Abstract:
An abnormality determination device for a secondary battery includes an internal-resistance calculation unit, a threshold memory unit, a capacity balance comparison unit, and an abnormality determination unit. The internal-resistance calculation unit detects an internal resistance in a negative-electrode reaction resistance dominant region in which a reaction resistance of a negative electrode is dominant in a charge and discharge reaction of the secondary battery. The threshold memory unit stores a capacity balance threshold used as a reference for determining abnormality in a balance between a capacity of a positive electrode and a capacity of the negative electrode in the secondary battery. The capacity balance comparison unit compares the internal resistance calculated by the internal-resistance calculation unit with the capacity balance threshold stored in the threshold memory unit. The abnormality determination unit determines abnormality in capacity balance in the secondary battery based on a comparison result from the capacity balance comparison unit.
Abstract:
A battery monitoring system includes a data acquiring unit and a failure determining unit. The data acquiring unit acquires a plurality of types of monitoring data to monitor a state of a secondary battery. The failure determining unit determines whether the secondary battery has failed. The failure determining unit performs sparsity regularization using the monitoring data as variables and calculates a partial correlation coefficient matrix of the monitoring data. The failure determining unit calculates, as an abnormality level, an amount of change in a partial correlation coefficient, which is a component of the partial correlation coefficient matrix, between two partial correlation coefficient matrices calculated at different periods. The failure determining unit determines that the secondary battery has failed when the calculated abnormality level exceeds a predetermined threshold.
Abstract:
A non-aqueous rechargeable battery has a non-aqueous electrolyte and positive and negative electrodes capable of intercalating and deintercalating lithium ions. The positive electrode contains a lithium transition metal oxide expressed by Li2-xNiαM1βM2γO4-∈, where 0.50
Abstract:
A positive electrode material includes: Li2NiαM1βM2γMnηO4-∈ that has a layered structure including a Li layer and a Ni layer, and in which a Ni—O bond length is shorter than that calculated from the Shannon's ionic radii. α satisfies a relation of 0.50
Abstract translation:正极材料包括:Li2Ni1M1βM2γMnηO4-∈,其具有包括Li层和Ni层的层状结构,其中Ni-O键长度短于从香农离子半径计算的长度。 α满足0.50 <α≤1.33的关系,β满足0≤β<0.67的关系,γ满足0.33≤γ≤1.1的关系,η满足关系0≤η≤1.00,∈满足关系0 ≤∈1.00,M1表示选自Co和Ga中的至少一种,M2表示选自Ge,Sn和Sb中的至少一种。 正极材料可以表示在用R3m的空间群指数化的粉末X射线衍射的测量中,0.9以上的峰强度比(I 300 / I 104)
Abstract:
A positive electrode material includes: Li2NiαM1βM2γMnηO4-ε; a layered structure including a Li layer and a Ni layer; and a chemical bond of M2-O. α satisfies an equation of 0.50