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公开(公告)号：US20180366757A1
公开(公告)日：2018-12-20
申请号：US15625750
申请日：2017-06-16
Applicant: Battelle Memorial Institute
Inventor： Xiaoliang Wei , Wei Wang , Aaron M. Hollas , Vincent L. Sprenkle , Zimin Nie , Bin Li
CPC classification number: H01M8/188 , C07D241/46 , H01M4/90 , H01M4/9016 , H01M4/96 , H01M8/08 , H01M2300/0002
Abstract: Embodiments of an aqueous electrolyte comprising a base and a phenazine derivative are disclosed. Redox flow batteries including the aqueous electrolyte are also disclosed. The phenazine derivative has a chemical structure according to formula I:
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公开(公告)号：US20140199607A1
公开(公告)日：2014-07-17
申请号：US14105823
申请日：2013-12-13
Applicant: Battelle Memorial Institute
Inventor： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Zimin Nie , Baowei Chen , Jianlu Zhang , Guanguang Xia
CPC classification number: H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
Abstract: Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
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公开(公告)号：US10727539B2
公开(公告)日：2020-07-28
申请号：US15724051
申请日：2017-10-03
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Bin Li , Huilin Pan , Zimin Nie , Jun Liu , Vincent L. Sprenkle
IPC: H01M10/36 , H01M4/62 , H01M10/04 , H01M4/42 , H01M4/38 , H01M4/66 , H01M4/58 , H01M10/38 , H01M4/02
Abstract: Disclosed are cathodes having electron-conductive high-surface-area materials, aqueous non-halide-containing electrolytes, secondary zinc-iodine energy storage devices using the same, and methods for assembling the same. The disclosed high-surface-area materials and the aqueous non-halide-containing electrolyte solutions can contribute together to the confinement of the active iodine species in the cathode and to the minimization of shuttle effects and self-discharging. The non-halide-containing electrolyte salts can facilitate preferential adsorption of the iodine species to the cathode material rather than dissolution in the aqueous electrolyte solution, thereby contributing to the confinement of the active iodine species.
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公开(公告)号：US09748595B2
公开(公告)日：2017-08-29
申请号：US14089499
申请日：2013-11-25
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Bin Li , Zimin Nie , Wei Wang , Jun Liu , Vincent L. Sprenkle
CPC classification number: H01M8/188 , H01M8/20 , Y02E60/528
Abstract: Improved metal-based redox flow batteries (RFBs) can utilize a metal and a divalent cation of the metal (M2+) as an active redox couple for a first electrode and electrolyte, respectively, in a first half-cell. For example, the metal can be Zn. The RFBs can also utilize a second electrolyte having I−, anions of Ix (for x≧3), or both in an aqueous solution, wherein the I− and the anions of Ix (for x≧3) compose an active redox couple in a second half-cell.
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公开(公告)号：US20160308233A1
公开(公告)日：2016-10-20
申请号：US14690224
申请日：2015-04-17
Applicant: Battelle Memorial Institute
Inventor： Tianbiao Liu , Bin Li , Xiaoliang Wei , Zimin Nie , Wei Wang , Jun Liu , Vincent L. Sprenkle
CPC classification number: H01M8/188 , H01M8/20 , H01M2300/0002 , Y02E60/528
Abstract: An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.
Abstract translation: 水性氧化还原液流电池系统包括水性阴极电解液和阳极电解液。 含水阴极电解液可以包含（i）任选取代的硫脲或硝酰自由基化合物和（ii）阴极电解液水性支持溶液。 水性阳极电解液可以包含（i）金属阳离子或紫色化合物和（ii）阳极电解液水性支持溶液。 阴极电解液水性支持溶液和阳极电解液水性支持溶液独立地可以包括（i）质子源，（ii）卤素源，或（iii）质子源和卤素源。
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Patent Agency Ranking
公开(公告)号：US20160099480A1
公开(公告)日：2016-04-07
申请号：US14875565
申请日：2015-10-05
Applicant: Battelle Memorial Institute
Inventor： Zimin Nie , Wei Wang , Xiaoliang Wei , Bin Li , Jun Liu , Vincent L. Sprenkle
Abstract: All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.
Abstract translation: 全硫酸钒氧化还原液电池系统具有阴极电解液和阳极电解液，其包含含有氯离子和磷酸根离子的水性支持溶液。 含水载体溶液稳定并提高钒物质在电解质中的溶解度，允许在所需工作温度范围内提高钒浓度。 根据一个实例，氯离子由MgCl 2提供，磷酸根离子由（NH 4）2 HPO 4提供。
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17.发明申请公开(公告)号：US20150380757A1
公开(公告)日：2015-12-31
申请号：US14815037
申请日：2015-07-31
Applicant: Battelle Memorial Institute
Inventor： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Zimin Nie , Baowei Chen , Jianlu Zhang , Guanguang Xia
CPC classification number: H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
Abstract: Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
Abstract translation: 具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。 此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。 根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。 支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。
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18.发明授权公开(公告)号：US09123931B2
公开(公告)日：2015-09-01
申请号：US14105823
申请日：2013-12-13
Applicant: Battelle Memorial Institute
Inventor： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Zimin Nie , Baowei Chen , Jianlu Zhang , Guanguang Xia
CPC classification number: H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
Abstract: Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
Abstract translation: 具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。 此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。 根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。 支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。
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19.发明申请公开(公告)号：US20140234753A1
公开(公告)日：2014-08-21
申请号：US14261262
申请日：2014-04-24
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Zimin Nie , Baowei Chen , Jianlu Zhang , Guanguang Xia
CPC classification number: H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
Abstract: Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
Abstract translation: 具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。 此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。 根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。 支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。
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20.发明申请公开(公告)号：US20140127542A1
公开(公告)日：2014-05-08
申请号：US13668604
申请日：2012-11-05
Applicant: Battelle Memorial Institute
Inventor： Bin Li , Xiaoliang Wei , Qingtao Luo , Zimin Nie , Wei Wang , Vincent L. Sprenkle
CPC classification number: H01M8/0243 , H01M8/0289 , H01M8/04186 , H01M8/188 , H01M8/20 , Y02E60/528
Abstract: Composite separators having a porous structure and including acid-stable, hydrophilic, inorganic particles enmeshed in a substantially fully fluorinated polyolefin matrix can be utilized in a number of applications. The inorganic particles can provide hydrophilic characteristics. The pores of the separator result in good selectivity and electrical conductivity. The fluorinated polymeric backbone can result in high chemical stability. Accordingly, one application of the composite separators is in redox flow batteries as low cost membranes. In such applications, the composite separator can also enable additional property-enhancing features compared to ion-exchange membranes. For example, simple capacity control can be achieved through hydraulic pressure by balancing the volumes of electrolyte on each side of the separator. While a porous separator can also allow for volume and pressure regulation, in RFBs that utilize corrosive and/or oxidizing compounds, the composite separators described herein are preferable for their robustness in the presence of such compounds.
Abstract translation: 具有多孔结构并且包含在基本上完全氟化的聚烯烃基质中的酸稳定的，亲水的无机颗粒的复合隔膜可用于许多应用中。 无机颗粒可以提供亲水性。 分离器的孔导致良好的选择性和导电性。 氟化聚合物骨架可导致高的化学稳定性。 因此，复合隔板的一个应用是作为低成本膜的氧化还原液流电池。 在这种应用中，与离子交换膜相比，复合分离器还可以实现额外的性能增强特征。 例如，通过平衡分离器两侧的电解液的体积，可以通过液压来实现简单的容量控制。 虽然多孔分离器还可以允许体积和压力调节，但是在使用腐蚀性和/或氧化性化合物的RFB中，本文所述的复合隔膜在其存在下的稳健性是优选的。
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