公开(公告)号：US20130102504A1

公开(公告)日：2013-04-25

申请号：US13659454

申请日：2012-10-24

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oette ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和制备以及包含该混合物的含水表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中将表面活性剂水溶液注入矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。

公开(公告)号：US09701890B2

公开(公告)日：2017-07-11

申请号：US14078908

申请日：2013-11-13

Applicant: BASF SE

Inventor： Roland Reichenbach-Klinke ,  Bjorn Langlotz ,  Ian Robert Macefield ,  Christian Spindler

IPC: E21B43/20 ,  E21B43/25 ,  C09K8/584 ,  C09K8/588

CPC classification number: C09K8/588 ,  C09K8/584

Abstract: Process for tertiary mineral oil production in which an aqueous injection fluid comprising at least a water soluble polyacrylamide-(co)polymer dissolved in the aqueous fluid is injected into a mineral oil deposit and the aqueous injection fluid is prepared by mixing a liquid dispersion polymer composition comprising particles of polyacrylamide-(co)polymers dispersed in an organic, hydrophobic liquid with an aqueous fluid. Preferably, the process is carried out on an off-shore production site.

公开(公告)号：US09657137B2

公开(公告)日：2017-05-23

申请号：US14652244

申请日：2013-12-13

Applicant: BASF SE

Inventor： Christian Bittner ,  Björn Langlotz ,  Benjamin Wenzke ,  Christian Spindler ,  Roland Reichenbach-Klinke ,  Markus Klumpe ,  Nicole Meier ,  Ulrich Annen ,  Thomas Ostrowski

IPC: C08G65/26 ,  C08F216/14 ,  C08F290/06

CPC classification number: C08G65/2696 ,  C08F216/1416 ,  C08F290/062 ,  C08F2216/1425 ,  C08G65/2609 ,  C08G65/2648 ,  C08G2650/36 ,  C08F220/58 ,  C08F2220/585 ,  C08F220/56

Abstract: The present invention relates to a process for preparing hydrophobically associating macromonomers M and to the novel macromonomers prepared by means of the process according to the invention. The macromonomers M comprise a copolymerizable, ethylenically unsaturated group and a polyether structure in block form, the latter consisting of a polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. Optionally, the macromonomers M may have a terminal polyethyleneoxy block. The macromonomers prepared by the process according to the invention are suitable for reaction with further monomers, especially with acrylamide, to give a water-soluble, hydrophobically associating copolymer.

公开(公告)号：US09475978B2

公开(公告)日：2016-10-25

申请号：US13659393

申请日：2012-10-24

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/602 ,  C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明还涉及其使用和制备，以及包含该混合物的水性表面活性剂制剂，以及通过Winsor III型微乳液淹水生产矿物油的方法，其中将表面活性剂水溶液注入到矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。

公开(公告)号：US20150353818A1

公开(公告)日：2015-12-10

申请号：US14832425

申请日：2015-08-21

Applicant: BASF SE*

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Vogel ,  Petra Neumann ,  Veronika Wloka ,  Martin Bock

IPC: C09K8/86 ,  E21B43/16

CPC classification number: C09K8/86 ,  C09K8/584 ,  E21B43/16

Abstract: The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O-(D)n-(B)m-(A)l-XYa−a/bMb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.

Abstract translation: 本发明涉及一种通过Winsor III型微乳液淹水进行矿物油提取的方法，其中包含至少三种离子表面活性剂的水性表面活性剂制剂，其对于烷基部分（R 1）（R 2）-CH- CH 2 - 并且具有通式（R1）（R2）-CH-CH2-O-（D）n-（B）m-（A）1-XYa-a / bMb +通过注射钻孔注入矿物油 通过生产钻孔从存款中取出原油。 本发明还涉及通式为离子表面活性剂的表面活性剂制剂。

公开(公告)号：US20140182851A1

公开(公告)日：2014-07-03

申请号：US14201323

申请日：2014-03-07

Applicant: BASF SE ,  Board of Regents, The University of Texas System

Inventor： Upali P. Weerasooriya ,  Gary A. Pope ,  Christian Bittner ,  Gunter Oetter ,  Jack F. Tinsley ,  Christian Spindler ,  Gabriela Alvarez Jurgenson ,  Sophie Vogel

IPC: C09K8/584 ,  E21B43/16

CPC classification number: C09K8/584 ,  C07C305/10 ,  C07C309/10 ,  C08G65/2609 ,  C08G65/3344 ,  E21B43/16

Abstract: Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.

Abstract translation: 本文描述了通过使用环氧丁烷和任选的环氧丙烷和/或环氧乙烷烷氧基化具有12至36个碳原子的格伯特醇（GA），然后引入末端阴离子基团来合成阴离子表面活性剂的组合物和方法。 本发明的GA通过易于且廉价的方法制备，其涉及具有6至18个碳原子的醇的高温碱催化二聚。 本发明的大型疏水醚表面活性剂用于增强采油（EOR）应用中，其用于溶解和动员油并用于环境清洁。 此外，不含阴离子末端基团的疏水基烷氧基化GA可用作超高分子量非离子表面活性剂。

公开(公告)号：US20140116690A1

公开(公告)日：2014-05-01

申请号：US14063013

申请日：2013-10-25

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: E21B43/16 ,  C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least one secondary alkanesulfonate having 14 to 17 carbon atoms of the general formula (I) and at least one anionic surfactant of the general formula (II) where R1, R2, R3, R4, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and production thereof, and to aqueous surfactant formulations comprising the surfactant mixture, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected through injection wells into a mineral oil deposit and crude oil is withdrawn through production wells from the deposit.

Abstract translation: 本发明涉及包含至少一种具有通式（I）的14至17个碳原子的仲烷基磺酸盐和至少一种通式（II）的阴离子表面活性剂的表面活性剂混合物，其中R1，R2，R3，R4，A0 ，k，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和生产以及包含表面活性剂混合物的水性表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中水性表面活性剂制剂通过注入井注入到 矿床和原油通过生产井从矿床中撤出。

公开(公告)号：US20130102505A1

公开(公告)日：2013-04-25

申请号：US13659285

申请日：2012-10-24

Applicant: Basf SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和制备以及包含该混合物的含水表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中将表面活性剂水溶液注入矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。