述了制备化合物I的方法和中间体以及用于控制有害真菌的化合物I的用途。

公开(公告)号：US06255352B1

公开(公告)日：2001-07-03

申请号：US09423860

申请日：1999-11-17

申请人： Wassilios Grammenos ,  Ruth Müller ,  Hubert Sauter ,  Herbert Bayer ,  Thomas Grote ,  Andreas Gypser ,  Reinhard Kirstgen ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann

发明人： Wassilios Grammenos ,  Ruth Müller ,  Hubert Sauter ,  Herbert Bayer ,  Thomas Grote ,  Andreas Gypser ,  Reinhard Kirstgen ,  Bernd Müller ,  Arne Ptock ,  Franz Röhl ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann

IPC分类号： A01N3324

CPC分类号： A01N35/10

摘要： A method for control of harmful fungi is provided by treating the fungi, or the materials, plants, the soil or seeds to be protected against fungal infection, with an effective amount of a bisoxime of the formula I or a salt or adduct thereof, the index and the substituents having the following meanings: R1 is halogen, alkyl or haloalkyl; R2 is cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino, alkylaminocarbonyl, substituted or unsubstituted phenyl, phenoxy or phenylthio; n is 0, 1, 2 or 3; R3 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl or phenylalkyl.

摘要翻译： 通过用有效量的式I的二肟或其盐或其加合物处理真菌或材料，植物，待保护的土壤或种子免受真菌感染，提供有害真菌的控制方法，指数 并且具有以下含义的取代基：R 1是卤素，烷基或卤代烷基; R 2是氰基，硝基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基氨基，二烷基氨基，烷基氨基羰基，取代或未取代的苯基，苯氧基或苯硫基; n 为0,1,2或3; R3为烷基，卤代烷基，烯基，卤代烯基，炔基，卤代炔基或苯基烷基。

公开(公告)号：US06562833B1

公开(公告)日：2003-05-13

申请号：US09701859

申请日：2000-12-05

申请人： Bernd Müller ,  Hubert Sauter ,  Herbert Bayer ,  Oliver Cullmann ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Arne Ptock ,  Norbert Götz ,  Thomas Grote ,  Michael Rack ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  John-Bryan Speakman

发明人： Bernd Müller ,  Hubert Sauter ,  Herbert Bayer ,  Oliver Cullmann ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Arne Ptock ,  Norbert Götz ,  Thomas Grote ,  Michael Rack ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  John-Bryan Speakman

IPC分类号： C07D23942

CPC分类号： C07D239/42 ,  A01N43/54

摘要： 2-(N-phenylamino)pyrimidines of the formula I, where: R1, R3 independently of one another are cyano, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or are C3-C8-cycloalkyl or a group C(═NORx)Ry R2 is halogen, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or R1 and R2 together with the two linking carbon atoms form a fused-on partially unsaturated 4- to 8-membered ring which may be up to trisubstituted by identical or different substituents selected from the group consisting of C1-C4-alkyl, halogen and C1-C4-alkoxy-carbonyl, which may contain a carbonyl group and/or, in addition to the multiple bond of the pyrimidine ring, a double bond and/or which may be interrupted by O, S or N—(C1-C4-alkyl); the substituents R4 to R8, Rx, Ry, Ra and Rb are as defined in the description; are used as fungicides.

摘要翻译： 式I的2-（N-苯基氨基）嘧啶，其中：R 1，R 3彼此独立地是氰基，C 1 -C 8 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，其中基团烷基，烯基和 炔基可以被氰基，卤素，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基羰基取代，或者是C 3 -C 8 - 环烷基或C（= NOR x）R 1 R 2是卤素，C 1 -C 8烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，其中基团烷基，烯基和炔基可以被氰基，卤素，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基羰基取代，或者R 1和R 2与两个连接碳原子一起形成稠合 - 部分不饱和的4-至8-元环，其可以由可以含有羰基的C 1 -C 4 - 烷基，卤素和C 1 -C 4 - 烷氧基 - 羰基的相同或不同取代基取代三取代， /或除了嘧啶环的多重键之外，可以被O，S或N-（C 1 -C 4 - 烷基）中断的双键和/或被中间的取代基取代基R4至R8，Rx，Ry，Ra 和Rb如t所定义 他的描述;被用作杀真菌剂。

公开(公告)号：US06228810B1

公开(公告)日：2001-05-08

申请号：US09254920

申请日：1999-03-17

申请人： Franz Röhl ,  Volker Harries ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  Arne Ptock ,  Hubert Sauter ,  Wassilios Grammenos ,  Thomas Grote ,  Herbert Bayer ,  Reinhard Kirstgen ,  Klaus Oberdorf ,  Bernd Müller ,  Ruth Müller

发明人： Franz Röhl ,  Volker Harries ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  Arne Ptock ,  Hubert Sauter ,  Wassilios Grammenos ,  Thomas Grote ,  Herbert Bayer ,  Reinhard Kirstgen ,  Klaus Oberdorf ,  Bernd Müller ,  Ruth Müller

IPC分类号： A01N4340

CPC分类号： C07D213/64 ,  A01N43/40 ,  C07D213/65 ,  C07D213/68

摘要： Pyridine derivatives of the formula I and their salts, their preparation, and their use for controlling animal pests and harmful fungi.

摘要翻译： 式I的吡啶衍生物及其盐，其制备方法及其用于控制​​动物害虫和有害真菌的用途。

公开(公告)号：US06211190B1

公开(公告)日：2001-04-03

申请号：US09117707

申请日：1998-08-04

申请人： Wassilios Grammenos ,  Herbert Bayer ,  Thomas Grote ,  Reinhard Kirstgen ,  Bernd Müller ,  Ruth Müller ,  Klaus Oberdorf ,  Arne Ptock ,  Hubert Sauter ,  Franz Röhl ,  Michael Rack ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Volker Harries

发明人： Wassilios Grammenos ,  Herbert Bayer ,  Thomas Grote ,  Reinhard Kirstgen ,  Bernd Müller ,  Ruth Müller ,  Klaus Oberdorf ,  Arne Ptock ,  Hubert Sauter ,  Franz Röhl ,  Michael Rack ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Volker Harries

IPC分类号： A01N4354

CPC分类号： C07D239/47 ,  A01N43/54 ,  C07D239/34

摘要： Pyrimidine compounds I wherein X is C(CO2CH3)═NOCH3, C(CONHCH3)═NOCH3, C(CO2CH3)═CHOCH3, C(CO2CH3)═CHCH3 or N(CO2CH3)—OCH3; R1, R2 are hydrogen, alkyl, haloalkyl or alkoxy; A is R3 is hydrogen, alkyl, haloalkyl, phenoxyalkyl, cycloalkyl, cyano, alkoxy, hydroxyl or halogen; R4 is hydrogen, optionally substituted alkyl, alkenyl, alkynyl, haloalkenyl, haloalkynyl, cycloalkyl or alkoxy; Y is hydrogen, hydroxyl, halogen, optionally substituted aryl, hetaryl, cycloalkyl, cycloalkenyl, heterocyclyl, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, aryloxy, arylthio, hetaryloxy, hetarylthio, cycloalkyloxy or alkylthio, or their salt, their synthesis and intermediates therefore, and their activity against fungi or animal pests.

摘要翻译： 嘧啶化合物I，其中X是C（CO 2 CH 3）= NOCH 3，C（CONHCH 3）= NOCH 3，C（CO 2 CH 3）= CHOCH 3，C（CO 2 CH 3）= CHCH 3或N（CO 2 CH 3）-OCH 3; R 1，R 2是氢，烷基，卤代烷基或烷氧基 烷基，卤代烷基，苯氧基烷基，环烷基，氰基，烷氧基，羟基或卤素; R4是氢，任选取代的烷基，烯基，炔基，卤代烯基，卤代炔基，环烷基或烷氧基; Y是氢，羟基，卤素， 任选取代的芳基，杂芳基，环烷基，环烯基，杂环基，烷基，烯基，炔基，卤代烷基，烷氧基，芳氧基，芳硫基，杂芳氧基，杂芳硫基，环烷氧基或烷硫基或它们的盐，因此它们的合成和中间体及其对真菌或 动物害虫

公开(公告)号：US06482984B2

公开(公告)日：2002-11-19

申请号：US09760710

申请日：2001-01-17

申请人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Markus Gewehr ,  Jordi Tormo i Blasco ,  Arne Ptock ,  Bernd Müller ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz

发明人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Markus Gewehr ,  Jordi Tormo i Blasco ,  Arne Ptock ,  Bernd Müller ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz

IPC分类号： C07C23305

CPC分类号： C07C251/48 ,  A01N37/50

摘要： Iminooxy-substituted benzyl phenyl ethers of the formula I in which the substituents and the index are as defined below: Y is H, CH3, F or Cl; Q is C(═CHOCH3)—COOCH3, C(═CHCH3)—COOCH3, C(═NOCH3)—COOCH3, C(═NOCH3)—CONHCH3 or N(—OCH3)—COOCH3; X is hydrogen, halogen, alkyl, alkoxy or CF3; m is 1 or 2, where the radicals X may be different if m=2; R1 is alkyl and R2 is hydrogen or alkyl; or R1 and R2 together are cyclopropyl, cyclopentyl or cyclohexyl; R3 is alkyl or CF3; and R4 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl or haloalkynyl; processes and intermediates for their preparation, compositions comprising them, and their use, are described.

摘要翻译： 取代基和指数如下定义的式Iin的亚氨氧基取代的苄基苯基醚：Y是H，CH 3，F或Cl; Q是C（= CHOCH 3）-COOCH 3，C（= CHCH 3）-COOCH 3，C （= NOCH 3）-COOCH 3，C（= NOCH 3）-CONHCH 3或N（-OCH 3）-COOCH 3; X是氢，卤素，烷基，烷氧基或CF 3; m是1或2，其中基团X可以不同，如果m = 2; R 1是烷基，R 2是氢或烷基; 或者R 1和R 2一起是环丙基，环戊基或环己基; R 3是烷基或CF 3; 和R 4是烷基，烯基，炔基，卤代烷基，卤代烯基或卤代炔基;其制备方法和中间体，包含它们的组合物及其用途。