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    Substituted (4-brompyrazole-3-yl) benzazoles
    5.
    发明授权
    Substituted (4-brompyrazole-3-yl) benzazoles 失效

    公开(公告)号：US06482774B1

    公开(公告)日：2002-11-19

    申请号：US09673996

    申请日：2000-10-25

    申请人： Cyrill Zagar ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Robert Reinhard ,  Peter Schäfer ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    发明人： Cyrill Zagar ,  Gerhard Hamprecht ,  Markus Menges ,  Olaf Menke ,  Robert Reinhard ,  Peter Schäfer ,  Karl-Otto Westphalen ,  Martina Otten ,  Helmut Walter

    IPC分类号： C07D41704

    CPC分类号： C07D413/04 ,  A01N43/74 ,  C07D231/16 ,  C07D417/04 ,  C07D417/14 ,  C07F9/6541 ,  C07F9/65583

    摘要： Substituted (4-bromopyrazol-3-yl)benzazoles I and their salts where R1=H, C1-C4-alkyl, C1-C4-haloalkyl; R2=CN, Cl-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; R4=H, halogen; R5=H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; Z=—N═C(XR6)—O— or —N═C(XR6)—S—, attached to &agr; via the nitrogen, oxygen or sulfur; X=a chemical bond, oxygen, sulfur, —S(O)—, —SO2—, —NH— or —N(R7)—; R6, R7=Cl-C6-alkyl, Cl-C6-haloalkyl, cyano-Cl-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkynyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-Cl-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, Cl-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-Cl-C4-alkyl, C1-C4-haloalkylsulfinyl-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkynylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, C1-C4-haloalkylsulfonyl-C1-C4-alkyl, C3-C4-alkenylsulfonyl-C1-C4-alkyl, C3-C4-alkynylsulfonyl-C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl, which may carry a CN or C1-C4-alkoxycarbonyl group, C1-C4-alkylthiocarbonyl-C1-C4-alkyl, aminocarbonyl-C1-C4-alkyl, C1-C4-alkylaminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di(C1-C4-alkyl)-phosphonyl-C1-C4-alkyl, C1-C4-alkoxyimino-C1-C4-alkyl, C3-C4-alkenyloxyimino-C1-C4-alkyl, unsubstituted or substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-membered heterocyclyl or heterocyclyl-C1-C4-alkyl, where each cycloalkyl and each heterocyclyl ring may contain a CO or CS ring member; if X=a chemical bond, —O—, —S—, —NH— or —N(R7)—, R6 may also be C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkylsulfonyl or C1-C4-haloalkylsulfonyl; if X=a chemical bond, R6 may furthermore be CN, SH, NH2, halogen, —CH2—CH(halogen)-R8, —CH═CH—R8 or —CH═C(halogen)-R8, where R8=COOH, C1-C4-alkoxycarbonyl, C1-C4-alkylthiocarbonyl, CONH2, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl or di(C1-C4-alkyl)phosphonyl; or R6+R7=an unsubstituted or substituted 1,3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene chain. Use: As herbicides; for the desiccation/defoliation of plants.

    Use of nitroethane derivatives as microbicides and specific nitroethane derivatives
    8.
    发明授权
    Use of nitroethane derivatives as microbicides and specific nitroethane derivatives 失效
    使用硝基乙烷衍生物作为杀菌剂和特定的硝基乙烷衍生物

    公开(公告)号：US06268514B1

    公开(公告)日：2001-07-31

    申请号：US09581420

    申请日：2000-06-13

    申请人： Gerhard Hamprecht ,  John-Bryan Speakman ,  Gisela Lorenz ,  Kurt Eger ,  Mathias Schmidt ,  Uta Witt

    发明人： Gerhard Hamprecht ,  John-Bryan Speakman ,  Gisela Lorenz ,  Kurt Eger ,  Mathias Schmidt ,  Uta Witt

    IPC分类号： C07D49302

    CPC分类号： C07D493/04 ,  A01N43/90

    摘要： The use of nitroethane derivatives of the formula I where: R1 is hydrogen, unsubstituted or substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, halogen, cyano or thiocyanato; R2 is hydrogen, formyl; halogen- or C1-C3-alkoxy-substituted or unsubstituted C1-C6-alkylcarbonyl, C2-C6-alkenylcarbonyl, C4-C6-alkyldienylcarbonyl or C2-C6-alkynylcarbonyl; A is unsubstituted or substituted phenyl, naphthyl, quinolyl, quinazolyl, quinoxalyl, 1-methylindolyl, 1-methylbenzimidazolyl, 2-methylindazolyl, benzofuranyl, benzothienyl, benzoxazolyl, benzothiazolyl, furyl, thienyl, pyrrolyl, isoxazolyl, isothiazolyl, pyrazolyl, oxazolyl, thiazolyl, imidazolyl, oxadiazolyl, thiadiazolyl, triazolyl, pyridinyl, pyridazinyl, pyrimidinyl, pyrazinyl or triazinyl, pyranyl or thiopyranyl; as microbicides is described.

    摘要翻译： 使用式I的硝基乙烷衍生物其中：R 1是氢，未取代或取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基，C 3 -C 6 - 炔基，卤素，氰基或硫氰酸酯; R 2是氢，甲酰基; 卤素或C 1 -C 3烷氧基取代或未取代的C 1 -C 6烷基羰基，C 2 -C 6 - 烯基羰基，C 4 -C 6烷基二烯基羰基或C 2 -C 6 - 炔基羰基; A是未取代或取代的苯基，萘基，喹啉基，喹唑啉基，喹喔啉基 ，1-甲基吲哚基，1-甲基苯并咪唑基，2-甲基吲唑基，苯并呋喃基，苯并噻吩基，苯并恶唑基，苯并噻唑基，呋喃基，噻吩基，吡咯基，异恶唑基，异噻唑基，吡唑基，恶唑基，噻唑基，咪唑基，恶二唑基，噻二唑基，三唑基，吡啶基，哒嗪基，嘧啶基 ，吡嗪基或三嗪基，吡喃基或噻喃基;描述为杀微生物剂。