Blowing Agent Composition of Hydrochlorofluoroolefin

    公开(公告)号:US20220267600A1

    公开(公告)日:2022-08-25

    申请号:US17723521

    申请日:2022-04-25

    Applicant: Arkema Inc.

    Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

    Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins

    公开(公告)号:US11091602B2

    公开(公告)日:2021-08-17

    申请号:US15659663

    申请日:2017-07-26

    Applicant: Arkema Inc.

    Abstract: The present invention relates to blowing agent compositions of carbon dioxide and at least one hydrochlorofluoroolefin (HCFO). The HCFOs can include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor made from thermoplastic resins. The blowing agent compositions may also optionally include one or more hydrofluoroolefins (HFOs).

    Stability of polyurethane polyol blends containing halogenated olefin blowing agents

    公开(公告)号:US10961339B2

    公开(公告)日:2021-03-30

    申请号:US16397028

    申请日:2019-04-29

    Applicant: Arkema Inc.

    Abstract: A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N′-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba).

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